Diiodido{2-[(4-methoxyphenyl)iminomethyl]pyridine-κ2N,N′}zinc
In the title complex, [ZnI2(C13H12N2O)], the ZnII atom has a distorted tetrahedral coordination. The organic ligand is bidentate, coordinating the ZnII atom via the two N atoms. The benzene and pyridine rings are oriented at a dihedral angle of 11.67 (9)°. In the crystal,...
Main Authors: | , , |
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2012-08-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812030486 |
Summary: | In the title complex, [ZnI2(C13H12N2O)], the ZnII atom has a distorted tetrahedral coordination. The organic ligand is bidentate, coordinating the ZnII atom via the two N atoms. The benzene and pyridine rings are oriented at a dihedral angle of 11.67 (9)°. In the crystal, weak C—H...I and C—H...O hydrogen bonds are observed, in addition to π–π stacking interactions, with a centroid–centroid distance of 3.72 (5) Å. |
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ISSN: | 1600-5368 |