Construction of crystallization nucleation and network crosslinking structure in bamboo scrap/magnesium oxychloride composites via nano-SiO2

The problem of utilizing substantial bamboo residual waste while also improving the quality of building composites was addressed by preparing bamboo scrap/magnesium oxychloride composites using bamboo scraps as a reinforcing material and magnesium oxychloride as a matrix. However, problems remain, s...

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Main Authors: Long Zheng, Yiqiang Wu, Ping Li, Baorong Sun, Guoan Sheng, Yingfeng Zuo
Format: Article
Language:English
Published: Elsevier 2021-11-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S223878542101320X
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author Long Zheng
Yiqiang Wu
Ping Li
Baorong Sun
Guoan Sheng
Yingfeng Zuo
author_facet Long Zheng
Yiqiang Wu
Ping Li
Baorong Sun
Guoan Sheng
Yingfeng Zuo
author_sort Long Zheng
collection DOAJ
description The problem of utilizing substantial bamboo residual waste while also improving the quality of building composites was addressed by preparing bamboo scrap/magnesium oxychloride composites using bamboo scraps as a reinforcing material and magnesium oxychloride as a matrix. However, problems remain, such as poor interface compatibility and poor water resistance, which limit its application range. Herein, nano-silica (nSiO2) was found to build a crystal nucleus and a network structure in the composites, such that the bamboo scrap/magnesium oxychloride composites had higher mechanical properties and water resistance. In addition, the nSiO2 crystal nucleus structure promoted the composites hydration process, promoted the growth of the 5-phase crystals and the close arrangement of the cross, thereby improved composites strength. The nSiO2 build a network structure at composites interface, which improved the compatibility of composites interfaces, thus improving water resistance. At the same time, nSiO2 and the crystal nuclei adsorbed a portion of CO2 and CO, which had a certain hindering effect on the release of toxic gases in fire, and provided new ideas for fire safety protection. These results expanded the scope of application of building composites, which can be used in the fields of fireproof materials and building decoration materials, and provided a good solution for bamboo processing waste, thus making a certain contribution to green environmental protection.
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spelling doaj.art-e5005944a7db42938a15fc8c17c67edc2022-12-21T19:37:59ZengElsevierJournal of Materials Research and Technology2238-78542021-11-011554965506Construction of crystallization nucleation and network crosslinking structure in bamboo scrap/magnesium oxychloride composites via nano-SiO2Long Zheng0Yiqiang Wu1Ping Li2Baorong Sun3Guoan Sheng4Yingfeng Zuo5College of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha, Hunan, 410004, PR ChinaCollege of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha, Hunan, 410004, PR ChinaCollege of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha, Hunan, 410004, PR ChinaCollege of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha, Hunan, 410004, PR ChinaCollege of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha, Hunan, 410004, PR ChinaCorresponding author.; College of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha, Hunan, 410004, PR ChinaThe problem of utilizing substantial bamboo residual waste while also improving the quality of building composites was addressed by preparing bamboo scrap/magnesium oxychloride composites using bamboo scraps as a reinforcing material and magnesium oxychloride as a matrix. However, problems remain, such as poor interface compatibility and poor water resistance, which limit its application range. Herein, nano-silica (nSiO2) was found to build a crystal nucleus and a network structure in the composites, such that the bamboo scrap/magnesium oxychloride composites had higher mechanical properties and water resistance. In addition, the nSiO2 crystal nucleus structure promoted the composites hydration process, promoted the growth of the 5-phase crystals and the close arrangement of the cross, thereby improved composites strength. The nSiO2 build a network structure at composites interface, which improved the compatibility of composites interfaces, thus improving water resistance. At the same time, nSiO2 and the crystal nuclei adsorbed a portion of CO2 and CO, which had a certain hindering effect on the release of toxic gases in fire, and provided new ideas for fire safety protection. These results expanded the scope of application of building composites, which can be used in the fields of fireproof materials and building decoration materials, and provided a good solution for bamboo processing waste, thus making a certain contribution to green environmental protection.http://www.sciencedirect.com/science/article/pii/S223878542101320XNano-SiO2Bamboo scrapsCompositesCrystal nucleusNetwork structureMagnesium oxychloride
spellingShingle Long Zheng
Yiqiang Wu
Ping Li
Baorong Sun
Guoan Sheng
Yingfeng Zuo
Construction of crystallization nucleation and network crosslinking structure in bamboo scrap/magnesium oxychloride composites via nano-SiO2
Journal of Materials Research and Technology
Nano-SiO2
Bamboo scraps
Composites
Crystal nucleus
Network structure
Magnesium oxychloride
title Construction of crystallization nucleation and network crosslinking structure in bamboo scrap/magnesium oxychloride composites via nano-SiO2
title_full Construction of crystallization nucleation and network crosslinking structure in bamboo scrap/magnesium oxychloride composites via nano-SiO2
title_fullStr Construction of crystallization nucleation and network crosslinking structure in bamboo scrap/magnesium oxychloride composites via nano-SiO2
title_full_unstemmed Construction of crystallization nucleation and network crosslinking structure in bamboo scrap/magnesium oxychloride composites via nano-SiO2
title_short Construction of crystallization nucleation and network crosslinking structure in bamboo scrap/magnesium oxychloride composites via nano-SiO2
title_sort construction of crystallization nucleation and network crosslinking structure in bamboo scrap magnesium oxychloride composites via nano sio2
topic Nano-SiO2
Bamboo scraps
Composites
Crystal nucleus
Network structure
Magnesium oxychloride
url http://www.sciencedirect.com/science/article/pii/S223878542101320X
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AT pingli constructionofcrystallizationnucleationandnetworkcrosslinkingstructureinbambooscrapmagnesiumoxychloridecompositesviananosio2
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