Dichlorido{N-[2-(diphenylphosphanyl)benzylidene]isopropylamine-κ2N,P}palladium(II) dimethyl sulfoxide monosolvate
In the title PdII complex, [PdCl2(C22H22NP)]·(CH3)2SO, the PdII atom is coordinated in an NPCl2 coordination sphere by the N(imino) and P(phosphane) atoms of the ligand and by two Cl− ions in a slightly distorted square-planar geometry [r.m.s. deviation = 0.081&#81...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811013936 |
| Summary: | In the title PdII complex, [PdCl2(C22H22NP)]·(CH3)2SO, the PdII atom is coordinated in an NPCl2 coordination sphere by the N(imino) and P(phosphane) atoms of the ligand and by two Cl− ions in a slightly distorted square-planar geometry [r.m.s. deviation = 0.081 (3) Å, plane defined by the four atoms around the Pd atom]. The dimethyl sulfoxide solvent molecules form centrosymmetric dimers due to an intermolecular C—H...O interaction. The crystal structure is further stabilized through two intermolecular C—H...π interactions. |
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| ISSN: | 1600-5368 |