Recent advances in the asymmetrical templation effect of polyoxometalate in silver clusters
The design and construction of polyoxometalate (POM)-templated silver clusters have received increasing attention, not only due to their aesthetic structures but also to their wide applications in chromatic materials, magnetism, electronics, and fluorescence. Among various POM-templated silver clust...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Tsinghua University Press
2022-12-01
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| Series: | Polyoxometalates |
| Subjects: | |
| Online Access: | https://www.sciopen.com/article/10.26599/POM.2022.9140010 |
| _version_ | 1797865993518710784 |
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| author | Jia-Yang Shi Rakesh Kumar Gupta Yong-Kai Deng Di Sun Zhi Wang |
| author_facet | Jia-Yang Shi Rakesh Kumar Gupta Yong-Kai Deng Di Sun Zhi Wang |
| author_sort | Jia-Yang Shi |
| collection | DOAJ |
| description | The design and construction of polyoxometalate (POM)-templated silver clusters have received increasing attention, not only due to their aesthetic structures but also to their wide applications in chromatic materials, magnetism, electronics, and fluorescence. Among various POM-templated silver clusters, asymmetrically-wrapped POM–silver clusters have unusual structures: POMs have exposed surfaces and an asymmetrically-connected silver shell, which endows the clusters with distinctive properties, such as redox and electrocatalytic activities. This review summarizes recent developments in this field, highlighting the syntheses, structures, and properties of the asymmetrically-wrapped POM–silver clusters. The formation mechanisms, challenges, and perspectives of such clusters are also discussed. We believe that this review will motivate the development of the asymmetrical templation effect of POM in silver clusters. |
| first_indexed | 2024-04-09T23:18:00Z |
| format | Article |
| id | doaj.art-e53649bee6654fe4afb36cea23cb263b |
| institution | Directory Open Access Journal |
| issn | 2957-9821 2957-9503 |
| language | English |
| last_indexed | 2024-04-09T23:18:00Z |
| publishDate | 2022-12-01 |
| publisher | Tsinghua University Press |
| record_format | Article |
| series | Polyoxometalates |
| spelling | doaj.art-e53649bee6654fe4afb36cea23cb263b2023-03-22T05:55:01ZengTsinghua University PressPolyoxometalates2957-98212957-95032022-12-01129140010914001010.26599/POM.2022.9140010Recent advances in the asymmetrical templation effect of polyoxometalate in silver clustersJia-Yang Shi0Rakesh Kumar Gupta1Yong-Kai Deng2Di Sun3Zhi Wang4https://orcid.org/0000-0001-8315-3501School of Chemistry and Chemical Engineering, State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, ChinaSchool of Chemistry and Chemical Engineering, State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, ChinaSchool of Chemistry and Chemical Engineering, State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, ChinaSchool of Chemistry and Chemical Engineering, State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, ChinaSchool of Chemistry and Chemical Engineering, State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, ChinaThe design and construction of polyoxometalate (POM)-templated silver clusters have received increasing attention, not only due to their aesthetic structures but also to their wide applications in chromatic materials, magnetism, electronics, and fluorescence. Among various POM-templated silver clusters, asymmetrically-wrapped POM–silver clusters have unusual structures: POMs have exposed surfaces and an asymmetrically-connected silver shell, which endows the clusters with distinctive properties, such as redox and electrocatalytic activities. This review summarizes recent developments in this field, highlighting the syntheses, structures, and properties of the asymmetrically-wrapped POM–silver clusters. The formation mechanisms, challenges, and perspectives of such clusters are also discussed. We believe that this review will motivate the development of the asymmetrical templation effect of POM in silver clusters.https://www.sciopen.com/article/10.26599/POM.2022.9140010asymmetrical templation effectpolyoxometalatessilver clusterssynthesesstructureselectrochemical properties |
| spellingShingle | Jia-Yang Shi Rakesh Kumar Gupta Yong-Kai Deng Di Sun Zhi Wang Recent advances in the asymmetrical templation effect of polyoxometalate in silver clusters Polyoxometalates asymmetrical templation effect polyoxometalates silver clusters syntheses structures electrochemical properties |
| title | Recent advances in the asymmetrical templation effect of polyoxometalate in silver clusters |
| title_full | Recent advances in the asymmetrical templation effect of polyoxometalate in silver clusters |
| title_fullStr | Recent advances in the asymmetrical templation effect of polyoxometalate in silver clusters |
| title_full_unstemmed | Recent advances in the asymmetrical templation effect of polyoxometalate in silver clusters |
| title_short | Recent advances in the asymmetrical templation effect of polyoxometalate in silver clusters |
| title_sort | recent advances in the asymmetrical templation effect of polyoxometalate in silver clusters |
| topic | asymmetrical templation effect polyoxometalates silver clusters syntheses structures electrochemical properties |
| url | https://www.sciopen.com/article/10.26599/POM.2022.9140010 |
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