Study on the Mechanism of Procyanidins Adsorption onto Chitosan Microflower
In order to understand the adsorption mechanism of chitosan microflower (CSMF) on procyanidins (PC), CSMF was used as an adsorbent to adsorb PC solutions under different adsorption conditions. The drug-loaded particles were characterized by scanning electron microscopy (SEM), Fourier infrared (FTIR)...
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| Format: | Article |
| Language: | zho |
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The editorial department of Science and Technology of Food Industry
2023-09-01
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| Series: | Shipin gongye ke-ji |
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| Online Access: | http://www.spgykj.com/cn/article/doi/10.13386/j.issn1002-0306.2022100097 |
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| author | Siyu JIAO Dingyu XU Xianchao YAO Xin LIU Chunyan LIN Lixin HE Rihui LIN |
| author_facet | Siyu JIAO Dingyu XU Xianchao YAO Xin LIU Chunyan LIN Lixin HE Rihui LIN |
| author_sort | Siyu JIAO |
| collection | DOAJ |
| description | In order to understand the adsorption mechanism of chitosan microflower (CSMF) on procyanidins (PC), CSMF was used as an adsorbent to adsorb PC solutions under different adsorption conditions. The drug-loaded particles were characterized by scanning electron microscopy (SEM), Fourier infrared (FTIR), X-ray diffraction (XRD), etc. Through adsorption kinetics, adsorption isotherm, and adsorption thermodynamics, the mechanism of CSMF adsorption PC was systematically studied. The results showed that the FTIR pattern of the drug-loaded particles produced a new characteristic peak at 1456 cm−1, indicating that the PC was successfully loaded onto the CSMF. The results of SEM and XRD analysis showed that the morphology and crystallinity of CSMF did not change after loading. The adsorption kinetics showed that the adsorption of PC by CSMF conformed to the pseudo-second-order kinetic model, and the adsorption rate was affected by the interaction between particle diffusion and boundary layer diffusion. The adsorption isotherm showed that the Freundlich adsorption isotherm model could more accurately reflect the entire adsorption process, indicating that the adsorption process of CSMF to PC was multilayer adsorption with surface energy inhomogeneity. Finally, adsorption thermodynamics showed that the adsorption of PC by CSMF was a spontaneous physical adsorption process with reduced entropy. |
| first_indexed | 2024-03-12T01:54:43Z |
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| id | doaj.art-e5419e6ea7c34a33bf5be5aebd53e415 |
| institution | Directory Open Access Journal |
| issn | 1002-0306 |
| language | zho |
| last_indexed | 2024-03-12T01:54:43Z |
| publishDate | 2023-09-01 |
| publisher | The editorial department of Science and Technology of Food Industry |
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| series | Shipin gongye ke-ji |
| spelling | doaj.art-e5419e6ea7c34a33bf5be5aebd53e4152023-09-08T06:41:53ZzhoThe editorial department of Science and Technology of Food IndustryShipin gongye ke-ji1002-03062023-09-014418434910.13386/j.issn1002-0306.20221000972022100097-18Study on the Mechanism of Procyanidins Adsorption onto Chitosan MicroflowerSiyu JIAO0Dingyu XU1Xianchao YAO2Xin LIU3Chunyan LIN4Lixin HE5Rihui LIN6Guangxi Key Laboratory of Chemistry and Engineering of Forest Products, Key Laboratory of Chemistry and Engineering of Forest Products, State Ethnic Affairs Commission, Guangxi Key Laboratory for Polysaccharide Materials and Modification, School of Chemistry and Chemical Engineering, Guangxi Minzu University, Nanning 530006, ChinaGuangxi Key Laboratory of Chemistry and Engineering of Forest Products, Key Laboratory of Chemistry and Engineering of Forest Products, State Ethnic Affairs Commission, Guangxi Key Laboratory for Polysaccharide Materials and Modification, School of Chemistry and Chemical Engineering, Guangxi Minzu University, Nanning 530006, ChinaGuangxi Key Laboratory of Chemistry and Engineering of Forest Products, Key Laboratory of Chemistry and Engineering of Forest Products, State Ethnic Affairs Commission, Guangxi Key Laboratory for Polysaccharide Materials and Modification, School of Chemistry and Chemical Engineering, Guangxi Minzu University, Nanning 530006, ChinaGuangxi Key Laboratory of Chemistry and Engineering of Forest Products, Key Laboratory of Chemistry and Engineering of Forest Products, State Ethnic Affairs Commission, Guangxi Key Laboratory for Polysaccharide Materials and Modification, School of Chemistry and Chemical Engineering, Guangxi Minzu University, Nanning 530006, ChinaGuangxi Key Laboratory of Chemistry and Engineering of Forest Products, Key Laboratory of Chemistry and Engineering of Forest Products, State Ethnic Affairs Commission, Guangxi Key Laboratory for Polysaccharide Materials and Modification, School of Chemistry and Chemical Engineering, Guangxi Minzu University, Nanning 530006, ChinaGuangxi Key Laboratory of Chemistry and Engineering of Forest Products, Key Laboratory of Chemistry and Engineering of Forest Products, State Ethnic Affairs Commission, Guangxi Key Laboratory for Polysaccharide Materials and Modification, School of Chemistry and Chemical Engineering, Guangxi Minzu University, Nanning 530006, ChinaGuangxi Key Laboratory of Chemistry and Engineering of Forest Products, Key Laboratory of Chemistry and Engineering of Forest Products, State Ethnic Affairs Commission, Guangxi Key Laboratory for Polysaccharide Materials and Modification, School of Chemistry and Chemical Engineering, Guangxi Minzu University, Nanning 530006, ChinaIn order to understand the adsorption mechanism of chitosan microflower (CSMF) on procyanidins (PC), CSMF was used as an adsorbent to adsorb PC solutions under different adsorption conditions. The drug-loaded particles were characterized by scanning electron microscopy (SEM), Fourier infrared (FTIR), X-ray diffraction (XRD), etc. Through adsorption kinetics, adsorption isotherm, and adsorption thermodynamics, the mechanism of CSMF adsorption PC was systematically studied. The results showed that the FTIR pattern of the drug-loaded particles produced a new characteristic peak at 1456 cm−1, indicating that the PC was successfully loaded onto the CSMF. The results of SEM and XRD analysis showed that the morphology and crystallinity of CSMF did not change after loading. The adsorption kinetics showed that the adsorption of PC by CSMF conformed to the pseudo-second-order kinetic model, and the adsorption rate was affected by the interaction between particle diffusion and boundary layer diffusion. The adsorption isotherm showed that the Freundlich adsorption isotherm model could more accurately reflect the entire adsorption process, indicating that the adsorption process of CSMF to PC was multilayer adsorption with surface energy inhomogeneity. Finally, adsorption thermodynamics showed that the adsorption of PC by CSMF was a spontaneous physical adsorption process with reduced entropy.http://www.spgykj.com/cn/article/doi/10.13386/j.issn1002-0306.2022100097chitosan microflowerprocyanidinsadsorption kineticsadsorption thermodynamics |
| spellingShingle | Siyu JIAO Dingyu XU Xianchao YAO Xin LIU Chunyan LIN Lixin HE Rihui LIN Study on the Mechanism of Procyanidins Adsorption onto Chitosan Microflower Shipin gongye ke-ji chitosan microflower procyanidins adsorption kinetics adsorption thermodynamics |
| title | Study on the Mechanism of Procyanidins Adsorption onto Chitosan Microflower |
| title_full | Study on the Mechanism of Procyanidins Adsorption onto Chitosan Microflower |
| title_fullStr | Study on the Mechanism of Procyanidins Adsorption onto Chitosan Microflower |
| title_full_unstemmed | Study on the Mechanism of Procyanidins Adsorption onto Chitosan Microflower |
| title_short | Study on the Mechanism of Procyanidins Adsorption onto Chitosan Microflower |
| title_sort | study on the mechanism of procyanidins adsorption onto chitosan microflower |
| topic | chitosan microflower procyanidins adsorption kinetics adsorption thermodynamics |
| url | http://www.spgykj.com/cn/article/doi/10.13386/j.issn1002-0306.2022100097 |
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