Thermoelectric properties of silicon and recycled silicon sawing waste

Large-scale-applicable thermoelectric materials should be both self-sustaining, in order to survive long-term duty cycles, and nonpolluting. Among all classes of known thermoelectric materials, these criteria reduce the available candidate pool, leaving silicon as one of the remaining options. Here...

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Main Authors: Ran He, Wieland Heyn, Felix Thiel, Nicolás Pérez, Christine Damm, Darius Pohl, Bernd Rellinghaus, Christian Reimann, Maximilian Beier, Jochen Friedrich, Hangtian Zhu, Zhifeng Ren, Kornelius Nielsch, Gabi Schierning
Format: Article
Language:English
Published: Elsevier 2019-03-01
Series:Journal of Materiomics
Online Access:http://www.sciencedirect.com/science/article/pii/S2352847818300960
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author Ran He
Wieland Heyn
Felix Thiel
Nicolás Pérez
Christine Damm
Darius Pohl
Bernd Rellinghaus
Christian Reimann
Maximilian Beier
Jochen Friedrich
Hangtian Zhu
Zhifeng Ren
Kornelius Nielsch
Gabi Schierning
author_facet Ran He
Wieland Heyn
Felix Thiel
Nicolás Pérez
Christine Damm
Darius Pohl
Bernd Rellinghaus
Christian Reimann
Maximilian Beier
Jochen Friedrich
Hangtian Zhu
Zhifeng Ren
Kornelius Nielsch
Gabi Schierning
author_sort Ran He
collection DOAJ
description Large-scale-applicable thermoelectric materials should be both self-sustaining, in order to survive long-term duty cycles, and nonpolluting. Among all classes of known thermoelectric materials, these criteria reduce the available candidate pool, leaving silicon as one of the remaining options. Here we first review the thermoelectric properties of various silicon-related materials with respect to their morphologies and microstructures. We then report the thermoelectric properties of silicon sawing wastes recycled from silicon wafer manufacturing. We obtain a high power factor of ∼32 μW cm−1 K−2 at 1273 K with 6% phosphorus substitution in the Si crystal, a value comparable to that of phosphorus-doped silicon-germanium alloys. Our work suggests the large-scale thermoelectric applicability of recycled silicon that would otherwise contribute to the millions of tons of industrial waste produced by the semiconductor industry. Keywords: Silicon, Thermoelectric, Nanostructure, Power factor, Sawing waste
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spelling doaj.art-e55eaeeff9bf4ef38d50c816edf572212023-09-02T21:39:45ZengElsevierJournal of Materiomics2352-84782019-03-01511533Thermoelectric properties of silicon and recycled silicon sawing wasteRan He0Wieland Heyn1Felix Thiel2Nicolás Pérez3Christine Damm4Darius Pohl5Bernd Rellinghaus6Christian Reimann7Maximilian Beier8Jochen Friedrich9Hangtian Zhu10Zhifeng Ren11Kornelius Nielsch12Gabi Schierning13Leibniz-Institut für Festkörper- und Werkstoffforschung Dresden, 01069, Dresden, Germany; Corresponding author.Leibniz-Institut für Festkörper- und Werkstoffforschung Dresden, 01069, Dresden, Germany; Institute of Materials Science, Technische Universität Dresden, 01069, Dresden, GermanyLeibniz-Institut für Festkörper- und Werkstoffforschung Dresden, 01069, Dresden, GermanyLeibniz-Institut für Festkörper- und Werkstoffforschung Dresden, 01069, Dresden, GermanyLeibniz-Institut für Festkörper- und Werkstoffforschung Dresden, 01069, Dresden, GermanyLeibniz-Institut für Festkörper- und Werkstoffforschung Dresden, 01069, Dresden, Germany; Dresden Center for Nanoanalysis, Technische Universität Dresden, 01062, Dresden, GermanyLeibniz-Institut für Festkörper- und Werkstoffforschung Dresden, 01069, Dresden, Germany; Dresden Center for Nanoanalysis, Technische Universität Dresden, 01062, Dresden, GermanyFraunhofer Institut für Integrierte Systeme und Bauelementetechnologie, 91058, Erlangen, GermanyFraunhofer Institut für Integrierte Systeme und Bauelementetechnologie, 91058, Erlangen, GermanyFraunhofer Institut für Integrierte Systeme und Bauelementetechnologie, 91058, Erlangen, GermanyDepartment of Physics and TcSUH, University of Houston, Houston, TX, 77204, USADepartment of Physics and TcSUH, University of Houston, Houston, TX, 77204, USALeibniz-Institut für Festkörper- und Werkstoffforschung Dresden, 01069, Dresden, Germany; Institute of Materials Science, Technische Universität Dresden, 01069, Dresden, GermanyLeibniz-Institut für Festkörper- und Werkstoffforschung Dresden, 01069, Dresden, Germany; Corresponding author.Large-scale-applicable thermoelectric materials should be both self-sustaining, in order to survive long-term duty cycles, and nonpolluting. Among all classes of known thermoelectric materials, these criteria reduce the available candidate pool, leaving silicon as one of the remaining options. Here we first review the thermoelectric properties of various silicon-related materials with respect to their morphologies and microstructures. We then report the thermoelectric properties of silicon sawing wastes recycled from silicon wafer manufacturing. We obtain a high power factor of ∼32 μW cm−1 K−2 at 1273 K with 6% phosphorus substitution in the Si crystal, a value comparable to that of phosphorus-doped silicon-germanium alloys. Our work suggests the large-scale thermoelectric applicability of recycled silicon that would otherwise contribute to the millions of tons of industrial waste produced by the semiconductor industry. Keywords: Silicon, Thermoelectric, Nanostructure, Power factor, Sawing wastehttp://www.sciencedirect.com/science/article/pii/S2352847818300960
spellingShingle Ran He
Wieland Heyn
Felix Thiel
Nicolás Pérez
Christine Damm
Darius Pohl
Bernd Rellinghaus
Christian Reimann
Maximilian Beier
Jochen Friedrich
Hangtian Zhu
Zhifeng Ren
Kornelius Nielsch
Gabi Schierning
Thermoelectric properties of silicon and recycled silicon sawing waste
Journal of Materiomics
title Thermoelectric properties of silicon and recycled silicon sawing waste
title_full Thermoelectric properties of silicon and recycled silicon sawing waste
title_fullStr Thermoelectric properties of silicon and recycled silicon sawing waste
title_full_unstemmed Thermoelectric properties of silicon and recycled silicon sawing waste
title_short Thermoelectric properties of silicon and recycled silicon sawing waste
title_sort thermoelectric properties of silicon and recycled silicon sawing waste
url http://www.sciencedirect.com/science/article/pii/S2352847818300960
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