Electrodeposition and Characterization of Nanocrystalline Nickel- Molybdenum Alloy

In this study, Ni-Mo nanocrystalline alloys were prepared on steel substrates by electrodeposition method from citrate-ammonia bath by applying current densities 30, 60 and 100 mA/cm2. Results indicated that the obtained coatings were uniform and compact. Moreover, molybdenum content in the alloy an...

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Main Authors: V. Rajaei, K. Raeissi, M. Shamanian, H. Rashtchi
Format: Article
Language:fas
Published: Isfahan University of Technology 2016-06-01
Series:Journal of Advanced Materials in Engineering
Subjects:
Online Access:http://jame.iut.ac.ir/article-1-787-en.html
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author V. Rajaei
K. Raeissi
M. Shamanian
H. Rashtchi
author_facet V. Rajaei
K. Raeissi
M. Shamanian
H. Rashtchi
author_sort V. Rajaei
collection DOAJ
description In this study, Ni-Mo nanocrystalline alloys were prepared on steel substrates by electrodeposition method from citrate-ammonia bath by applying current densities 30, 60 and 100 mA/cm2. Results indicated that the obtained coatings were uniform and compact. Moreover, molybdenum content in the alloy and current efficiency decreased with increasing electrodeposition current density. X-ray diffraction analyses indicated that all coatings were composed of face-centered cubic solid solution of molybdenum in nickel with grain size of 9-5 nanometer. Moreover, the most intensive plane in X-ray diffragtogram was (111). On the othe hand, roughness measurements indicated that surface roughness escalated with increasing current density. Corrosion behavior study showed decrease in corrosion current density of substrate with applying Ni-Mo alloy coatings. In addition, corrosion current density reduced with increasing molybdenum content of the coating and the minimum amount was related to the coating with 13 atomic percent molybdenum.
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spelling doaj.art-e5738f07e74a415f8a0a33071956d35d2022-12-21T23:26:51ZfasIsfahan University of TechnologyJournal of Advanced Materials in Engineering2251-600X2423-57332016-06-013517181Electrodeposition and Characterization of Nanocrystalline Nickel- Molybdenum AlloyV. Rajaei0K. Raeissi1M. Shamanian2H. Rashtchi3 Department of Materials Engineering, Isfahan University of Technology, Isfahan, Iran Department of Materials Engineering, Isfahan University of Technology, Isfahan, Iran Department of Materials Engineering, Isfahan University of Technology, Isfahan, Iran Department of Materials Engineering, Isfahan University of Technology, Isfahan, Iran In this study, Ni-Mo nanocrystalline alloys were prepared on steel substrates by electrodeposition method from citrate-ammonia bath by applying current densities 30, 60 and 100 mA/cm2. Results indicated that the obtained coatings were uniform and compact. Moreover, molybdenum content in the alloy and current efficiency decreased with increasing electrodeposition current density. X-ray diffraction analyses indicated that all coatings were composed of face-centered cubic solid solution of molybdenum in nickel with grain size of 9-5 nanometer. Moreover, the most intensive plane in X-ray diffragtogram was (111). On the othe hand, roughness measurements indicated that surface roughness escalated with increasing current density. Corrosion behavior study showed decrease in corrosion current density of substrate with applying Ni-Mo alloy coatings. In addition, corrosion current density reduced with increasing molybdenum content of the coating and the minimum amount was related to the coating with 13 atomic percent molybdenum.http://jame.iut.ac.ir/article-1-787-en.htmlnickel- molybdenum alloyelectrodepositionmorphologycurrent density
spellingShingle V. Rajaei
K. Raeissi
M. Shamanian
H. Rashtchi
Electrodeposition and Characterization of Nanocrystalline Nickel- Molybdenum Alloy
Journal of Advanced Materials in Engineering
nickel- molybdenum alloy
electrodeposition
morphology
current density
title Electrodeposition and Characterization of Nanocrystalline Nickel- Molybdenum Alloy
title_full Electrodeposition and Characterization of Nanocrystalline Nickel- Molybdenum Alloy
title_fullStr Electrodeposition and Characterization of Nanocrystalline Nickel- Molybdenum Alloy
title_full_unstemmed Electrodeposition and Characterization of Nanocrystalline Nickel- Molybdenum Alloy
title_short Electrodeposition and Characterization of Nanocrystalline Nickel- Molybdenum Alloy
title_sort electrodeposition and characterization of nanocrystalline nickel molybdenum alloy
topic nickel- molybdenum alloy
electrodeposition
morphology
current density
url http://jame.iut.ac.ir/article-1-787-en.html
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AT kraeissi electrodepositionandcharacterizationofnanocrystallinenickelmolybdenumalloy
AT mshamanian electrodepositionandcharacterizationofnanocrystallinenickelmolybdenumalloy
AT hrashtchi electrodepositionandcharacterizationofnanocrystallinenickelmolybdenumalloy