Espectroscopia Mössbauer na caracterização de compostos ferrosos em solos e sua relação com retenção de fósforo Mössbauer spectroscopy in the characterization of ferrous compounds in soils and its relationship with phosphorus retention

<abstract language="eng">The chemical role of iron-bearing compounds on the dynamics of phosphorus in selected Brazilian latosols was investigated. The iron oxides were characterized in an attempt to assess their main chemical-mineralogical properties influencing the ion sorption mec...

Full description

Bibliographic Details
Main Authors: Nilton Curi, Paulo Emilio Ferreira da Motta, José Domingos Fabris, Luiz Carlos Alves de Oliveira
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2008-01-01
Series:Química Nova
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422008000600035
_version_ 1818611574477160448
author Nilton Curi
Paulo Emilio Ferreira da Motta
José Domingos Fabris
Luiz Carlos Alves de Oliveira
author_facet Nilton Curi
Paulo Emilio Ferreira da Motta
José Domingos Fabris
Luiz Carlos Alves de Oliveira
author_sort Nilton Curi
collection DOAJ
description <abstract language="eng">The chemical role of iron-bearing compounds on the dynamics of phosphorus in selected Brazilian latosols was investigated. The iron oxides were characterized in an attempt to assess their main chemical-mineralogical properties influencing the ion sorption mechanisms in those pedosystems. It was found that increasing total iron contents tend to increase the phosphorus adsorption capacity in the selected soils. 110 K-Mössbauer data reveal that the dominant iron oxides are hematite and goethite. Particularly for the yellower soil samples some prominent doublets, more certainly due to superparamagnetic relaxation, may be assigned to corresponding fractions of relatively small-sized particles.
first_indexed 2024-12-16T15:32:30Z
format Article
id doaj.art-e59f4551a7664d1188c0083ebd05ee64
institution Directory Open Access Journal
issn 0100-4042
1678-7064
language English
last_indexed 2024-12-16T15:32:30Z
publishDate 2008-01-01
publisher Sociedade Brasileira de Química
record_format Article
series Química Nova
spelling doaj.art-e59f4551a7664d1188c0083ebd05ee642022-12-21T22:26:18ZengSociedade Brasileira de QuímicaQuímica Nova0100-40421678-70642008-01-013161467147110.1590/S0100-40422008000600035Espectroscopia Mössbauer na caracterização de compostos ferrosos em solos e sua relação com retenção de fósforo Mössbauer spectroscopy in the characterization of ferrous compounds in soils and its relationship with phosphorus retentionNilton CuriPaulo Emilio Ferreira da MottaJosé Domingos FabrisLuiz Carlos Alves de Oliveira<abstract language="eng">The chemical role of iron-bearing compounds on the dynamics of phosphorus in selected Brazilian latosols was investigated. The iron oxides were characterized in an attempt to assess their main chemical-mineralogical properties influencing the ion sorption mechanisms in those pedosystems. It was found that increasing total iron contents tend to increase the phosphorus adsorption capacity in the selected soils. 110 K-Mössbauer data reveal that the dominant iron oxides are hematite and goethite. Particularly for the yellower soil samples some prominent doublets, more certainly due to superparamagnetic relaxation, may be assigned to corresponding fractions of relatively small-sized particles.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422008000600035iron oxidesphosphorus sorptionMössbauer spectroscopy
spellingShingle Nilton Curi
Paulo Emilio Ferreira da Motta
José Domingos Fabris
Luiz Carlos Alves de Oliveira
Espectroscopia Mössbauer na caracterização de compostos ferrosos em solos e sua relação com retenção de fósforo Mössbauer spectroscopy in the characterization of ferrous compounds in soils and its relationship with phosphorus retention
Química Nova
iron oxides
phosphorus sorption
Mössbauer spectroscopy
title Espectroscopia Mössbauer na caracterização de compostos ferrosos em solos e sua relação com retenção de fósforo Mössbauer spectroscopy in the characterization of ferrous compounds in soils and its relationship with phosphorus retention
title_full Espectroscopia Mössbauer na caracterização de compostos ferrosos em solos e sua relação com retenção de fósforo Mössbauer spectroscopy in the characterization of ferrous compounds in soils and its relationship with phosphorus retention
title_fullStr Espectroscopia Mössbauer na caracterização de compostos ferrosos em solos e sua relação com retenção de fósforo Mössbauer spectroscopy in the characterization of ferrous compounds in soils and its relationship with phosphorus retention
title_full_unstemmed Espectroscopia Mössbauer na caracterização de compostos ferrosos em solos e sua relação com retenção de fósforo Mössbauer spectroscopy in the characterization of ferrous compounds in soils and its relationship with phosphorus retention
title_short Espectroscopia Mössbauer na caracterização de compostos ferrosos em solos e sua relação com retenção de fósforo Mössbauer spectroscopy in the characterization of ferrous compounds in soils and its relationship with phosphorus retention
title_sort espectroscopia mossbauer na caracterizacao de compostos ferrosos em solos e sua relacao com retencao de fosforo mossbauer spectroscopy in the characterization of ferrous compounds in soils and its relationship with phosphorus retention
topic iron oxides
phosphorus sorption
Mössbauer spectroscopy
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422008000600035
work_keys_str_mv AT niltoncuri espectroscopiamossbauernacaracterizacaodecompostosferrososemsolosesuarelacaocomretencaodefosforomossbauerspectroscopyinthecharacterizationofferrouscompoundsinsoilsanditsrelationshipwithphosphorusretention
AT pauloemilioferreiradamotta espectroscopiamossbauernacaracterizacaodecompostosferrososemsolosesuarelacaocomretencaodefosforomossbauerspectroscopyinthecharacterizationofferrouscompoundsinsoilsanditsrelationshipwithphosphorusretention
AT josedomingosfabris espectroscopiamossbauernacaracterizacaodecompostosferrososemsolosesuarelacaocomretencaodefosforomossbauerspectroscopyinthecharacterizationofferrouscompoundsinsoilsanditsrelationshipwithphosphorusretention
AT luizcarlosalvesdeoliveira espectroscopiamossbauernacaracterizacaodecompostosferrososemsolosesuarelacaocomretencaodefosforomossbauerspectroscopyinthecharacterizationofferrouscompoundsinsoilsanditsrelationshipwithphosphorusretention