Preparation and characterization of HMX/NH2-GO composite with enhanced thermal safety and desensitization

To improve the safety of HMX, HMX/NH2-GO composite was prepared with aqueous ammonia functionalized graphene oxide (NH2-GO). The composite was characterized by SEM, Zeta potential, XPS, Raman spectrum, XRD, HPLC, DSC and BAM sensitivity test. The results indicated that the functionalization with aqu...

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Bibliographic Details
Main Authors: Yu-lan Song, Qi Huang, Bo Jin, Ru-fang Peng
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2022-11-01
Series:Defence Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2214914721001124
Description
Summary:To improve the safety of HMX, HMX/NH2-GO composite was prepared with aqueous ammonia functionalized graphene oxide (NH2-GO). The composite was characterized by SEM, Zeta potential, XPS, Raman spectrum, XRD, HPLC, DSC and BAM sensitivity test. The results indicated that the functionalization with aqueous ammonia can enhance the interaction between GO and HMX, and more efficiently desensitize the explosive. The optimal impact sensitivity of the HMX/NH2-GO composite can be not less than 40 J, which is also the most insensitivity compared to the previous reports prepared by coating desensitization with non-energetic desensitized material. Moreover, the potential reason for the different impact and friction sensitivity was also discussed, which may bring a novel perspective to achieve the desensitization of energetic material.
ISSN:2214-9147