Clickable Polymers Accessible through Nucleophilic Substitution on Polysaccharides: A Sophisticated Route to Functional Polymers
This review article is dedicated to special polysaccharide esters – the polysaccharide toluenesulfonic acid esters (tosylates) and polysaccharide carbonate esters. After describing the specifics of the synthesis, particular emphasis is placed on the use of polysaccharide tosylates and polysaccharide...
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| Format: | Article |
| Language: | English |
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North Carolina State University
2022-11-01
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| Series: | BioResources |
| Subjects: | |
| Online Access: | https://ojs.cnr.ncsu.edu/index.php/BRJ/article/view/22153 |
| _version_ | 1797794874201735168 |
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| author | Agnes Kemmer Haisong Qi Thomas Heinze |
| author_facet | Agnes Kemmer Haisong Qi Thomas Heinze |
| author_sort | Agnes Kemmer |
| collection | DOAJ |
| description | This review article is dedicated to special polysaccharide esters – the polysaccharide toluenesulfonic acid esters (tosylates) and polysaccharide carbonate esters. After describing the specifics of the synthesis, particular emphasis is placed on the use of polysaccharide tosylates and polysaccharide phenyl carbonates for subsequent modification by nucleophilic substitution (SN) reactions. For this purpose, the advantages and limitations of the respective derivatives are discussed with regard to their application in chemical modification with nucleophiles containing functional groups. A few functional polysaccharide derivatives and their properties are presented. Finally, reactive derivatives for click chemistry approaches are featured. These can be prepared starting from the reactive intermediate of either polysaccharide tosylate or polysaccharide phenyl carbonate. |
| first_indexed | 2024-03-13T03:09:19Z |
| format | Article |
| id | doaj.art-e5c0c1699f744daa84133f732b8d909f |
| institution | Directory Open Access Journal |
| issn | 1930-2126 |
| language | English |
| last_indexed | 2024-03-13T03:09:19Z |
| publishDate | 2022-11-01 |
| publisher | North Carolina State University |
| record_format | Article |
| series | BioResources |
| spelling | doaj.art-e5c0c1699f744daa84133f732b8d909f2023-06-26T18:15:10ZengNorth Carolina State UniversityBioResources1930-21262022-11-0117472677284155Clickable Polymers Accessible through Nucleophilic Substitution on Polysaccharides: A Sophisticated Route to Functional PolymersAgnes Kemmer0Haisong Qi1Thomas Heinze2Friedrich-Schiller-University JenaSouth China University of TechnologyFriedrich-Schiller-University JenaThis review article is dedicated to special polysaccharide esters – the polysaccharide toluenesulfonic acid esters (tosylates) and polysaccharide carbonate esters. After describing the specifics of the synthesis, particular emphasis is placed on the use of polysaccharide tosylates and polysaccharide phenyl carbonates for subsequent modification by nucleophilic substitution (SN) reactions. For this purpose, the advantages and limitations of the respective derivatives are discussed with regard to their application in chemical modification with nucleophiles containing functional groups. A few functional polysaccharide derivatives and their properties are presented. Finally, reactive derivatives for click chemistry approaches are featured. These can be prepared starting from the reactive intermediate of either polysaccharide tosylate or polysaccharide phenyl carbonate.https://ojs.cnr.ncsu.edu/index.php/BRJ/article/view/22153polysaccharide tosylatepolysaccharide phenyl carbonatenucleophilic substitutionreactive polysaccharideclick chemistry |
| spellingShingle | Agnes Kemmer Haisong Qi Thomas Heinze Clickable Polymers Accessible through Nucleophilic Substitution on Polysaccharides: A Sophisticated Route to Functional Polymers BioResources polysaccharide tosylate polysaccharide phenyl carbonate nucleophilic substitution reactive polysaccharide click chemistry |
| title | Clickable Polymers Accessible through Nucleophilic Substitution on Polysaccharides: A Sophisticated Route to Functional Polymers |
| title_full | Clickable Polymers Accessible through Nucleophilic Substitution on Polysaccharides: A Sophisticated Route to Functional Polymers |
| title_fullStr | Clickable Polymers Accessible through Nucleophilic Substitution on Polysaccharides: A Sophisticated Route to Functional Polymers |
| title_full_unstemmed | Clickable Polymers Accessible through Nucleophilic Substitution on Polysaccharides: A Sophisticated Route to Functional Polymers |
| title_short | Clickable Polymers Accessible through Nucleophilic Substitution on Polysaccharides: A Sophisticated Route to Functional Polymers |
| title_sort | clickable polymers accessible through nucleophilic substitution on polysaccharides a sophisticated route to functional polymers |
| topic | polysaccharide tosylate polysaccharide phenyl carbonate nucleophilic substitution reactive polysaccharide click chemistry |
| url | https://ojs.cnr.ncsu.edu/index.php/BRJ/article/view/22153 |
| work_keys_str_mv | AT agneskemmer clickablepolymersaccessiblethroughnucleophilicsubstitutiononpolysaccharidesasophisticatedroutetofunctionalpolymers AT haisongqi clickablepolymersaccessiblethroughnucleophilicsubstitutiononpolysaccharidesasophisticatedroutetofunctionalpolymers AT thomasheinze clickablepolymersaccessiblethroughnucleophilicsubstitutiononpolysaccharidesasophisticatedroutetofunctionalpolymers |