Structural and optical properties of TiO2:NiO nanoparticles thin films prepare by chemical spray pyrolysis

The properties of structural and optical of pure and doped nano titanium dioxide (TiO2) films, prepared using chemical spray pyrolysis (CPS) technique, with different nanosize nickel oxide (NiO) concentrations in the range (3-9)wt% have been studied. X-Ray diffraction (XRD) technique where using to...

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Main Authors: Wasan A. Al-Taa'y, Bushra A. Hasan
Format: Article
Language:English
Published: University of Baghdad 2021-06-01
Series:Iraqi Journal of Physics
Subjects:
Online Access:https://ijp.uobaghdad.edu.iq/index.php/physics/article/view/632
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author Wasan A. Al-Taa'y
Bushra A. Hasan
author_facet Wasan A. Al-Taa'y
Bushra A. Hasan
author_sort Wasan A. Al-Taa'y
collection DOAJ
description The properties of structural and optical of pure and doped nano titanium dioxide (TiO2) films, prepared using chemical spray pyrolysis (CPS) technique, with different nanosize nickel oxide (NiO) concentrations in the range (3-9)wt% have been studied. X-Ray diffraction (XRD) technique where using to analysis the structure properties of the prepared thin films. The results revealed that the structure properties of TiO2 have polycrystalline structure with anatase phase. The parameters, energy gap, extinction coefficient, refractive index, real and imaginary parts were studied using absorbance and transmittance measurements from a computerized ultraviolet visible spectrophotometer (Shimadzu UV-1601 PC) in the wavelengths range (300-800)nm. Optical properties of TiO2 affected by the adding of NiO impurity where the transmittance increased as NiO concentration increased but with more adding the transmittance returned to decrease again. It was found the extinction coefficient, refractive index, real and imaginary parts values decreased with increasing doping percentage up to 7% and then increases occur one more again at 9%. Energy gap values increased after doping with NiO where the values lies in the range was 3.31 to 3.51 eV .
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spelling doaj.art-e5ddc858dd1747939d56ad59cb6b310b2023-03-10T20:53:05ZengUniversity of BaghdadIraqi Journal of Physics2070-40032664-55482021-06-01194910.30723/ijp.v19i49.632Structural and optical properties of TiO2:NiO nanoparticles thin films prepare by chemical spray pyrolysisWasan A. Al-Taa'y0Bushra A. Hasan1Department of Physics, College of Science, AL-Nahrain UniversityDepartment of Physics, College of Science, University of Baghdad The properties of structural and optical of pure and doped nano titanium dioxide (TiO2) films, prepared using chemical spray pyrolysis (CPS) technique, with different nanosize nickel oxide (NiO) concentrations in the range (3-9)wt% have been studied. X-Ray diffraction (XRD) technique where using to analysis the structure properties of the prepared thin films. The results revealed that the structure properties of TiO2 have polycrystalline structure with anatase phase. The parameters, energy gap, extinction coefficient, refractive index, real and imaginary parts were studied using absorbance and transmittance measurements from a computerized ultraviolet visible spectrophotometer (Shimadzu UV-1601 PC) in the wavelengths range (300-800)nm. Optical properties of TiO2 affected by the adding of NiO impurity where the transmittance increased as NiO concentration increased but with more adding the transmittance returned to decrease again. It was found the extinction coefficient, refractive index, real and imaginary parts values decreased with increasing doping percentage up to 7% and then increases occur one more again at 9%. Energy gap values increased after doping with NiO where the values lies in the range was 3.31 to 3.51 eV . https://ijp.uobaghdad.edu.iq/index.php/physics/article/view/632TiO2 metal oxide, NiO nickle oxide, structure and Optical properties.
spellingShingle Wasan A. Al-Taa'y
Bushra A. Hasan
Structural and optical properties of TiO2:NiO nanoparticles thin films prepare by chemical spray pyrolysis
Iraqi Journal of Physics
TiO2 metal oxide, NiO nickle oxide, structure and Optical properties.
title Structural and optical properties of TiO2:NiO nanoparticles thin films prepare by chemical spray pyrolysis
title_full Structural and optical properties of TiO2:NiO nanoparticles thin films prepare by chemical spray pyrolysis
title_fullStr Structural and optical properties of TiO2:NiO nanoparticles thin films prepare by chemical spray pyrolysis
title_full_unstemmed Structural and optical properties of TiO2:NiO nanoparticles thin films prepare by chemical spray pyrolysis
title_short Structural and optical properties of TiO2:NiO nanoparticles thin films prepare by chemical spray pyrolysis
title_sort structural and optical properties of tio2 nio nanoparticles thin films prepare by chemical spray pyrolysis
topic TiO2 metal oxide, NiO nickle oxide, structure and Optical properties.
url https://ijp.uobaghdad.edu.iq/index.php/physics/article/view/632
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