The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings
The furan heterocycle is a dienic reagent particularly suitable for the Diels-Alder reaction and maleimides represent a typical family of complementary reagents because of their strong dienophilic character. This paper reviews critically the studies devoted to the exploitation of the Diels Alder rea...
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| Format: | Article |
| Language: | English |
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Associação Brasileira de Polímeros
2005-06-01
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| Series: | Polímeros |
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| Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282005000200007 |
| _version_ | 1818236710790627328 |
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| author | Alessandro Gandini |
| author_facet | Alessandro Gandini |
| author_sort | Alessandro Gandini |
| collection | DOAJ |
| description | The furan heterocycle is a dienic reagent particularly suitable for the Diels-Alder reaction and maleimides represent a typical family of complementary reagents because of their strong dienophilic character. This paper reviews critically the studies devoted to the exploitation of the Diels Alder reaction between those moieties to synthesise macromolecular materials possessing different structures and properties. The most relevant approaches in this field are (i) polycondensation reactions calling upon A-A and B-B monomers and (ii) reversible cross-linking of linear polymers bearing pendant furan or maleimide moieties, based on the temperature sensitivity of the Diels-Alder equilibrium. |
| first_indexed | 2024-12-12T12:14:12Z |
| format | Article |
| id | doaj.art-e5ffd526e4fa4542906a425bbbe8fde9 |
| institution | Directory Open Access Journal |
| issn | 0104-1428 1678-5169 |
| language | English |
| last_indexed | 2024-12-12T12:14:12Z |
| publishDate | 2005-06-01 |
| publisher | Associação Brasileira de Polímeros |
| record_format | Article |
| series | Polímeros |
| spelling | doaj.art-e5ffd526e4fa4542906a425bbbe8fde92022-12-22T00:24:48ZengAssociação Brasileira de PolímerosPolímeros0104-14281678-51692005-06-011529510110.1590/S0104-14282005000200007The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplingsAlessandro GandiniThe furan heterocycle is a dienic reagent particularly suitable for the Diels-Alder reaction and maleimides represent a typical family of complementary reagents because of their strong dienophilic character. This paper reviews critically the studies devoted to the exploitation of the Diels Alder reaction between those moieties to synthesise macromolecular materials possessing different structures and properties. The most relevant approaches in this field are (i) polycondensation reactions calling upon A-A and B-B monomers and (ii) reversible cross-linking of linear polymers bearing pendant furan or maleimide moieties, based on the temperature sensitivity of the Diels-Alder equilibrium.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282005000200007Diels-Alder reactionfuran polymersmaleimidespolycondensationreversible cross-linking |
| spellingShingle | Alessandro Gandini The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings Polímeros Diels-Alder reaction furan polymers maleimides polycondensation reversible cross-linking |
| title | The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings |
| title_full | The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings |
| title_fullStr | The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings |
| title_full_unstemmed | The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings |
| title_short | The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings |
| title_sort | application of the diels alder reaction to polymer syntheses based on furan maleimide reversible couplings |
| topic | Diels-Alder reaction furan polymers maleimides polycondensation reversible cross-linking |
| url | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282005000200007 |
| work_keys_str_mv | AT alessandrogandini theapplicationofthedielsalderreactiontopolymersynthesesbasedonfuranmaleimidereversiblecouplings AT alessandrogandini applicationofthedielsalderreactiontopolymersynthesesbasedonfuranmaleimidereversiblecouplings |