Preparation, characterization and thermophysical properties investigation of A70/polyaniline nanocomposite phase change material for medium temperature solar applications

The ever-present demand for energy from various application in industrial and domestic processes has led to the consumption of fossil fuel at a rapid rate with adverse effect due to global warming. This study focuses on the thermal energy storage aspect intended for medium temperature applications....

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Main Authors: A.K. Pandey, Mathew George, Nasrudin Abd Rahim, V.V. Tyagi, Syed Shahabuddin, R. Saidur
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2021-06-01
Series:Energy and Built Environment
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666123320300891
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author A.K. Pandey
Mathew George
Nasrudin Abd Rahim
V.V. Tyagi
Syed Shahabuddin
R. Saidur
author_facet A.K. Pandey
Mathew George
Nasrudin Abd Rahim
V.V. Tyagi
Syed Shahabuddin
R. Saidur
author_sort A.K. Pandey
collection DOAJ
description The ever-present demand for energy from various application in industrial and domestic processes has led to the consumption of fossil fuel at a rapid rate with adverse effect due to global warming. This study focuses on the thermal energy storage aspect intended for medium temperature applications. A novel composite A70 and PANI was prepared and characterized. The study investigates the composites thermophysical and optical properties. Differential Scanning Calorimetry and Transient Hot Bridge measured thermal storage capacity and thermal conductivity of the composite, respectively. The heat storage capacity of the composite remained stable within 4% whereas a highest rise of 11.96% in thermal conductivity was measured. The composites thermal, chemical, and physical stability were analysed from Thermogravimetric Analyser, Fourier Infrared Transform, and Scanning Electron Microscope, respectively. The composites were thermally stable up to a temperature of 250 °C. No chemical reaction occurred between the nanomaterial and base PCM matrix. The microscopic visuals did not show any considerable change in the microscopic structure of the material. In the case of optical properties, the composites showed significant reduction in transmittance of solar spectrum with respect to pure A70. The maximum decrement in transmission was around ~89% compared to A70. As the composite prepared were thermally stable till 250 °C, hence may be utilized for solar thermal and low concentrated photovoltaic application but not limited to these.
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spelling doaj.art-e606f0e6004643c4ad0e70ec06e47c352022-12-21T19:37:15ZengKeAi Communications Co., Ltd.Energy and Built Environment2666-12332021-06-0123271277Preparation, characterization and thermophysical properties investigation of A70/polyaniline nanocomposite phase change material for medium temperature solar applicationsA.K. Pandey0Mathew George1Nasrudin Abd Rahim2V.V. Tyagi3Syed Shahabuddin4R. Saidur5Research Centre for Nano-Materials and Energy Technology (RCNMET), School of Science and Technology, Sunway University, No. 5, Jalan Universiti, Bandar Sunway, Petaling Jaya, 47500 Selangor Darul Ehsan, Malaysia; Corresponding author at: Research Centre for Nano-Materials and Energy Technology (RCNMET), School of Science and Technology, Sunway University, No. 5, Jalan Universiti, Bandar Sunway, Petaling Jaya, 47500 Selangor Darul Ehsan, Malaysia.Higher Institution Centre of Excellence (HICoE), UM Power Energy Dedicated Advanced Centre (UMPEDAC), Level 4, Wisma R&D, University of Malaya, Jalan Pantai Baharu, 59990 Kuala Lumpur, MalaysiaHigher Institution Centre of Excellence (HICoE), UM Power Energy Dedicated Advanced Centre (UMPEDAC), Level 4, Wisma R&D, University of Malaya, Jalan Pantai Baharu, 59990 Kuala Lumpur, Malaysia; Renewable Energy Research Group, King Abdulaziz University, Jeddah 21589, Saudi Arabia; Corresponding author at: Higher Institution Centre of Excellence (HICoE), UM Power Energy Dedicated Advanced Centre (UMPEDAC), Level 4, Wisma R&D, University of Malaya, Jalan Pantai Baharu, 59990 Kuala Lumpur, Malaysia.School of Energy Management, Shri Mata Vaishno Devi University, Katra 182320, (J&K), IndiaDepartment of Science, School of Technology, Pandit Deendayal Petroleum University, Knowledge Corridor, Raisan Village, Gandhinagar 382007, Gujrat, IndiaResearch Centre for Nano-Materials and Energy Technology (RCNMET), School of Science and Technology, Sunway University, No. 5, Jalan Universiti, Bandar Sunway, Petaling Jaya, 47500 Selangor Darul Ehsan, MalaysiaThe ever-present demand for energy from various application in industrial and domestic processes has led to the consumption of fossil fuel at a rapid rate with adverse effect due to global warming. This study focuses on the thermal energy storage aspect intended for medium temperature applications. A novel composite A70 and PANI was prepared and characterized. The study investigates the composites thermophysical and optical properties. Differential Scanning Calorimetry and Transient Hot Bridge measured thermal storage capacity and thermal conductivity of the composite, respectively. The heat storage capacity of the composite remained stable within 4% whereas a highest rise of 11.96% in thermal conductivity was measured. The composites thermal, chemical, and physical stability were analysed from Thermogravimetric Analyser, Fourier Infrared Transform, and Scanning Electron Microscope, respectively. The composites were thermally stable up to a temperature of 250 °C. No chemical reaction occurred between the nanomaterial and base PCM matrix. The microscopic visuals did not show any considerable change in the microscopic structure of the material. In the case of optical properties, the composites showed significant reduction in transmittance of solar spectrum with respect to pure A70. The maximum decrement in transmission was around ~89% compared to A70. As the composite prepared were thermally stable till 250 °C, hence may be utilized for solar thermal and low concentrated photovoltaic application but not limited to these.http://www.sciencedirect.com/science/article/pii/S2666123320300891Phase change materialsSolar energyThermal conductivityLatent heatPolyaniline
spellingShingle A.K. Pandey
Mathew George
Nasrudin Abd Rahim
V.V. Tyagi
Syed Shahabuddin
R. Saidur
Preparation, characterization and thermophysical properties investigation of A70/polyaniline nanocomposite phase change material for medium temperature solar applications
Energy and Built Environment
Phase change materials
Solar energy
Thermal conductivity
Latent heat
Polyaniline
title Preparation, characterization and thermophysical properties investigation of A70/polyaniline nanocomposite phase change material for medium temperature solar applications
title_full Preparation, characterization and thermophysical properties investigation of A70/polyaniline nanocomposite phase change material for medium temperature solar applications
title_fullStr Preparation, characterization and thermophysical properties investigation of A70/polyaniline nanocomposite phase change material for medium temperature solar applications
title_full_unstemmed Preparation, characterization and thermophysical properties investigation of A70/polyaniline nanocomposite phase change material for medium temperature solar applications
title_short Preparation, characterization and thermophysical properties investigation of A70/polyaniline nanocomposite phase change material for medium temperature solar applications
title_sort preparation characterization and thermophysical properties investigation of a70 polyaniline nanocomposite phase change material for medium temperature solar applications
topic Phase change materials
Solar energy
Thermal conductivity
Latent heat
Polyaniline
url http://www.sciencedirect.com/science/article/pii/S2666123320300891
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