Preparation and Wave-absorbing Performance of Retinyl Schiff Base Salts Coordinated with Rare Earth La<sup>3+</sup> and Ce<sup>3+</sup> Ions
With vitamin A acetate as raw material, ethylenediamine retinyl Schiff base salts coordinated with rare earth ion La<sup>3+</sup>, Ce<sup>3+</sup> were synthesized, and the structure of the products was characterized by FT-IR and Raman spectra. The electromagnetic parameters...
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Language: | zho |
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Journal of Aeronautical Materials
2018-04-01
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Series: | Journal of Aeronautical Materials |
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Online Access: | http://html.rhhz.net/CHXB/html/2018-2-104.htm |
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author | LIU Huteng ZHOU Kesheng DENG Lianwen LIU Sheng HE Longhui YAO Lingling |
author_facet | LIU Huteng ZHOU Kesheng DENG Lianwen LIU Sheng HE Longhui YAO Lingling |
author_sort | LIU Huteng |
collection | DOAJ |
description | With vitamin A acetate as raw material, ethylenediamine retinyl Schiff base salts coordinated with rare earth ion La<sup>3+</sup>, Ce<sup>3+</sup> were synthesized, and the structure of the products was characterized by FT-IR and Raman spectra. The electromagnetic parameters in the frequency range of 2-18 GHz were measured by microwave vector network analyzer, its reflectivity was calculated, and the main factors and mechanism that affect the wave-absorbing performance of rare retinyl Schiff base salts were discussed. The results show that the coordination bond is formed by the rare earth ions and Schiff base. The reflectivity of Schiff base coordinated with La<sup>3+</sup> ion is –16 dB at 12.9 GHz (bandwidth with reflectivity better than –10 dB is 3.1 GHz), the reflectivity of Schiff base coordinated with Ce<sup>3+</sup> ion is –18.8 dB at 12.7 GHz (bandwidth with reflectivity better than –10 dB is 3.4 GHz). Microwave absorption performances of the both are superior to the wave-absorbing performance of Schiff base coordinated with non-rare earth ions. |
first_indexed | 2024-12-12T16:49:35Z |
format | Article |
id | doaj.art-e60debb7fc954c37a5e829ada7bef4a8 |
institution | Directory Open Access Journal |
issn | 1005-5053 1005-5053 |
language | zho |
last_indexed | 2024-12-12T16:49:35Z |
publishDate | 2018-04-01 |
publisher | Journal of Aeronautical Materials |
record_format | Article |
series | Journal of Aeronautical Materials |
spelling | doaj.art-e60debb7fc954c37a5e829ada7bef4a82022-12-22T00:18:23ZzhoJournal of Aeronautical MaterialsJournal of Aeronautical Materials1005-50531005-50532018-04-0138210410910.11868/j.issn.1005-5053.2017.000001201802000001Preparation and Wave-absorbing Performance of Retinyl Schiff Base Salts Coordinated with Rare Earth La<sup>3+</sup> and Ce<sup>3+</sup> IonsLIU HutengZHOU KeshengDENG LianwenLIU ShengHE LonghuiYAO LinglingWith vitamin A acetate as raw material, ethylenediamine retinyl Schiff base salts coordinated with rare earth ion La<sup>3+</sup>, Ce<sup>3+</sup> were synthesized, and the structure of the products was characterized by FT-IR and Raman spectra. The electromagnetic parameters in the frequency range of 2-18 GHz were measured by microwave vector network analyzer, its reflectivity was calculated, and the main factors and mechanism that affect the wave-absorbing performance of rare retinyl Schiff base salts were discussed. The results show that the coordination bond is formed by the rare earth ions and Schiff base. The reflectivity of Schiff base coordinated with La<sup>3+</sup> ion is –16 dB at 12.9 GHz (bandwidth with reflectivity better than –10 dB is 3.1 GHz), the reflectivity of Schiff base coordinated with Ce<sup>3+</sup> ion is –18.8 dB at 12.7 GHz (bandwidth with reflectivity better than –10 dB is 3.4 GHz). Microwave absorption performances of the both are superior to the wave-absorbing performance of Schiff base coordinated with non-rare earth ions.http://html.rhhz.net/CHXB/html/2018-2-104.htmretinyl Schiff baserare earth iondielectric lossabsorption performancewave absorbing principle |
spellingShingle | LIU Huteng ZHOU Kesheng DENG Lianwen LIU Sheng HE Longhui YAO Lingling Preparation and Wave-absorbing Performance of Retinyl Schiff Base Salts Coordinated with Rare Earth La<sup>3+</sup> and Ce<sup>3+</sup> Ions Journal of Aeronautical Materials retinyl Schiff base rare earth ion dielectric loss absorption performance wave absorbing principle |
title | Preparation and Wave-absorbing Performance of Retinyl Schiff Base Salts Coordinated with Rare Earth La<sup>3+</sup> and Ce<sup>3+</sup> Ions |
title_full | Preparation and Wave-absorbing Performance of Retinyl Schiff Base Salts Coordinated with Rare Earth La<sup>3+</sup> and Ce<sup>3+</sup> Ions |
title_fullStr | Preparation and Wave-absorbing Performance of Retinyl Schiff Base Salts Coordinated with Rare Earth La<sup>3+</sup> and Ce<sup>3+</sup> Ions |
title_full_unstemmed | Preparation and Wave-absorbing Performance of Retinyl Schiff Base Salts Coordinated with Rare Earth La<sup>3+</sup> and Ce<sup>3+</sup> Ions |
title_short | Preparation and Wave-absorbing Performance of Retinyl Schiff Base Salts Coordinated with Rare Earth La<sup>3+</sup> and Ce<sup>3+</sup> Ions |
title_sort | preparation and wave absorbing performance of retinyl schiff base salts coordinated with rare earth la sup 3 sup and ce sup 3 sup ions |
topic | retinyl Schiff base rare earth ion dielectric loss absorption performance wave absorbing principle |
url | http://html.rhhz.net/CHXB/html/2018-2-104.htm |
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