Preparation and Wave-absorbing Performance of Retinyl Schiff Base Salts Coordinated with Rare Earth La<sup>3+</sup> and Ce<sup>3+</sup> Ions

With vitamin A acetate as raw material, ethylenediamine retinyl Schiff base salts coordinated with rare earth ion La<sup>3+</sup>, Ce<sup>3+</sup> were synthesized, and the structure of the products was characterized by FT-IR and Raman spectra. The electromagnetic parameters...

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Main Authors: LIU Huteng, ZHOU Kesheng, DENG Lianwen, LIU Sheng, HE Longhui, YAO Lingling
Format: Article
Language:zho
Published: Journal of Aeronautical Materials 2018-04-01
Series:Journal of Aeronautical Materials
Subjects:
Online Access:http://html.rhhz.net/CHXB/html/2018-2-104.htm
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author LIU Huteng
ZHOU Kesheng
DENG Lianwen
LIU Sheng
HE Longhui
YAO Lingling
author_facet LIU Huteng
ZHOU Kesheng
DENG Lianwen
LIU Sheng
HE Longhui
YAO Lingling
author_sort LIU Huteng
collection DOAJ
description With vitamin A acetate as raw material, ethylenediamine retinyl Schiff base salts coordinated with rare earth ion La<sup>3+</sup>, Ce<sup>3+</sup> were synthesized, and the structure of the products was characterized by FT-IR and Raman spectra. The electromagnetic parameters in the frequency range of 2-18 GHz were measured by microwave vector network analyzer, its reflectivity was calculated, and the main factors and mechanism that affect the wave-absorbing performance of rare retinyl Schiff base salts were discussed. The results show that the coordination bond is formed by the rare earth ions and Schiff base. The reflectivity of Schiff base coordinated with La<sup>3+</sup> ion is &#8211;16 dB at 12.9 GHz (bandwidth with reflectivity better than &#8211;10 dB is 3.1 GHz), the reflectivity of Schiff base coordinated with Ce<sup>3+</sup> ion is &#8211;18.8 dB at 12.7 GHz (bandwidth with reflectivity better than &#8211;10 dB is 3.4 GHz). Microwave absorption performances of the both are superior to the wave-absorbing performance of Schiff base coordinated with non-rare earth ions.
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spelling doaj.art-e60debb7fc954c37a5e829ada7bef4a82022-12-22T00:18:23ZzhoJournal of Aeronautical MaterialsJournal of Aeronautical Materials1005-50531005-50532018-04-0138210410910.11868/j.issn.1005-5053.2017.000001201802000001Preparation and Wave-absorbing Performance of Retinyl Schiff Base Salts Coordinated with Rare Earth La<sup>3+</sup> and Ce<sup>3+</sup> IonsLIU HutengZHOU KeshengDENG LianwenLIU ShengHE LonghuiYAO LinglingWith vitamin A acetate as raw material, ethylenediamine retinyl Schiff base salts coordinated with rare earth ion La<sup>3+</sup>, Ce<sup>3+</sup> were synthesized, and the structure of the products was characterized by FT-IR and Raman spectra. The electromagnetic parameters in the frequency range of 2-18 GHz were measured by microwave vector network analyzer, its reflectivity was calculated, and the main factors and mechanism that affect the wave-absorbing performance of rare retinyl Schiff base salts were discussed. The results show that the coordination bond is formed by the rare earth ions and Schiff base. The reflectivity of Schiff base coordinated with La<sup>3+</sup> ion is &#8211;16 dB at 12.9 GHz (bandwidth with reflectivity better than &#8211;10 dB is 3.1 GHz), the reflectivity of Schiff base coordinated with Ce<sup>3+</sup> ion is &#8211;18.8 dB at 12.7 GHz (bandwidth with reflectivity better than &#8211;10 dB is 3.4 GHz). Microwave absorption performances of the both are superior to the wave-absorbing performance of Schiff base coordinated with non-rare earth ions.http://html.rhhz.net/CHXB/html/2018-2-104.htmretinyl Schiff baserare earth iondielectric lossabsorption performancewave absorbing principle
spellingShingle LIU Huteng
ZHOU Kesheng
DENG Lianwen
LIU Sheng
HE Longhui
YAO Lingling
Preparation and Wave-absorbing Performance of Retinyl Schiff Base Salts Coordinated with Rare Earth La<sup>3+</sup> and Ce<sup>3+</sup> Ions
Journal of Aeronautical Materials
retinyl Schiff base
rare earth ion
dielectric loss
absorption performance
wave absorbing principle
title Preparation and Wave-absorbing Performance of Retinyl Schiff Base Salts Coordinated with Rare Earth La<sup>3+</sup> and Ce<sup>3+</sup> Ions
title_full Preparation and Wave-absorbing Performance of Retinyl Schiff Base Salts Coordinated with Rare Earth La<sup>3+</sup> and Ce<sup>3+</sup> Ions
title_fullStr Preparation and Wave-absorbing Performance of Retinyl Schiff Base Salts Coordinated with Rare Earth La<sup>3+</sup> and Ce<sup>3+</sup> Ions
title_full_unstemmed Preparation and Wave-absorbing Performance of Retinyl Schiff Base Salts Coordinated with Rare Earth La<sup>3+</sup> and Ce<sup>3+</sup> Ions
title_short Preparation and Wave-absorbing Performance of Retinyl Schiff Base Salts Coordinated with Rare Earth La<sup>3+</sup> and Ce<sup>3+</sup> Ions
title_sort preparation and wave absorbing performance of retinyl schiff base salts coordinated with rare earth la sup 3 sup and ce sup 3 sup ions
topic retinyl Schiff base
rare earth ion
dielectric loss
absorption performance
wave absorbing principle
url http://html.rhhz.net/CHXB/html/2018-2-104.htm
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