Collective Relaxation Processes in Nonchiral Nematics

Nematic–nematic transitions in a highly polar nematic compound are studied, in thick cells in which the molecules are aligned parallel to the substrates but perpendicular to the applied electric field, using dielectric spectroscopy in the frequency range 1 Hz to 10 MHz over a wide temperature range....

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Main Authors: Neelam Yadav, Yuri P. Panarin, Wanhe Jiang, Georg H. Mehl, Jagdish K. Vij
Format: Article
Language:English
Published: MDPI AG 2023-06-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/13/6/962
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author Neelam Yadav
Yuri P. Panarin
Wanhe Jiang
Georg H. Mehl
Jagdish K. Vij
author_facet Neelam Yadav
Yuri P. Panarin
Wanhe Jiang
Georg H. Mehl
Jagdish K. Vij
author_sort Neelam Yadav
collection DOAJ
description Nematic–nematic transitions in a highly polar nematic compound are studied, in thick cells in which the molecules are aligned parallel to the substrates but perpendicular to the applied electric field, using dielectric spectroscopy in the frequency range 1 Hz to 10 MHz over a wide temperature range. The studied compound displays three nematic phases under cooling from the isotropic phase: ubiquitous nematic N; high polarizability N<sub>X</sub>; and ferroelectric nematic N<sub>F</sub>. Two collective processes were observed. The dielectric strength and relaxation frequency of one of the processes P<sub>2</sub> showed a dependence on the thickness of the cell. The process P<sub>1</sub> is the amplitude mode, while the process P<sub>2</sub> is the phason mode.
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spelling doaj.art-e6210c239cbd4554b558a953ec19be1c2023-11-18T09:57:11ZengMDPI AGCrystals2073-43522023-06-0113696210.3390/cryst13060962Collective Relaxation Processes in Nonchiral NematicsNeelam Yadav0Yuri P. Panarin1Wanhe Jiang2Georg H. Mehl3Jagdish K. Vij4Department of Electronic and Electrical Engineering, Trinity College Dublin, The University of Dublin, Dublin 2, D02 PN40 Dublin, IrelandDepartment of Electronic and Electrical Engineering, Trinity College Dublin, The University of Dublin, Dublin 2, D02 PN40 Dublin, IrelandDepartment of Chemistry, University of Hull, Hull HU6 7RX, UKDepartment of Chemistry, University of Hull, Hull HU6 7RX, UKDepartment of Electronic and Electrical Engineering, Trinity College Dublin, The University of Dublin, Dublin 2, D02 PN40 Dublin, IrelandNematic–nematic transitions in a highly polar nematic compound are studied, in thick cells in which the molecules are aligned parallel to the substrates but perpendicular to the applied electric field, using dielectric spectroscopy in the frequency range 1 Hz to 10 MHz over a wide temperature range. The studied compound displays three nematic phases under cooling from the isotropic phase: ubiquitous nematic N; high polarizability N<sub>X</sub>; and ferroelectric nematic N<sub>F</sub>. Two collective processes were observed. The dielectric strength and relaxation frequency of one of the processes P<sub>2</sub> showed a dependence on the thickness of the cell. The process P<sub>1</sub> is the amplitude mode, while the process P<sub>2</sub> is the phason mode.https://www.mdpi.com/2073-4352/13/6/962dielectric spectroscopydielectric permittivityferroelectric nematicschiralrelaxation processesplanar alignment
spellingShingle Neelam Yadav
Yuri P. Panarin
Wanhe Jiang
Georg H. Mehl
Jagdish K. Vij
Collective Relaxation Processes in Nonchiral Nematics
Crystals
dielectric spectroscopy
dielectric permittivity
ferroelectric nematics
chiral
relaxation processes
planar alignment
title Collective Relaxation Processes in Nonchiral Nematics
title_full Collective Relaxation Processes in Nonchiral Nematics
title_fullStr Collective Relaxation Processes in Nonchiral Nematics
title_full_unstemmed Collective Relaxation Processes in Nonchiral Nematics
title_short Collective Relaxation Processes in Nonchiral Nematics
title_sort collective relaxation processes in nonchiral nematics
topic dielectric spectroscopy
dielectric permittivity
ferroelectric nematics
chiral
relaxation processes
planar alignment
url https://www.mdpi.com/2073-4352/13/6/962
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