Enhancement in the optical and carbon dioxide gas sensing properties of polythiophene by dispersion of manganese dioxide nanoparticles

The present research article demonstrates the dispersion of manganese dioxide (MnO2) nanoparticles in polythiophene (PTh) to enhance the optical and gas sensing properties of PTh/MnO2 nanocomposites. The structural aspects of the as-synthesized nanocomposites were demonstrated by the techniques such...

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Main Authors: N.S. Wadatkar, S.A. Waghuley
Format: Article
Language:English
Published: Elsevier 2024-06-01
Series:Sustainable Chemistry for Climate Action
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2772826923000251
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author N.S. Wadatkar
S.A. Waghuley
author_facet N.S. Wadatkar
S.A. Waghuley
author_sort N.S. Wadatkar
collection DOAJ
description The present research article demonstrates the dispersion of manganese dioxide (MnO2) nanoparticles in polythiophene (PTh) to enhance the optical and gas sensing properties of PTh/MnO2 nanocomposites. The structural aspects of the as-synthesized nanocomposites were demonstrated by the techniques such as X-ray diffraction (XRD), Fourier transmission infrared spectroscopy (FTIR), Field emission scanning electron microscopy (FE-SEM). Furthermore, the optical characterization of the resulting composite was investigated using UV–Vis spectroscopy. UV–Vis analyses of obtained nanocomposite revealed a forbidden band of ∼ 3.7 eV. The prepared nanocomposites were exposed to CO2 gas to investigate the composites suitability for gas sensing application, which prove to be promising materials. The prominent exploit of the present work is that 0.8 Wt. % MnO2 loaded PTh composite material exhibits significant sensing response at low operating temperature including good stability and fast response and recovery time. The core objective of this work is the discussion of the enhancement in stability, response and recovery time as a consequence of the interaction between the CO2 gas and the as-synthesized nanocomposites.
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spelling doaj.art-e632e5ad35c446ce813bb108c4fd86d62023-12-21T07:39:02ZengElsevierSustainable Chemistry for Climate Action2772-82692024-06-014100036Enhancement in the optical and carbon dioxide gas sensing properties of polythiophene by dispersion of manganese dioxide nanoparticlesN.S. Wadatkar0S.A. Waghuley1Department of Physics, Government Polytechnic, Amravati 444603, India; Corresponding author.Department of Physics, Sant Gadge Baba Amravati University, Amravati 444602, IndiaThe present research article demonstrates the dispersion of manganese dioxide (MnO2) nanoparticles in polythiophene (PTh) to enhance the optical and gas sensing properties of PTh/MnO2 nanocomposites. The structural aspects of the as-synthesized nanocomposites were demonstrated by the techniques such as X-ray diffraction (XRD), Fourier transmission infrared spectroscopy (FTIR), Field emission scanning electron microscopy (FE-SEM). Furthermore, the optical characterization of the resulting composite was investigated using UV–Vis spectroscopy. UV–Vis analyses of obtained nanocomposite revealed a forbidden band of ∼ 3.7 eV. The prepared nanocomposites were exposed to CO2 gas to investigate the composites suitability for gas sensing application, which prove to be promising materials. The prominent exploit of the present work is that 0.8 Wt. % MnO2 loaded PTh composite material exhibits significant sensing response at low operating temperature including good stability and fast response and recovery time. The core objective of this work is the discussion of the enhancement in stability, response and recovery time as a consequence of the interaction between the CO2 gas and the as-synthesized nanocomposites.http://www.sciencedirect.com/science/article/pii/S2772826923000251Polythiophene/MnO2 nanocompositesOptical propertiesSensing response
spellingShingle N.S. Wadatkar
S.A. Waghuley
Enhancement in the optical and carbon dioxide gas sensing properties of polythiophene by dispersion of manganese dioxide nanoparticles
Sustainable Chemistry for Climate Action
Polythiophene/MnO2 nanocomposites
Optical properties
Sensing response
title Enhancement in the optical and carbon dioxide gas sensing properties of polythiophene by dispersion of manganese dioxide nanoparticles
title_full Enhancement in the optical and carbon dioxide gas sensing properties of polythiophene by dispersion of manganese dioxide nanoparticles
title_fullStr Enhancement in the optical and carbon dioxide gas sensing properties of polythiophene by dispersion of manganese dioxide nanoparticles
title_full_unstemmed Enhancement in the optical and carbon dioxide gas sensing properties of polythiophene by dispersion of manganese dioxide nanoparticles
title_short Enhancement in the optical and carbon dioxide gas sensing properties of polythiophene by dispersion of manganese dioxide nanoparticles
title_sort enhancement in the optical and carbon dioxide gas sensing properties of polythiophene by dispersion of manganese dioxide nanoparticles
topic Polythiophene/MnO2 nanocomposites
Optical properties
Sensing response
url http://www.sciencedirect.com/science/article/pii/S2772826923000251
work_keys_str_mv AT nswadatkar enhancementintheopticalandcarbondioxidegassensingpropertiesofpolythiophenebydispersionofmanganesedioxidenanoparticles
AT sawaghuley enhancementintheopticalandcarbondioxidegassensingpropertiesofpolythiophenebydispersionofmanganesedioxidenanoparticles