{5,5′-Dimethoxy-2,2′-[4,5-dimethyl-o-phenylenebis(nitrilomethylidyne)]diphenolato}nickel(II)
In the title Schiff base complex, [Ni(C24H22N2O4)], the NiII atom shows a square-planar geometry. The dihedral angles between the central benzene ring and the two outer rings are 4.79 (15) and 7.54 (15)°. In the crystal, molecules are connected through interm...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810051834 |
| Summary: | In the title Schiff base complex, [Ni(C24H22N2O4)], the NiII atom shows a square-planar geometry. The dihedral angles between the central benzene ring and the two outer rings are 4.79 (15) and 7.54 (15)°. In the crystal, molecules are connected through intermolecular C—H...O hydrogen bond, resulting in chains extending along the c axis. The crystal structure is further stabilized by intermolecular π–π interactions, with centroid–centroid distances in the range 3.3760 (15)–3.7196 (17) Å. |
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| ISSN: | 1600-5368 |