{5,5′-Dimethoxy-2,2′-[4,5-dimethyl-o-phenylenebis(nitrilomethylidyne)]diphenolato}nickel(II)
In the title Schiff base complex, [Ni(C24H22N2O4)], the NiII atom shows a square-planar geometry. The dihedral angles between the central benzene ring and the two outer rings are 4.79 (15) and 7.54 (15)°. In the crystal, molecules are connected through interm...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810051834 |
| _version_ | 1818894482526961664 |
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| author | Muhammad Nawaz Tahir Reza Kia Hadi Kargar Atefeh Sahraei |
| author_facet | Muhammad Nawaz Tahir Reza Kia Hadi Kargar Atefeh Sahraei |
| author_sort | Muhammad Nawaz Tahir |
| collection | DOAJ |
| description | In the title Schiff base complex, [Ni(C24H22N2O4)], the NiII atom shows a square-planar geometry. The dihedral angles between the central benzene ring and the two outer rings are 4.79 (15) and 7.54 (15)°. In the crystal, molecules are connected through intermolecular C—H...O hydrogen bond, resulting in chains extending along the c axis. The crystal structure is further stabilized by intermolecular π–π interactions, with centroid–centroid distances in the range 3.3760 (15)–3.7196 (17) Å. |
| first_indexed | 2024-12-19T18:29:12Z |
| format | Article |
| id | doaj.art-e69e126095c3405fba5dde892ee2aa8d |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T18:29:12Z |
| publishDate | 2011-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-e69e126095c3405fba5dde892ee2aa8d2022-12-21T20:10:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-01-01671m82m8310.1107/S1600536810051834{5,5′-Dimethoxy-2,2′-[4,5-dimethyl-o-phenylenebis(nitrilomethylidyne)]diphenolato}nickel(II)Muhammad Nawaz TahirReza KiaHadi KargarAtefeh SahraeiIn the title Schiff base complex, [Ni(C24H22N2O4)], the NiII atom shows a square-planar geometry. The dihedral angles between the central benzene ring and the two outer rings are 4.79 (15) and 7.54 (15)°. In the crystal, molecules are connected through intermolecular C—H...O hydrogen bond, resulting in chains extending along the c axis. The crystal structure is further stabilized by intermolecular π–π interactions, with centroid–centroid distances in the range 3.3760 (15)–3.7196 (17) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536810051834 |
| spellingShingle | Muhammad Nawaz Tahir Reza Kia Hadi Kargar Atefeh Sahraei {5,5′-Dimethoxy-2,2′-[4,5-dimethyl-o-phenylenebis(nitrilomethylidyne)]diphenolato}nickel(II) Acta Crystallographica Section E |
| title | {5,5′-Dimethoxy-2,2′-[4,5-dimethyl-o-phenylenebis(nitrilomethylidyne)]diphenolato}nickel(II) |
| title_full | {5,5′-Dimethoxy-2,2′-[4,5-dimethyl-o-phenylenebis(nitrilomethylidyne)]diphenolato}nickel(II) |
| title_fullStr | {5,5′-Dimethoxy-2,2′-[4,5-dimethyl-o-phenylenebis(nitrilomethylidyne)]diphenolato}nickel(II) |
| title_full_unstemmed | {5,5′-Dimethoxy-2,2′-[4,5-dimethyl-o-phenylenebis(nitrilomethylidyne)]diphenolato}nickel(II) |
| title_short | {5,5′-Dimethoxy-2,2′-[4,5-dimethyl-o-phenylenebis(nitrilomethylidyne)]diphenolato}nickel(II) |
| title_sort | 5 5 amp 8242 dimethoxy 2 2 amp 8242 4 5 dimethyl o phenylenebis nitrilomethylidyne diphenolato nickel ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810051834 |
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