Colorimetric Freshness Indicator Based on Cellulose Nanocrystal–Silver Nanoparticle Composite for Intelligent Food Packaging

In this study, a colorimetric freshness indicator based on cellulose nanocrystal-silver nanoparticles (CNC-AgNPs) was successfully fabricated to offer a convenient approach for monitoring the quality of packaged food. AgNPs were directly synthesized and embedded in CNC via a one-pot hydrothermal gre...

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Main Authors: Seongyoung Kwon, Seonghyuk Ko
Format: Article
Language:English
Published: MDPI AG 2022-09-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/14/17/3695
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author Seongyoung Kwon
Seonghyuk Ko
author_facet Seongyoung Kwon
Seonghyuk Ko
author_sort Seongyoung Kwon
collection DOAJ
description In this study, a colorimetric freshness indicator based on cellulose nanocrystal-silver nanoparticles (CNC-AgNPs) was successfully fabricated to offer a convenient approach for monitoring the quality of packaged food. AgNPs were directly synthesized and embedded in CNC via a one-pot hydrothermal green synthesis, and CNC-AgNP composited indicator films were prepared using a simple casting method. The AgNPs obtained were confirmed by UV-Vis diffuse reflectance spectroscopy and X-ray diffraction. The ability of the as-prepared CNC-AgNP film to indicate food quality was assessed in terms of the intensity of its color change when in contact with spoilage gases from chicken breast. The CNC-AgNP films initially exhibited a yellowish to dark wine-red color depending on the amount of AgNPs involved. They gradually turned colorless and subsequently to metallic grey. This transition is attributed to the reaction of AgNPs and hydrogen sulfide (H<sub>2</sub>S), which alters the surface plasmon resonance of AgNPs. Consequently, the color change was suitably discernible to the human eye, implying that the CNC-AgNP composite is a highly effective colorimetric freshness indicator. It can potentially serve as an accurate and irreversible food quality indicator in intelligent packaging during distribution or storage of products that emit hydrogen sulfide when deteriorating, such as poultry products or broccoli.
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spelling doaj.art-e6b06eff7ded478ebeffae55086f18922023-11-23T14:01:14ZengMDPI AGPolymers2073-43602022-09-011417369510.3390/polym14173695Colorimetric Freshness Indicator Based on Cellulose Nanocrystal–Silver Nanoparticle Composite for Intelligent Food PackagingSeongyoung Kwon0Seonghyuk Ko1Department of Packaging, Yonsei University, Wonju 26493, KoreaDepartment of Packaging, Yonsei University, Wonju 26493, KoreaIn this study, a colorimetric freshness indicator based on cellulose nanocrystal-silver nanoparticles (CNC-AgNPs) was successfully fabricated to offer a convenient approach for monitoring the quality of packaged food. AgNPs were directly synthesized and embedded in CNC via a one-pot hydrothermal green synthesis, and CNC-AgNP composited indicator films were prepared using a simple casting method. The AgNPs obtained were confirmed by UV-Vis diffuse reflectance spectroscopy and X-ray diffraction. The ability of the as-prepared CNC-AgNP film to indicate food quality was assessed in terms of the intensity of its color change when in contact with spoilage gases from chicken breast. The CNC-AgNP films initially exhibited a yellowish to dark wine-red color depending on the amount of AgNPs involved. They gradually turned colorless and subsequently to metallic grey. This transition is attributed to the reaction of AgNPs and hydrogen sulfide (H<sub>2</sub>S), which alters the surface plasmon resonance of AgNPs. Consequently, the color change was suitably discernible to the human eye, implying that the CNC-AgNP composite is a highly effective colorimetric freshness indicator. It can potentially serve as an accurate and irreversible food quality indicator in intelligent packaging during distribution or storage of products that emit hydrogen sulfide when deteriorating, such as poultry products or broccoli.https://www.mdpi.com/2073-4360/14/17/3695cellulose nanocrystalsilver nanoparticlehydrothermal green synthesiscolorimetric freshness indicatorintelligent packaging
spellingShingle Seongyoung Kwon
Seonghyuk Ko
Colorimetric Freshness Indicator Based on Cellulose Nanocrystal–Silver Nanoparticle Composite for Intelligent Food Packaging
Polymers
cellulose nanocrystal
silver nanoparticle
hydrothermal green synthesis
colorimetric freshness indicator
intelligent packaging
title Colorimetric Freshness Indicator Based on Cellulose Nanocrystal–Silver Nanoparticle Composite for Intelligent Food Packaging
title_full Colorimetric Freshness Indicator Based on Cellulose Nanocrystal–Silver Nanoparticle Composite for Intelligent Food Packaging
title_fullStr Colorimetric Freshness Indicator Based on Cellulose Nanocrystal–Silver Nanoparticle Composite for Intelligent Food Packaging
title_full_unstemmed Colorimetric Freshness Indicator Based on Cellulose Nanocrystal–Silver Nanoparticle Composite for Intelligent Food Packaging
title_short Colorimetric Freshness Indicator Based on Cellulose Nanocrystal–Silver Nanoparticle Composite for Intelligent Food Packaging
title_sort colorimetric freshness indicator based on cellulose nanocrystal silver nanoparticle composite for intelligent food packaging
topic cellulose nanocrystal
silver nanoparticle
hydrothermal green synthesis
colorimetric freshness indicator
intelligent packaging
url https://www.mdpi.com/2073-4360/14/17/3695
work_keys_str_mv AT seongyoungkwon colorimetricfreshnessindicatorbasedoncellulosenanocrystalsilvernanoparticlecompositeforintelligentfoodpackaging
AT seonghyukko colorimetricfreshnessindicatorbasedoncellulosenanocrystalsilvernanoparticlecompositeforintelligentfoodpackaging