A novel MnFe2O4-HSO3 nanocatalyst for heterogeneous Fenton degradation of antibiotics

A novel sulfonic-functionalized MnFe2O4 (MnFe2O4-HSO3) Fenton nanocatalyst was prepared and tested for the degradation of three antibiotics from different categories. The effect of category of the antibiotic was investigated and the obtained results indicated that the degradation rate was the highes...

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Main Authors: Sizhan Wu, Hangdao Qin, Hao Cheng, Wei Shi, Jing Chen, Jiming Huang, Hui Li
Format: Article
Language:English
Published: Elsevier 2022-11-01
Series:Catalysis Communications
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1566736722001273
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author Sizhan Wu
Hangdao Qin
Hao Cheng
Wei Shi
Jing Chen
Jiming Huang
Hui Li
author_facet Sizhan Wu
Hangdao Qin
Hao Cheng
Wei Shi
Jing Chen
Jiming Huang
Hui Li
author_sort Sizhan Wu
collection DOAJ
description A novel sulfonic-functionalized MnFe2O4 (MnFe2O4-HSO3) Fenton nanocatalyst was prepared and tested for the degradation of three antibiotics from different categories. The effect of category of the antibiotic was investigated and the obtained results indicated that the degradation rate was the highest for erythromycin, lower for tetracycline and the lowest for amikacin. Moreover, the role of -HSO3 was investigated by a series of comparative experiments between MnFe2O4 and MnFe2O4-HSO3. The introduction of -HSO3 prevented the leaching of metals and promoted the decomposition of H2O2 into •OH radicals. Finally, the excellent stability of MnFe2O4-HSO3 was verified.
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spelling doaj.art-e6dff10940cc4ff5b23df29e69a091c42022-12-22T04:06:57ZengElsevierCatalysis Communications1873-39052022-11-01171106522A novel MnFe2O4-HSO3 nanocatalyst for heterogeneous Fenton degradation of antibioticsSizhan Wu0Hangdao Qin1Hao Cheng2Wei Shi3Jing Chen4Jiming Huang5Hui Li6School of Material and Chemical Engineering, Tongren University, Tongren 554300, ChinaCorresponding author.; School of Material and Chemical Engineering, Tongren University, Tongren 554300, ChinaSchool of Material and Chemical Engineering, Tongren University, Tongren 554300, ChinaSchool of Material and Chemical Engineering, Tongren University, Tongren 554300, ChinaSchool of Material and Chemical Engineering, Tongren University, Tongren 554300, ChinaSchool of Material and Chemical Engineering, Tongren University, Tongren 554300, ChinaSchool of Material and Chemical Engineering, Tongren University, Tongren 554300, ChinaA novel sulfonic-functionalized MnFe2O4 (MnFe2O4-HSO3) Fenton nanocatalyst was prepared and tested for the degradation of three antibiotics from different categories. The effect of category of the antibiotic was investigated and the obtained results indicated that the degradation rate was the highest for erythromycin, lower for tetracycline and the lowest for amikacin. Moreover, the role of -HSO3 was investigated by a series of comparative experiments between MnFe2O4 and MnFe2O4-HSO3. The introduction of -HSO3 prevented the leaching of metals and promoted the decomposition of H2O2 into •OH radicals. Finally, the excellent stability of MnFe2O4-HSO3 was verified.http://www.sciencedirect.com/science/article/pii/S1566736722001273Heterogeneous Fenton oxidationMnFe2O4AntibioticsDegradationSulfonic-functionalization
spellingShingle Sizhan Wu
Hangdao Qin
Hao Cheng
Wei Shi
Jing Chen
Jiming Huang
Hui Li
A novel MnFe2O4-HSO3 nanocatalyst for heterogeneous Fenton degradation of antibiotics
Catalysis Communications
Heterogeneous Fenton oxidation
MnFe2O4
Antibiotics
Degradation
Sulfonic-functionalization
title A novel MnFe2O4-HSO3 nanocatalyst for heterogeneous Fenton degradation of antibiotics
title_full A novel MnFe2O4-HSO3 nanocatalyst for heterogeneous Fenton degradation of antibiotics
title_fullStr A novel MnFe2O4-HSO3 nanocatalyst for heterogeneous Fenton degradation of antibiotics
title_full_unstemmed A novel MnFe2O4-HSO3 nanocatalyst for heterogeneous Fenton degradation of antibiotics
title_short A novel MnFe2O4-HSO3 nanocatalyst for heterogeneous Fenton degradation of antibiotics
title_sort novel mnfe2o4 hso3 nanocatalyst for heterogeneous fenton degradation of antibiotics
topic Heterogeneous Fenton oxidation
MnFe2O4
Antibiotics
Degradation
Sulfonic-functionalization
url http://www.sciencedirect.com/science/article/pii/S1566736722001273
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