Structural and Optical Properties of Nanocrystalline Pbs Thin Films Prepared by Microwave-Assisted Chemical Bath Deposition

Nanocrystalline lead sulfide (PbS) thin films have been successfully deposited onto glass substrate via microwave assisted chemical bath deposition. Aqueous solutions of lead nitrate Pb(NO3) and thiourea [SC(NH2)2] were used as lead and sulfur ion sources respectively. Structural and morphological s...

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Main Author: Muhammed Husham
Format: Article
Language:English
Published: Tishk International University 2022-06-01
Series:Eurasian Journal of Science and Engineering
Subjects:
Online Access:https://eajse.tiu.edu.iq/index.php/volume-8-issue-2-article-2/
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author Muhammed Husham
author_facet Muhammed Husham
author_sort Muhammed Husham
collection DOAJ
description Nanocrystalline lead sulfide (PbS) thin films have been successfully deposited onto glass substrate via microwave assisted chemical bath deposition. Aqueous solutions of lead nitrate Pb(NO3) and thiourea [SC(NH2)2] were used as lead and sulfur ion sources respectively. Structural and morphological studies revealed a high synthesized nanocrystalline PbS thin films quality. Optical studies showed a significant blue shifting in the energy gap of the prepared nanocrystalline PbS thin films. Compared with bulk PbS, the prepared nanocrystalline PbS showed large energy gap, value of about 2.4 eV. This could be attributed to the confinement effect of nanocrystalline PbS thin films. The study introduced a simple and cost-effective method to further investigate other properties of nanocrystalline PbS thin films such as electrical and morphological properties.
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spelling doaj.art-e70a9e83e8734ea08dbc899ed15fee0e2023-08-02T07:19:51ZengTishk International UniversityEurasian Journal of Science and Engineering2414-56292414-56022022-06-01821015Structural and Optical Properties of Nanocrystalline Pbs Thin Films Prepared by Microwave-Assisted Chemical Bath DepositionMuhammed Husham0Physics Education Department, Faculty of Education, Tishk International University, Erbil, IraqNanocrystalline lead sulfide (PbS) thin films have been successfully deposited onto glass substrate via microwave assisted chemical bath deposition. Aqueous solutions of lead nitrate Pb(NO3) and thiourea [SC(NH2)2] were used as lead and sulfur ion sources respectively. Structural and morphological studies revealed a high synthesized nanocrystalline PbS thin films quality. Optical studies showed a significant blue shifting in the energy gap of the prepared nanocrystalline PbS thin films. Compared with bulk PbS, the prepared nanocrystalline PbS showed large energy gap, value of about 2.4 eV. This could be attributed to the confinement effect of nanocrystalline PbS thin films. The study introduced a simple and cost-effective method to further investigate other properties of nanocrystalline PbS thin films such as electrical and morphological properties.https://eajse.tiu.edu.iq/index.php/volume-8-issue-2-article-2/nanocrystalline pbs thin filmspropertiesmicrowave cbdblue shiftenergy gap
spellingShingle Muhammed Husham
Structural and Optical Properties of Nanocrystalline Pbs Thin Films Prepared by Microwave-Assisted Chemical Bath Deposition
Eurasian Journal of Science and Engineering
nanocrystalline pbs thin films
properties
microwave cbd
blue shift
energy gap
title Structural and Optical Properties of Nanocrystalline Pbs Thin Films Prepared by Microwave-Assisted Chemical Bath Deposition
title_full Structural and Optical Properties of Nanocrystalline Pbs Thin Films Prepared by Microwave-Assisted Chemical Bath Deposition
title_fullStr Structural and Optical Properties of Nanocrystalline Pbs Thin Films Prepared by Microwave-Assisted Chemical Bath Deposition
title_full_unstemmed Structural and Optical Properties of Nanocrystalline Pbs Thin Films Prepared by Microwave-Assisted Chemical Bath Deposition
title_short Structural and Optical Properties of Nanocrystalline Pbs Thin Films Prepared by Microwave-Assisted Chemical Bath Deposition
title_sort structural and optical properties of nanocrystalline pbs thin films prepared by microwave assisted chemical bath deposition
topic nanocrystalline pbs thin films
properties
microwave cbd
blue shift
energy gap
url https://eajse.tiu.edu.iq/index.php/volume-8-issue-2-article-2/
work_keys_str_mv AT muhammedhusham structuralandopticalpropertiesofnanocrystallinepbsthinfilmspreparedbymicrowaveassistedchemicalbathdeposition