Bimetallic Layers Increase Sensitivity of Affinity Sensors Based on Surface Plasmon Resonance

Two metals are used in resonant layers for chemical sensors based on surface plasmon resonance (SPR) - gold and silver. Gold displays higher shift of the resonance angle to changes of ambient refraction index and is chemically stable. Silver posses narrower resonance curve thus providing a higher si...

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Main Authors: Yuri M. Shirshov, Vladimir M. Mirsky, Elena R. Surovtseva, Anton V. Samoylov, Stepan A. Zynio
Format: Article
Language:English
Published: MDPI AG 2002-02-01
Series:Sensors
Subjects:
Online Access:http://www.mdpi.com/1424-8220/2/2/62/
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author Yuri M. Shirshov
Vladimir M. Mirsky
Elena R. Surovtseva
Anton V. Samoylov
Stepan A. Zynio
author_facet Yuri M. Shirshov
Vladimir M. Mirsky
Elena R. Surovtseva
Anton V. Samoylov
Stepan A. Zynio
author_sort Yuri M. Shirshov
collection DOAJ
description Two metals are used in resonant layers for chemical sensors based on surface plasmon resonance (SPR) - gold and silver. Gold displays higher shift of the resonance angle to changes of ambient refraction index and is chemically stable. Silver posses narrower resonance curve thus providing a higher signal/noise ratio of SPR chemical sensors, but has a poor chemical stability. A new structure of resonant metallic film based on bimetallic silver/gold layers (gold as an outer layer) is suggested. It combines advantages of both gold and silver resonant layers. Bimetallic resonant films display so high shift of resonance angle on changes of ambient refraction index as gold films, but show narrower resonance curve, thus providing a higher signal / noise ratio. Additionally, the outer gold layer protects silver against oxidation.
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spelling doaj.art-e716e6b59c9640f8a5b3f60a9e4dedbe2022-12-22T04:09:03ZengMDPI AGSensors1424-82202002-02-0122627010.3390/s20200062Bimetallic Layers Increase Sensitivity of Affinity Sensors Based on Surface Plasmon ResonanceYuri M. ShirshovVladimir M. MirskyElena R. SurovtsevaAnton V. SamoylovStepan A. ZynioTwo metals are used in resonant layers for chemical sensors based on surface plasmon resonance (SPR) - gold and silver. Gold displays higher shift of the resonance angle to changes of ambient refraction index and is chemically stable. Silver posses narrower resonance curve thus providing a higher signal/noise ratio of SPR chemical sensors, but has a poor chemical stability. A new structure of resonant metallic film based on bimetallic silver/gold layers (gold as an outer layer) is suggested. It combines advantages of both gold and silver resonant layers. Bimetallic resonant films display so high shift of resonance angle on changes of ambient refraction index as gold films, but show narrower resonance curve, thus providing a higher signal / noise ratio. Additionally, the outer gold layer protects silver against oxidation.http://www.mdpi.com/1424-8220/2/2/62/Surface plasmon resonanceBiosensorSensitivitySignal / noise ratio
spellingShingle Yuri M. Shirshov
Vladimir M. Mirsky
Elena R. Surovtseva
Anton V. Samoylov
Stepan A. Zynio
Bimetallic Layers Increase Sensitivity of Affinity Sensors Based on Surface Plasmon Resonance
Sensors
Surface plasmon resonance
Biosensor
Sensitivity
Signal / noise ratio
title Bimetallic Layers Increase Sensitivity of Affinity Sensors Based on Surface Plasmon Resonance
title_full Bimetallic Layers Increase Sensitivity of Affinity Sensors Based on Surface Plasmon Resonance
title_fullStr Bimetallic Layers Increase Sensitivity of Affinity Sensors Based on Surface Plasmon Resonance
title_full_unstemmed Bimetallic Layers Increase Sensitivity of Affinity Sensors Based on Surface Plasmon Resonance
title_short Bimetallic Layers Increase Sensitivity of Affinity Sensors Based on Surface Plasmon Resonance
title_sort bimetallic layers increase sensitivity of affinity sensors based on surface plasmon resonance
topic Surface plasmon resonance
Biosensor
Sensitivity
Signal / noise ratio
url http://www.mdpi.com/1424-8220/2/2/62/
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AT elenarsurovtseva bimetalliclayersincreasesensitivityofaffinitysensorsbasedonsurfaceplasmonresonance
AT antonvsamoylov bimetalliclayersincreasesensitivityofaffinitysensorsbasedonsurfaceplasmonresonance
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