Di-μ-nitrito-κ3O:O,O′;κ3O,O′:O-bis{[2,6-bis(pyrazol-1-yl-κN2)pyridine-κN](nitrito-κ2O,O′)cadmium(II)}
In the title centrosymmetric binuclear complex, [Cd2(NO2)4(C11H9N5)2], the unique CdII ion is in a distorted dodecahedral CdN3O5 coordination environment. The two inversion-related CdII ions are separated by 3.9920 (6) Å and are bridged by two O atoms from tw...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809039841 |
| _version_ | 1818906257030905856 |
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| author | Ting Ting Sun Lin Meng Jing Min Shi |
| author_facet | Ting Ting Sun Lin Meng Jing Min Shi |
| author_sort | Ting Ting Sun |
| collection | DOAJ |
| description | In the title centrosymmetric binuclear complex, [Cd2(NO2)4(C11H9N5)2], the unique CdII ion is in a distorted dodecahedral CdN3O5 coordination environment. The two inversion-related CdII ions are separated by 3.9920 (6) Å and are bridged by two O atoms from two nitrite ligands. There are two types of π–π stacking interactions involving symmetry-related pyrazole rings, with centroid–centroid distances of 3.445 (2) and 3.431 (2) Å. |
| first_indexed | 2024-12-19T21:36:21Z |
| format | Article |
| id | doaj.art-e71bd59c27b84db98ed0a6c2b132052a |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T21:36:21Z |
| publishDate | 2009-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-e71bd59c27b84db98ed0a6c2b132052a2022-12-21T20:04:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1318m131810.1107/S1600536809039841Di-μ-nitrito-κ3O:O,O′;κ3O,O′:O-bis{[2,6-bis(pyrazol-1-yl-κN2)pyridine-κN](nitrito-κ2O,O′)cadmium(II)}Ting Ting SunLin MengJing Min ShiIn the title centrosymmetric binuclear complex, [Cd2(NO2)4(C11H9N5)2], the unique CdII ion is in a distorted dodecahedral CdN3O5 coordination environment. The two inversion-related CdII ions are separated by 3.9920 (6) Å and are bridged by two O atoms from two nitrite ligands. There are two types of π–π stacking interactions involving symmetry-related pyrazole rings, with centroid–centroid distances of 3.445 (2) and 3.431 (2) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536809039841 |
| spellingShingle | Ting Ting Sun Lin Meng Jing Min Shi Di-μ-nitrito-κ3O:O,O′;κ3O,O′:O-bis{[2,6-bis(pyrazol-1-yl-κN2)pyridine-κN](nitrito-κ2O,O′)cadmium(II)} Acta Crystallographica Section E |
| title | Di-μ-nitrito-κ3O:O,O′;κ3O,O′:O-bis{[2,6-bis(pyrazol-1-yl-κN2)pyridine-κN](nitrito-κ2O,O′)cadmium(II)} |
| title_full | Di-μ-nitrito-κ3O:O,O′;κ3O,O′:O-bis{[2,6-bis(pyrazol-1-yl-κN2)pyridine-κN](nitrito-κ2O,O′)cadmium(II)} |
| title_fullStr | Di-μ-nitrito-κ3O:O,O′;κ3O,O′:O-bis{[2,6-bis(pyrazol-1-yl-κN2)pyridine-κN](nitrito-κ2O,O′)cadmium(II)} |
| title_full_unstemmed | Di-μ-nitrito-κ3O:O,O′;κ3O,O′:O-bis{[2,6-bis(pyrazol-1-yl-κN2)pyridine-κN](nitrito-κ2O,O′)cadmium(II)} |
| title_short | Di-μ-nitrito-κ3O:O,O′;κ3O,O′:O-bis{[2,6-bis(pyrazol-1-yl-κN2)pyridine-κN](nitrito-κ2O,O′)cadmium(II)} |
| title_sort | di amp 956 nitrito amp 954 3o o o amp 8242 amp 954 3o o amp 8242 o bis 2 6 bis pyrazol 1 yl amp 954 n2 pyridine amp 954 n nitrito amp 954 2o o amp 8242 cadmium ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809039841 |
| work_keys_str_mv | AT tingtingsun diamp956nitritoamp9543oooamp8242amp9543ooamp8242obis26bispyrazol1ylamp954n2pyridineamp954nnitritoamp9542ooamp8242cadmiumii AT linmeng diamp956nitritoamp9543oooamp8242amp9543ooamp8242obis26bispyrazol1ylamp954n2pyridineamp954nnitritoamp9542ooamp8242cadmiumii AT jingminshi diamp956nitritoamp9543oooamp8242amp9543ooamp8242obis26bispyrazol1ylamp954n2pyridineamp954nnitritoamp9542ooamp8242cadmiumii |