Recent advancement and key opportunities of MXenes for electrocatalysis

Summary: MXenes are promising materials for electrocatalysis due to their excellent metallic conductivity, hydrophilicity, high specific surface area, and excellent electrochemical properties. Herein, we summarize the recent advancement of MXene-based materials for electrocatalysis and highlight the...

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Main Authors: Xianhong Wu, Yi Wang, Zhong-Shuai Wu
Format: Article
Language:English
Published: Elsevier 2024-02-01
Series:iScience
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2589004224001275
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author Xianhong Wu
Yi Wang
Zhong-Shuai Wu
author_facet Xianhong Wu
Yi Wang
Zhong-Shuai Wu
author_sort Xianhong Wu
collection DOAJ
description Summary: MXenes are promising materials for electrocatalysis due to their excellent metallic conductivity, hydrophilicity, high specific surface area, and excellent electrochemical properties. Herein, we summarize the recent advancement of MXene-based materials for electrocatalysis and highlight their key challenges and opportunities. In particular, this review emphasizes on the major design principles of MXene-based electrocatalysts, including (1) coupling MXene with active materials or heteroatomic doping to create highly active synergistic catalyst sites; (2) construction of 3D MXene structure or introducing interlayer spacers to increase active areas and form fast mass-charge transfer channel; and (3) protecting edge of MXene or in situ transforming the surface of MXene to stable active substance that inhibits the oxidation of MXene and then enhances the stability. Consequently, MXene-based materials exhibit outstanding performance for a variety of electrocatalytic reactions. Finally, the key challenges and promising prospects of the practical applications of MXene-based electrocatalysts are briefly proposed.
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spelling doaj.art-e72bf0b2f3f741a097399a5f236924d22024-01-29T04:16:16ZengElsevieriScience2589-00422024-02-01272108906Recent advancement and key opportunities of MXenes for electrocatalysisXianhong Wu0Yi Wang1Zhong-Shuai Wu2State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China; College of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034, ChinaState Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China; University of Chinese Academy of Sciences, Shijingshan District, Beijing 100049, ChinaState Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China; Dalian National Laboratory for Clean Energy, Chinese Academy of Sciences, Dalian 116023, China; Corresponding authorSummary: MXenes are promising materials for electrocatalysis due to their excellent metallic conductivity, hydrophilicity, high specific surface area, and excellent electrochemical properties. Herein, we summarize the recent advancement of MXene-based materials for electrocatalysis and highlight their key challenges and opportunities. In particular, this review emphasizes on the major design principles of MXene-based electrocatalysts, including (1) coupling MXene with active materials or heteroatomic doping to create highly active synergistic catalyst sites; (2) construction of 3D MXene structure or introducing interlayer spacers to increase active areas and form fast mass-charge transfer channel; and (3) protecting edge of MXene or in situ transforming the surface of MXene to stable active substance that inhibits the oxidation of MXene and then enhances the stability. Consequently, MXene-based materials exhibit outstanding performance for a variety of electrocatalytic reactions. Finally, the key challenges and promising prospects of the practical applications of MXene-based electrocatalysts are briefly proposed.http://www.sciencedirect.com/science/article/pii/S2589004224001275Materials chemistryEnergy materials
spellingShingle Xianhong Wu
Yi Wang
Zhong-Shuai Wu
Recent advancement and key opportunities of MXenes for electrocatalysis
iScience
Materials chemistry
Energy materials
title Recent advancement and key opportunities of MXenes for electrocatalysis
title_full Recent advancement and key opportunities of MXenes for electrocatalysis
title_fullStr Recent advancement and key opportunities of MXenes for electrocatalysis
title_full_unstemmed Recent advancement and key opportunities of MXenes for electrocatalysis
title_short Recent advancement and key opportunities of MXenes for electrocatalysis
title_sort recent advancement and key opportunities of mxenes for electrocatalysis
topic Materials chemistry
Energy materials
url http://www.sciencedirect.com/science/article/pii/S2589004224001275
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