Using a geochemical method of dissolved and insoluble fractions to characterize surface snow melting and major element elution

A geochemical method to characterize post-depositional melting and elution is demonstrated using inductively coupled plasma mass spectrometry to measure concentrations of dissolved and insoluble fractions of major crustal elements in snow samples collected from March 2006 to January 2010 at Urumqi G...

Full description

Bibliographic Details
Main Authors: GUANGJIAN WU, PEILIN LI, XUELEI ZHANG, CHENGLONG ZHANG
Format: Article
Language:English
Published: Cambridge University Press 2018-12-01
Series:Journal of Glaciology
Subjects:
Online Access:https://www.cambridge.org/core/product/identifier/S0022143018000874/type/journal_article
_version_ 1811155830979952640
author GUANGJIAN WU
PEILIN LI
XUELEI ZHANG
CHENGLONG ZHANG
author_facet GUANGJIAN WU
PEILIN LI
XUELEI ZHANG
CHENGLONG ZHANG
author_sort GUANGJIAN WU
collection DOAJ
description A geochemical method to characterize post-depositional melting and elution is demonstrated using inductively coupled plasma mass spectrometry to measure concentrations of dissolved and insoluble fractions of major crustal elements in snow samples collected from March 2006 to January 2010 at Urumqi Glacier No. 1, Tien Shan. Dust from these samples has compositional homogeneity, suggesting that dust has a stable dissolved fraction percentage (DFP, calculated as dissolved/(dissolved + insoluble)%). Calcium has the highest DFP (averaging 61.5 ± 19.4%), followed by Na (30.4 ± 19.6%), Mg (13.2 ± 9.8%), and K (7.9 ± 9.8%). Acid input can affect dissolution of Na and Ca. Taking DFP values of unmelted samples as the reference, the higher DFPs refer to strengthened dissolution from acid input, while the lower ones refer to elution. Based on the DFP difference between unmelted and eluted states, an elution sequence Ca > Na > Mg > K is obtained. Some details such as the beginning and the ending stages of elution can be found by DFP and acid input index, while using ion concentration is not capable of this. Our results reveal that acid input is an important mechanism for DFP changes, that the DFP index can provide an effective assessment of snow elution, and that this will aid in understanding low latitude ice cores.
first_indexed 2024-04-10T04:41:17Z
format Article
id doaj.art-e72db12be6994ba39a7cf42542ac7ab9
institution Directory Open Access Journal
issn 0022-1430
1727-5652
language English
last_indexed 2024-04-10T04:41:17Z
publishDate 2018-12-01
publisher Cambridge University Press
record_format Article
series Journal of Glaciology
spelling doaj.art-e72db12be6994ba39a7cf42542ac7ab92023-03-09T12:40:41ZengCambridge University PressJournal of Glaciology0022-14301727-56522018-12-01641003101310.1017/jog.2018.87Using a geochemical method of dissolved and insoluble fractions to characterize surface snow melting and major element elutionGUANGJIAN WU0PEILIN LI1XUELEI ZHANG2https://orcid.org/0000-0002-5992-4334CHENGLONG ZHANG3Key Laboratory of Tibetan Environment Changes and Land Surface Processes, Institute of Tibetan Plateau Research, Chinese Academy of Sciences, Beijing 100101, China CAS Center for Excellence in Tibetan Plateau Earth Sciences, Beijing 100101, ChinaKey Laboratory of Tibetan Environment Changes and Land Surface Processes, Institute of Tibetan Plateau Research, Chinese Academy of Sciences, Beijing 100101, China University of Chinese Academy of Sciences, Beijing 100049, ChinaNortheast Institute of Geography and Agroecology, Chinese Academy of Sciences, Changchun 130102, ChinaResearch Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, 100085, ChinaA geochemical method to characterize post-depositional melting and elution is demonstrated using inductively coupled plasma mass spectrometry to measure concentrations of dissolved and insoluble fractions of major crustal elements in snow samples collected from March 2006 to January 2010 at Urumqi Glacier No. 1, Tien Shan. Dust from these samples has compositional homogeneity, suggesting that dust has a stable dissolved fraction percentage (DFP, calculated as dissolved/(dissolved + insoluble)%). Calcium has the highest DFP (averaging 61.5 ± 19.4%), followed by Na (30.4 ± 19.6%), Mg (13.2 ± 9.8%), and K (7.9 ± 9.8%). Acid input can affect dissolution of Na and Ca. Taking DFP values of unmelted samples as the reference, the higher DFPs refer to strengthened dissolution from acid input, while the lower ones refer to elution. Based on the DFP difference between unmelted and eluted states, an elution sequence Ca > Na > Mg > K is obtained. Some details such as the beginning and the ending stages of elution can be found by DFP and acid input index, while using ion concentration is not capable of this. Our results reveal that acid input is an important mechanism for DFP changes, that the DFP index can provide an effective assessment of snow elution, and that this will aid in understanding low latitude ice cores.https://www.cambridge.org/core/product/identifier/S0022143018000874/type/journal_articlemelt-surfacemountain glacierssnow and ice chemistry
spellingShingle GUANGJIAN WU
PEILIN LI
XUELEI ZHANG
CHENGLONG ZHANG
Using a geochemical method of dissolved and insoluble fractions to characterize surface snow melting and major element elution
Journal of Glaciology
melt-surface
mountain glaciers
snow and ice chemistry
title Using a geochemical method of dissolved and insoluble fractions to characterize surface snow melting and major element elution
title_full Using a geochemical method of dissolved and insoluble fractions to characterize surface snow melting and major element elution
title_fullStr Using a geochemical method of dissolved and insoluble fractions to characterize surface snow melting and major element elution
title_full_unstemmed Using a geochemical method of dissolved and insoluble fractions to characterize surface snow melting and major element elution
title_short Using a geochemical method of dissolved and insoluble fractions to characterize surface snow melting and major element elution
title_sort using a geochemical method of dissolved and insoluble fractions to characterize surface snow melting and major element elution
topic melt-surface
mountain glaciers
snow and ice chemistry
url https://www.cambridge.org/core/product/identifier/S0022143018000874/type/journal_article
work_keys_str_mv AT guangjianwu usingageochemicalmethodofdissolvedandinsolublefractionstocharacterizesurfacesnowmeltingandmajorelementelution
AT peilinli usingageochemicalmethodofdissolvedandinsolublefractionstocharacterizesurfacesnowmeltingandmajorelementelution
AT xueleizhang usingageochemicalmethodofdissolvedandinsolublefractionstocharacterizesurfacesnowmeltingandmajorelementelution
AT chenglongzhang usingageochemicalmethodofdissolvedandinsolublefractionstocharacterizesurfacesnowmeltingandmajorelementelution