Synthesis of SiC/BiOCl Composites and Its Efficient Photocatalytic Activity

BiOCl nanosheets nucleated and grew on cottage cheese-like SiC substrate via hydrothermal procedure, through which a tight heterojunction was formed. SiC/BiOCl composites with varied morphologies were acquired that the formation of BiOCl was involved with different form of carbon existed on surface...

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Main Authors: Wanli Liu, Qi Li, Xianglong Yang, Xiufang Chen, Xiangang Xu
Format: Article
Language:English
Published: MDPI AG 2020-08-01
Series:Catalysts
Subjects:
Online Access:https://www.mdpi.com/2073-4344/10/8/946
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author Wanli Liu
Qi Li
Xianglong Yang
Xiufang Chen
Xiangang Xu
author_facet Wanli Liu
Qi Li
Xianglong Yang
Xiufang Chen
Xiangang Xu
author_sort Wanli Liu
collection DOAJ
description BiOCl nanosheets nucleated and grew on cottage cheese-like SiC substrate via hydrothermal procedure, through which a tight heterojunction was formed. SiC/BiOCl composites with varied morphologies were acquired that the formation of BiOCl was involved with different form of carbon existed on surface of SiC. The photocatalytic mechanism analysis revealed that the combination of SiC and BOC significantly enhanced photocatalytic activities owing to the improved visible light utilization, efficient separation of photo-generated carriers, and promoted reactive area. The main active species during the photocatalytic reaction was determined as ·O<sup>2−</sup> radical by additionally adding trapping agent into the reactant. The SiC-BOC composites showed much higher photoactivities in photocurrent responses and photocatalytic degradation of TC-HCl, which mainly attributed to the well-built heterointerface promoted by Bi-C bonds and the interlaced structure obtained by increasing exposure of (010) facets in BiOCl. The nucleation, growth and combination architecture of BiOCl was all influenced by the involvement of SiC.
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spelling doaj.art-e748d124196440a08ce3131cef5afcfe2023-11-20T10:27:34ZengMDPI AGCatalysts2073-43442020-08-0110894610.3390/catal10080946Synthesis of SiC/BiOCl Composites and Its Efficient Photocatalytic ActivityWanli Liu0Qi Li1Xianglong Yang2Xiufang Chen3Xiangang Xu4State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, ChinaState Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, ChinaState Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, ChinaState Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, ChinaState Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, ChinaBiOCl nanosheets nucleated and grew on cottage cheese-like SiC substrate via hydrothermal procedure, through which a tight heterojunction was formed. SiC/BiOCl composites with varied morphologies were acquired that the formation of BiOCl was involved with different form of carbon existed on surface of SiC. The photocatalytic mechanism analysis revealed that the combination of SiC and BOC significantly enhanced photocatalytic activities owing to the improved visible light utilization, efficient separation of photo-generated carriers, and promoted reactive area. The main active species during the photocatalytic reaction was determined as ·O<sup>2−</sup> radical by additionally adding trapping agent into the reactant. The SiC-BOC composites showed much higher photoactivities in photocurrent responses and photocatalytic degradation of TC-HCl, which mainly attributed to the well-built heterointerface promoted by Bi-C bonds and the interlaced structure obtained by increasing exposure of (010) facets in BiOCl. The nucleation, growth and combination architecture of BiOCl was all influenced by the involvement of SiC.https://www.mdpi.com/2073-4344/10/8/946SiCBiOClphotocatalysisdegradation of TC-HClhydrogen production
spellingShingle Wanli Liu
Qi Li
Xianglong Yang
Xiufang Chen
Xiangang Xu
Synthesis of SiC/BiOCl Composites and Its Efficient Photocatalytic Activity
Catalysts
SiC
BiOCl
photocatalysis
degradation of TC-HCl
hydrogen production
title Synthesis of SiC/BiOCl Composites and Its Efficient Photocatalytic Activity
title_full Synthesis of SiC/BiOCl Composites and Its Efficient Photocatalytic Activity
title_fullStr Synthesis of SiC/BiOCl Composites and Its Efficient Photocatalytic Activity
title_full_unstemmed Synthesis of SiC/BiOCl Composites and Its Efficient Photocatalytic Activity
title_short Synthesis of SiC/BiOCl Composites and Its Efficient Photocatalytic Activity
title_sort synthesis of sic biocl composites and its efficient photocatalytic activity
topic SiC
BiOCl
photocatalysis
degradation of TC-HCl
hydrogen production
url https://www.mdpi.com/2073-4344/10/8/946
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AT xianglongyang synthesisofsicbioclcompositesanditsefficientphotocatalyticactivity
AT xiufangchen synthesisofsicbioclcompositesanditsefficientphotocatalyticactivity
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