Morphology and properties of a photopolymer/clay nanocomposite prepared by a rapid prototyping system

This study represents an in situ polymerization by preparation of tetrafunction polyester acrylate mixed with 1,6-hexanediol diacrylate/clay nanocomposite by digital light processor rapid prototyping. The morphology of nano-clay fillers and the dispersing agent in the photopolymer matrix are investi...

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Main Authors: Chiu Shih-Hsuan, Wicaksono Sigit Tri, Chen Kun-Ting, Pong Sheng-Hong
Format: Article
Language:English
Published: De Gruyter 2014-03-01
Series:Science and Engineering of Composite Materials
Subjects:
Online Access:https://doi.org/10.1515/secm-2012-0041
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author Chiu Shih-Hsuan
Wicaksono Sigit Tri
Chen Kun-Ting
Pong Sheng-Hong
author_facet Chiu Shih-Hsuan
Wicaksono Sigit Tri
Chen Kun-Ting
Pong Sheng-Hong
author_sort Chiu Shih-Hsuan
collection DOAJ
description This study represents an in situ polymerization by preparation of tetrafunction polyester acrylate mixed with 1,6-hexanediol diacrylate/clay nanocomposite by digital light processor rapid prototyping. The morphology of nano-clay fillers and the dispersing agent in the photopolymer matrix are investigated by scanning electron microscopy (SEM). Degradation temperature, tensile strength, impact strength, and hardness are characterized by using thermogravimetric analysis, universal tensile machine, Izod impact tester, and hardness shore A tester, respectively. Results show that the effect of clay loading with an appropriate amount of dispersant tends to significantly increase not only the tensile strength and hardness but also the degradation temperature of photopolymer/clay nanocomposite; however, the impact strength is not affected. In the same conditions, as visualized on SEM images, the nanocomposite tends to form the exfoliated structure with agglomeration of clay, which is caused by uneven distribution of nano-clay in the photopolymer matrix.
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spelling doaj.art-e7559623d6a24a8b8fa6d194f13d59d52022-12-21T22:40:54ZengDe GruyterScience and Engineering of Composite Materials0792-12332191-03592014-03-0121220521010.1515/secm-2012-0041Morphology and properties of a photopolymer/clay nanocomposite prepared by a rapid prototyping systemChiu Shih-Hsuan0Wicaksono Sigit TriChen Kun-Ting1Pong Sheng-Hong2Department of Materials Science and Engineering, National Taiwan University of Science and Technology, 43, Section 4, Keelung Road, Taipei, TaiwanDepartment of Materials Science and Engineering, National Taiwan University of Science and Technology, 43, Section 4, Keelung Road, Taipei, TaiwanDepartment of Creative Product and Technological Application, Lan Yang Institute of Technology, No. 79 Fu Shin Road, Tou Chen, I Lan 261, TaiwanThis study represents an in situ polymerization by preparation of tetrafunction polyester acrylate mixed with 1,6-hexanediol diacrylate/clay nanocomposite by digital light processor rapid prototyping. The morphology of nano-clay fillers and the dispersing agent in the photopolymer matrix are investigated by scanning electron microscopy (SEM). Degradation temperature, tensile strength, impact strength, and hardness are characterized by using thermogravimetric analysis, universal tensile machine, Izod impact tester, and hardness shore A tester, respectively. Results show that the effect of clay loading with an appropriate amount of dispersant tends to significantly increase not only the tensile strength and hardness but also the degradation temperature of photopolymer/clay nanocomposite; however, the impact strength is not affected. In the same conditions, as visualized on SEM images, the nanocomposite tends to form the exfoliated structure with agglomeration of clay, which is caused by uneven distribution of nano-clay in the photopolymer matrix.https://doi.org/10.1515/secm-2012-0041claydispersionsnanocompositesphotopolymerizationrapid prototyping
spellingShingle Chiu Shih-Hsuan
Wicaksono Sigit Tri
Chen Kun-Ting
Pong Sheng-Hong
Morphology and properties of a photopolymer/clay nanocomposite prepared by a rapid prototyping system
Science and Engineering of Composite Materials
clay
dispersions
nanocomposites
photopolymerization
rapid prototyping
title Morphology and properties of a photopolymer/clay nanocomposite prepared by a rapid prototyping system
title_full Morphology and properties of a photopolymer/clay nanocomposite prepared by a rapid prototyping system
title_fullStr Morphology and properties of a photopolymer/clay nanocomposite prepared by a rapid prototyping system
title_full_unstemmed Morphology and properties of a photopolymer/clay nanocomposite prepared by a rapid prototyping system
title_short Morphology and properties of a photopolymer/clay nanocomposite prepared by a rapid prototyping system
title_sort morphology and properties of a photopolymer clay nanocomposite prepared by a rapid prototyping system
topic clay
dispersions
nanocomposites
photopolymerization
rapid prototyping
url https://doi.org/10.1515/secm-2012-0041
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AT wicaksonosigittri morphologyandpropertiesofaphotopolymerclaynanocompositepreparedbyarapidprototypingsystem
AT chenkunting morphologyandpropertiesofaphotopolymerclaynanocompositepreparedbyarapidprototypingsystem
AT pongshenghong morphologyandpropertiesofaphotopolymerclaynanocompositepreparedbyarapidprototypingsystem