Visible light photocatalytic degradation of 4-chlorophenol using C/ZnO/CdS nanocomposite

C/ZnO/CdS nanocomposite was synthesized using the microemulsion method. Nanocomposite synthesized in the present work was characterized using X-ray diffractometer (XRD), scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDX) transmission electron microscope (TEM), diffuse ref...

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Main Authors: Atul B. Lavand, Yuvraj S. Malghe
Format: Article
Language:English
Published: Elsevier 2015-09-01
Series:Journal of Saudi Chemical Society
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1319610315000897
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author Atul B. Lavand
Yuvraj S. Malghe
author_facet Atul B. Lavand
Yuvraj S. Malghe
author_sort Atul B. Lavand
collection DOAJ
description C/ZnO/CdS nanocomposite was synthesized using the microemulsion method. Nanocomposite synthesized in the present work was characterized using X-ray diffractometer (XRD), scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDX) transmission electron microscope (TEM), diffuse reflectance and photoluminescence (PL) spectroscopy. TEM study shows that CdS nanoparticles are successfully anchored on the surface of C doped ZnO nanorods. UV–visible spectrum of C/ZnO/CdS nanocomposite shows a red shift. CdS nanoparticles work as photo sensitizers to expand the photo-response of C doped ZnO to the visible region. Photoluminescence (PL) spectroscopy reveals evidence for interaction between C/ZnO and CdS. PL quenching observed for C/ZnO/CdS nanocomposite is attributed to improved charge separation properties, which increases its photocatalytic efficiency. C/ZnO/CdS nanocomposite exhibits exceptionally high photocatalytic activity for degradation of 4-chlorophenol (CP) via Z-scheme mechanism. C/ZnO/CdS nanocomposite is a highly stable and reusable photocatalyst.
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spelling doaj.art-e78d3e7f22fb4d8197e98597ab2314912022-12-22T00:23:39ZengElsevierJournal of Saudi Chemical Society1319-61032015-09-0119547147810.1016/j.jscs.2015.07.001Visible light photocatalytic degradation of 4-chlorophenol using C/ZnO/CdS nanocompositeAtul B. LavandYuvraj S. MalgheC/ZnO/CdS nanocomposite was synthesized using the microemulsion method. Nanocomposite synthesized in the present work was characterized using X-ray diffractometer (XRD), scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDX) transmission electron microscope (TEM), diffuse reflectance and photoluminescence (PL) spectroscopy. TEM study shows that CdS nanoparticles are successfully anchored on the surface of C doped ZnO nanorods. UV–visible spectrum of C/ZnO/CdS nanocomposite shows a red shift. CdS nanoparticles work as photo sensitizers to expand the photo-response of C doped ZnO to the visible region. Photoluminescence (PL) spectroscopy reveals evidence for interaction between C/ZnO and CdS. PL quenching observed for C/ZnO/CdS nanocomposite is attributed to improved charge separation properties, which increases its photocatalytic efficiency. C/ZnO/CdS nanocomposite exhibits exceptionally high photocatalytic activity for degradation of 4-chlorophenol (CP) via Z-scheme mechanism. C/ZnO/CdS nanocomposite is a highly stable and reusable photocatalyst.http://www.sciencedirect.com/science/article/pii/S1319610315000897Visible lightPhotocatalysisC doped ZnOCdSNanocomposite
spellingShingle Atul B. Lavand
Yuvraj S. Malghe
Visible light photocatalytic degradation of 4-chlorophenol using C/ZnO/CdS nanocomposite
Journal of Saudi Chemical Society
Visible light
Photocatalysis
C doped ZnO
CdS
Nanocomposite
title Visible light photocatalytic degradation of 4-chlorophenol using C/ZnO/CdS nanocomposite
title_full Visible light photocatalytic degradation of 4-chlorophenol using C/ZnO/CdS nanocomposite
title_fullStr Visible light photocatalytic degradation of 4-chlorophenol using C/ZnO/CdS nanocomposite
title_full_unstemmed Visible light photocatalytic degradation of 4-chlorophenol using C/ZnO/CdS nanocomposite
title_short Visible light photocatalytic degradation of 4-chlorophenol using C/ZnO/CdS nanocomposite
title_sort visible light photocatalytic degradation of 4 chlorophenol using c zno cds nanocomposite
topic Visible light
Photocatalysis
C doped ZnO
CdS
Nanocomposite
url http://www.sciencedirect.com/science/article/pii/S1319610315000897
work_keys_str_mv AT atulblavand visiblelightphotocatalyticdegradationof4chlorophenolusingcznocdsnanocomposite
AT yuvrajsmalghe visiblelightphotocatalyticdegradationof4chlorophenolusingcznocdsnanocomposite