Triarylazoimidazole-Zn<sup>II</sup>, Cd<sup>II</sup>, and Hg<sup>II</sup> Complexes: Structures, Photophysics, and Antibacterial Properties
Novel triarylazoimidazoles containing strong electron donors (<i>p</i>-NEt<sub>2</sub>) or acceptors (<i>p</i>-NO<sub>2</sub>) by the azoaryl group, and their group 12 metal complexes were synthesized and fully characterized, including X-ray analysis f...
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2022-05-01
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| author | Alexey A. Artemjev Artyom A. Astafiev Anna V. Vologzhanina Alexey S. Kubasov Gleb M. Burkin Alexander S. Novikov Andreii S. Kritchenkov Anatoly A. Kirichuk Alexander G. Tskhovrebov |
| author_facet | Alexey A. Artemjev Artyom A. Astafiev Anna V. Vologzhanina Alexey S. Kubasov Gleb M. Burkin Alexander S. Novikov Andreii S. Kritchenkov Anatoly A. Kirichuk Alexander G. Tskhovrebov |
| author_sort | Alexey A. Artemjev |
| collection | DOAJ |
| description | Novel triarylazoimidazoles containing strong electron donors (<i>p</i>-NEt<sub>2</sub>) or acceptors (<i>p</i>-NO<sub>2</sub>) by the azoaryl group, and their group 12 metal complexes were synthesized and fully characterized, including X-ray analysis for several complexes. Novel complexes exhibit red photo-luminescence emission (<i>Φ</i> up to 0.21) in a solution. Moreover, the antibacterial activity of complexes was tested against Gram-positive microorganism <i>S</i>. <i>aureus</i> and Gram-negative microorganism <i>E</i>. <i>coli</i>. |
| first_indexed | 2024-03-10T03:05:17Z |
| format | Article |
| id | doaj.art-e797bb1f041e49b0b6639282a4e2a8ae |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-03-10T03:05:17Z |
| publishDate | 2022-05-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Crystals |
| spelling | doaj.art-e797bb1f041e49b0b6639282a4e2a8ae2023-11-23T10:35:23ZengMDPI AGCrystals2073-43522022-05-0112568010.3390/cryst12050680Triarylazoimidazole-Zn<sup>II</sup>, Cd<sup>II</sup>, and Hg<sup>II</sup> Complexes: Structures, Photophysics, and Antibacterial PropertiesAlexey A. Artemjev0Artyom A. Astafiev1Anna V. Vologzhanina2Alexey S. Kubasov3Gleb M. Burkin4Alexander S. Novikov5Andreii S. Kritchenkov6Anatoly A. Kirichuk7Alexander G. Tskhovrebov8Research Institute of Chemistry, Peoples’ Friendship University of Russia, Miklukho-Maklaya Str. 6, 117198 Moscow, RussiaN.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Kosygina 4, 119991 Moscow, RussiaA.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova Str. 28, 119334 Moscow, RussiaN.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninsky Prt. 31, 119071 Moscow, RussiaResearch Institute of Chemistry, Peoples’ Friendship University of Russia, Miklukho-Maklaya Str. 6, 117198 Moscow, RussiaInstitute of Chemistry Saint Petersburg State University, Universitetskaya Nab. 7/9, 199034 Saint Petersburg, RussiaResearch Institute of Chemistry, Peoples’ Friendship University of Russia, Miklukho-Maklaya Str. 6, 117198 Moscow, RussiaResearch Institute of Chemistry, Peoples’ Friendship University of Russia, Miklukho-Maklaya Str. 6, 117198 Moscow, RussiaResearch Institute of Chemistry, Peoples’ Friendship University of Russia, Miklukho-Maklaya Str. 6, 117198 Moscow, RussiaNovel triarylazoimidazoles containing strong electron donors (<i>p</i>-NEt<sub>2</sub>) or acceptors (<i>p</i>-NO<sub>2</sub>) by the azoaryl group, and their group 12 metal complexes were synthesized and fully characterized, including X-ray analysis for several complexes. Novel complexes exhibit red photo-luminescence emission (<i>Φ</i> up to 0.21) in a solution. Moreover, the antibacterial activity of complexes was tested against Gram-positive microorganism <i>S</i>. <i>aureus</i> and Gram-negative microorganism <i>E</i>. <i>coli</i>.https://www.mdpi.com/2073-4352/12/5/680azo dyesnitrogen heterocyclesfluorescencephotoswitchable materialsZnCd |
| spellingShingle | Alexey A. Artemjev Artyom A. Astafiev Anna V. Vologzhanina Alexey S. Kubasov Gleb M. Burkin Alexander S. Novikov Andreii S. Kritchenkov Anatoly A. Kirichuk Alexander G. Tskhovrebov Triarylazoimidazole-Zn<sup>II</sup>, Cd<sup>II</sup>, and Hg<sup>II</sup> Complexes: Structures, Photophysics, and Antibacterial Properties Crystals azo dyes nitrogen heterocycles fluorescence photoswitchable materials Zn Cd |
| title | Triarylazoimidazole-Zn<sup>II</sup>, Cd<sup>II</sup>, and Hg<sup>II</sup> Complexes: Structures, Photophysics, and Antibacterial Properties |
| title_full | Triarylazoimidazole-Zn<sup>II</sup>, Cd<sup>II</sup>, and Hg<sup>II</sup> Complexes: Structures, Photophysics, and Antibacterial Properties |
| title_fullStr | Triarylazoimidazole-Zn<sup>II</sup>, Cd<sup>II</sup>, and Hg<sup>II</sup> Complexes: Structures, Photophysics, and Antibacterial Properties |
| title_full_unstemmed | Triarylazoimidazole-Zn<sup>II</sup>, Cd<sup>II</sup>, and Hg<sup>II</sup> Complexes: Structures, Photophysics, and Antibacterial Properties |
| title_short | Triarylazoimidazole-Zn<sup>II</sup>, Cd<sup>II</sup>, and Hg<sup>II</sup> Complexes: Structures, Photophysics, and Antibacterial Properties |
| title_sort | triarylazoimidazole zn sup ii sup cd sup ii sup and hg sup ii sup complexes structures photophysics and antibacterial properties |
| topic | azo dyes nitrogen heterocycles fluorescence photoswitchable materials Zn Cd |
| url | https://www.mdpi.com/2073-4352/12/5/680 |
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