Biochar from Agro-Forest Residue: Application Perspective Based on Decision Support Analysis

The present work aims at (a) carbonizing agriculture biomass residue; (b) characterizing the obtained biochar; and (c) exploring its potential use for energy/resource recovery purposes. Six types of biomass were carbonized. The biochar was investigated through scanning electron microscopy with energ...

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Main Authors: Tsvetelina Petrova, Iliyana Naydenova, João Ribau, Ana F. Ferreira
Format: Article
Language:English
Published: MDPI AG 2023-03-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/13/5/3240
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author Tsvetelina Petrova
Iliyana Naydenova
João Ribau
Ana F. Ferreira
author_facet Tsvetelina Petrova
Iliyana Naydenova
João Ribau
Ana F. Ferreira
author_sort Tsvetelina Petrova
collection DOAJ
description The present work aims at (a) carbonizing agriculture biomass residue; (b) characterizing the obtained biochar; and (c) exploring its potential use for energy/resource recovery purposes. Six types of biomass were carbonized. The biochar was investigated through scanning electron microscopy with energy dispersive X-ray spectroscopy detector, thermogravimetric (TGA), proximate, ultimate, and Brunauer–Emmett–Teller analyses, along with bulk density, pH, electrical conductivity, and salt content measurements. The results served as input data for multi-criteria, multi-objective decision analysis of biochar, aiming to evaluate its best application prospective. The TGA identified two general stages: devolatilization (stage 2: 180–560 °C), and combustion (stage 3: 560–720 °C). The activation energy of stage 2 decreased with an increasing heating rate, but the opposite trend was observed for stage 3. The biochar CO<sub>2</sub> adsorption suggested possible applications beyond energy conversion technologies. The decision support analysis revealed that peach stones, cherry stones, and grape pomace biochar achieved the most promising results for all evaluated applications (biofuel; catalyst; CO<sub>2</sub> sequestration and soil amendment; supercapacitor) in contrast to colza, softwood, or sunflower husks char.
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spelling doaj.art-e7bfe147ea1d4f6ba39998da3f53cc672023-11-17T07:21:11ZengMDPI AGApplied Sciences2076-34172023-03-01135324010.3390/app13053240Biochar from Agro-Forest Residue: Application Perspective Based on Decision Support AnalysisTsvetelina Petrova0Iliyana Naydenova1João Ribau2Ana F. Ferreira3Technical College-Sofia, Technical University of Sofia, 1000 Sofia, BulgariaTechnical College-Sofia, Technical University of Sofia, 1000 Sofia, BulgariaAgência Nacional de Inovação (ANI), 1649-038 Lisboa, PortugalIDMEC, Instituto Superior Técnico, Universidade de Lisboa, 1049-001 Lisboa, PortugalThe present work aims at (a) carbonizing agriculture biomass residue; (b) characterizing the obtained biochar; and (c) exploring its potential use for energy/resource recovery purposes. Six types of biomass were carbonized. The biochar was investigated through scanning electron microscopy with energy dispersive X-ray spectroscopy detector, thermogravimetric (TGA), proximate, ultimate, and Brunauer–Emmett–Teller analyses, along with bulk density, pH, electrical conductivity, and salt content measurements. The results served as input data for multi-criteria, multi-objective decision analysis of biochar, aiming to evaluate its best application prospective. The TGA identified two general stages: devolatilization (stage 2: 180–560 °C), and combustion (stage 3: 560–720 °C). The activation energy of stage 2 decreased with an increasing heating rate, but the opposite trend was observed for stage 3. The biochar CO<sub>2</sub> adsorption suggested possible applications beyond energy conversion technologies. The decision support analysis revealed that peach stones, cherry stones, and grape pomace biochar achieved the most promising results for all evaluated applications (biofuel; catalyst; CO<sub>2</sub> sequestration and soil amendment; supercapacitor) in contrast to colza, softwood, or sunflower husks char.https://www.mdpi.com/2076-3417/13/5/3240biomasscarbonizationbiochar characterizationdecision support analysis
spellingShingle Tsvetelina Petrova
Iliyana Naydenova
João Ribau
Ana F. Ferreira
Biochar from Agro-Forest Residue: Application Perspective Based on Decision Support Analysis
Applied Sciences
biomass
carbonization
biochar characterization
decision support analysis
title Biochar from Agro-Forest Residue: Application Perspective Based on Decision Support Analysis
title_full Biochar from Agro-Forest Residue: Application Perspective Based on Decision Support Analysis
title_fullStr Biochar from Agro-Forest Residue: Application Perspective Based on Decision Support Analysis
title_full_unstemmed Biochar from Agro-Forest Residue: Application Perspective Based on Decision Support Analysis
title_short Biochar from Agro-Forest Residue: Application Perspective Based on Decision Support Analysis
title_sort biochar from agro forest residue application perspective based on decision support analysis
topic biomass
carbonization
biochar characterization
decision support analysis
url https://www.mdpi.com/2076-3417/13/5/3240
work_keys_str_mv AT tsvetelinapetrova biocharfromagroforestresidueapplicationperspectivebasedondecisionsupportanalysis
AT iliyananaydenova biocharfromagroforestresidueapplicationperspectivebasedondecisionsupportanalysis
AT joaoribau biocharfromagroforestresidueapplicationperspectivebasedondecisionsupportanalysis
AT anafferreira biocharfromagroforestresidueapplicationperspectivebasedondecisionsupportanalysis