Mono- and Dinuclear Aluminium Complexes Derived from Biguanide and Carbothiamide Ligands
Dianionic N,N-chelating ligands play a crucial role in coordination chemistry, but reports on related complexes remain limited to certain types of ligands. In here, the reactions of two diprotic ligands, i.e., a biguanide and a carbothiamide, with trimethylaluminium, are reported, which give rise to...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2021-07-01
|
| Series: | Inorganics |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2304-6740/9/7/52 |
| _version_ | 1827687543499390976 |
|---|---|
| author | Maximilian Dehmel Helmar Görls Robert Kretschmer |
| author_facet | Maximilian Dehmel Helmar Görls Robert Kretschmer |
| author_sort | Maximilian Dehmel |
| collection | DOAJ |
| description | Dianionic N,N-chelating ligands play a crucial role in coordination chemistry, but reports on related complexes remain limited to certain types of ligands. In here, the reactions of two diprotic ligands, i.e., a biguanide and a carbothiamide, with trimethylaluminium, are reported, which give rise to mono- and dinuclear aluminium(III) complexes. In addition, single deprotonation of the diprotic biguanide using potassium bis(trimethylsilyl)amide gives rise to a one-dimensional coordination polymer. All complexes have been fully characterized, and their solid-state structures were determined by single crystal X-ray diffraction analysis. |
| first_indexed | 2024-03-10T09:36:47Z |
| format | Article |
| id | doaj.art-e7c89fc6fa17477b8602567e9398676b |
| institution | Directory Open Access Journal |
| issn | 2304-6740 |
| language | English |
| last_indexed | 2024-03-10T09:36:47Z |
| publishDate | 2021-07-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Inorganics |
| spelling | doaj.art-e7c89fc6fa17477b8602567e9398676b2023-11-22T04:04:06ZengMDPI AGInorganics2304-67402021-07-01975210.3390/inorganics9070052Mono- and Dinuclear Aluminium Complexes Derived from Biguanide and Carbothiamide LigandsMaximilian Dehmel0Helmar Görls1Robert Kretschmer2Institute of Inorganic and Analytical Chemistry, Friedrich Schiller University Jena, Humboldtstraße 8, 07743 Jena, GermanyInstitute of Inorganic and Analytical Chemistry, Friedrich Schiller University Jena, Humboldtstraße 8, 07743 Jena, GermanyInstitute of Inorganic and Analytical Chemistry, Friedrich Schiller University Jena, Humboldtstraße 8, 07743 Jena, GermanyDianionic N,N-chelating ligands play a crucial role in coordination chemistry, but reports on related complexes remain limited to certain types of ligands. In here, the reactions of two diprotic ligands, i.e., a biguanide and a carbothiamide, with trimethylaluminium, are reported, which give rise to mono- and dinuclear aluminium(III) complexes. In addition, single deprotonation of the diprotic biguanide using potassium bis(trimethylsilyl)amide gives rise to a one-dimensional coordination polymer. All complexes have been fully characterized, and their solid-state structures were determined by single crystal X-ray diffraction analysis.https://www.mdpi.com/2304-6740/9/7/52aluminiumbiguanidesligand designnitrogen ligands |
| spellingShingle | Maximilian Dehmel Helmar Görls Robert Kretschmer Mono- and Dinuclear Aluminium Complexes Derived from Biguanide and Carbothiamide Ligands Inorganics aluminium biguanides ligand design nitrogen ligands |
| title | Mono- and Dinuclear Aluminium Complexes Derived from Biguanide and Carbothiamide Ligands |
| title_full | Mono- and Dinuclear Aluminium Complexes Derived from Biguanide and Carbothiamide Ligands |
| title_fullStr | Mono- and Dinuclear Aluminium Complexes Derived from Biguanide and Carbothiamide Ligands |
| title_full_unstemmed | Mono- and Dinuclear Aluminium Complexes Derived from Biguanide and Carbothiamide Ligands |
| title_short | Mono- and Dinuclear Aluminium Complexes Derived from Biguanide and Carbothiamide Ligands |
| title_sort | mono and dinuclear aluminium complexes derived from biguanide and carbothiamide ligands |
| topic | aluminium biguanides ligand design nitrogen ligands |
| url | https://www.mdpi.com/2304-6740/9/7/52 |
| work_keys_str_mv | AT maximiliandehmel monoanddinuclearaluminiumcomplexesderivedfrombiguanideandcarbothiamideligands AT helmargorls monoanddinuclearaluminiumcomplexesderivedfrombiguanideandcarbothiamideligands AT robertkretschmer monoanddinuclearaluminiumcomplexesderivedfrombiguanideandcarbothiamideligands |