Synthesis and Behavior of Hexamethylenetetramine-Based Ionic Liquids as an Active Ingredient in Latent Curing Formulations with Ethylene Glycol for DGEBA
The paper presents the preparation of new ionic liquids based on hexamethylenetetramine with bis(trifluoromethanesulfonyl)imide and dicyanamide anion, which were characterized in detail in terms of their purity (Ion Chromatography) and thermal properties (Differential Scanning Calorimetry), as well...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2023-01-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/28/2/892 |
| _version_ | 1827622852336025600 |
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| author | Dawid Zielinski Andrea Szpecht Paulina Hinc Marcin Smiglak |
| author_facet | Dawid Zielinski Andrea Szpecht Paulina Hinc Marcin Smiglak |
| author_sort | Dawid Zielinski |
| collection | DOAJ |
| description | The paper presents the preparation of new ionic liquids based on hexamethylenetetramine with bis(trifluoromethanesulfonyl)imide and dicyanamide anion, which were characterized in detail in terms of their purity (Ion Chromatography) and thermal properties (Differential Scanning Calorimetry), as well as stability. The obtained substances were used to develop curing systems with ethylene glycol, which were successfully tested for their application with bisphenol A diglycidyl ether molecule. In addition, the curing process and its relationship to the structure of the ionic liquid are characterized in detail. The research showed that hexamethylenetetramine-based new ionic liquids can be successfully designed using well-known and simple synthetic methods—the Delepine reaction. Moreover, attention was paid to their stability, related limitations, and the application of hexamethylenetetramine-based ionic liquids in epoxy-curing systems. |
| first_indexed | 2024-03-09T11:33:59Z |
| format | Article |
| id | doaj.art-e7eac0ba9e6a49fa95f0492f80366867 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-09T11:33:59Z |
| publishDate | 2023-01-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-e7eac0ba9e6a49fa95f0492f803668672023-11-30T23:46:25ZengMDPI AGMolecules1420-30492023-01-0128289210.3390/molecules28020892Synthesis and Behavior of Hexamethylenetetramine-Based Ionic Liquids as an Active Ingredient in Latent Curing Formulations with Ethylene Glycol for DGEBADawid Zielinski0Andrea Szpecht1Paulina Hinc2Marcin Smiglak3Poznan Science and Technology Park, Adam Mickiewicz University Foundation, 61-612 Poznań, PolandPoznan Science and Technology Park, Adam Mickiewicz University Foundation, 61-612 Poznań, PolandFaculty of Chemistry, Adam Mickiewicz University in Poznań, 61-614 Poznań, PolandPoznan Science and Technology Park, Adam Mickiewicz University Foundation, 61-612 Poznań, PolandThe paper presents the preparation of new ionic liquids based on hexamethylenetetramine with bis(trifluoromethanesulfonyl)imide and dicyanamide anion, which were characterized in detail in terms of their purity (Ion Chromatography) and thermal properties (Differential Scanning Calorimetry), as well as stability. The obtained substances were used to develop curing systems with ethylene glycol, which were successfully tested for their application with bisphenol A diglycidyl ether molecule. In addition, the curing process and its relationship to the structure of the ionic liquid are characterized in detail. The research showed that hexamethylenetetramine-based new ionic liquids can be successfully designed using well-known and simple synthetic methods—the Delepine reaction. Moreover, attention was paid to their stability, related limitations, and the application of hexamethylenetetramine-based ionic liquids in epoxy-curing systems.https://www.mdpi.com/1420-3049/28/2/892hexamethylenetetramineionic liquidsepoxy resinethylene glycolcuring agentcomposites |
| spellingShingle | Dawid Zielinski Andrea Szpecht Paulina Hinc Marcin Smiglak Synthesis and Behavior of Hexamethylenetetramine-Based Ionic Liquids as an Active Ingredient in Latent Curing Formulations with Ethylene Glycol for DGEBA Molecules hexamethylenetetramine ionic liquids epoxy resin ethylene glycol curing agent composites |
| title | Synthesis and Behavior of Hexamethylenetetramine-Based Ionic Liquids as an Active Ingredient in Latent Curing Formulations with Ethylene Glycol for DGEBA |
| title_full | Synthesis and Behavior of Hexamethylenetetramine-Based Ionic Liquids as an Active Ingredient in Latent Curing Formulations with Ethylene Glycol for DGEBA |
| title_fullStr | Synthesis and Behavior of Hexamethylenetetramine-Based Ionic Liquids as an Active Ingredient in Latent Curing Formulations with Ethylene Glycol for DGEBA |
| title_full_unstemmed | Synthesis and Behavior of Hexamethylenetetramine-Based Ionic Liquids as an Active Ingredient in Latent Curing Formulations with Ethylene Glycol for DGEBA |
| title_short | Synthesis and Behavior of Hexamethylenetetramine-Based Ionic Liquids as an Active Ingredient in Latent Curing Formulations with Ethylene Glycol for DGEBA |
| title_sort | synthesis and behavior of hexamethylenetetramine based ionic liquids as an active ingredient in latent curing formulations with ethylene glycol for dgeba |
| topic | hexamethylenetetramine ionic liquids epoxy resin ethylene glycol curing agent composites |
| url | https://www.mdpi.com/1420-3049/28/2/892 |
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