Highly Selective Bio-hydrocarbon Production using Sidoarjo Mud Based-Catalysts in the Hydrocracking of Waste Palm Cooking Oil
In this work, Lapindo mud (LM) was used as catalyst support. This is because the Lapindo mud has a high SiO2 content of 45.33 %. This research aims to produce a hydrocracking catalyst based on Lapindo mud through impregnation of Ni and Pt metals as well as grafting amine groups. Ni and Pt metals imp...
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Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
2022-12-01
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Series: | Bulletin of Chemical Reaction Engineering & Catalysis |
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Online Access: | https://journal.bcrec.id/index.php/bcrec/article/view/15472 |
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author | Wega Trisunaryanti Triyono Triyono Iip Izul Fallah Shafira Salsiah Gesha Desy Alisha |
author_facet | Wega Trisunaryanti Triyono Triyono Iip Izul Fallah Shafira Salsiah Gesha Desy Alisha |
author_sort | Wega Trisunaryanti |
collection | DOAJ |
description | In this work, Lapindo mud (LM) was used as catalyst support. This is because the Lapindo mud has a high SiO2 content of 45.33 %. This research aims to produce a hydrocracking catalyst based on Lapindo mud through impregnation of Ni and Pt metals as well as grafting amine groups. Ni and Pt metals impregnation using wet impregnation method followed by amine group grafting. The best catalyst in this study was NiPt-NH2/LM which contained Ni and Pt metals, surface area, and pore diameters of 1.68 wt.% and 0.4 wt.%, 6.59 m2/g, 15.51 nm, respectively. The effectiveness of the catalyst was tested against temperature and catalyst: feed ratio. The catalyst with the best activity and selectivity was tested for reusability 3 times through hydrocracking process. The yield of liquid products obtained in the hydrocracking process of WPO using NiPt-NH2/LM catalyst with the optimum temperature and the weight ratio of catalyst:feed at 550 oC was 79.4 wt. % which consists of hydrocarbon compound of 55.9 wt.%. The yield of liquid products obtained in the hydrocracking WPO using the used NiPt-BH2/LM catalyst was 28.4 wt.% which consists of hydrocarbon compound of 23.6 wt.%. Copyright © 2022 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). |
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institution | Directory Open Access Journal |
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language | English |
last_indexed | 2024-03-11T22:52:10Z |
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publisher | Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) |
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spelling | doaj.art-e7f5fdc31c574ad4b2ca81376357c0db2023-09-22T03:27:22ZengMasyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)Bulletin of Chemical Reaction Engineering & Catalysis1978-29932022-12-0117471272410.9767/bcrec.17.4.15472.712-7246958Highly Selective Bio-hydrocarbon Production using Sidoarjo Mud Based-Catalysts in the Hydrocracking of Waste Palm Cooking OilWega Trisunaryanti0Triyono Triyono1Iip Izul Fallah2Shafira Salsiah3Gesha Desy Alisha4Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, IndonesiaIn this work, Lapindo mud (LM) was used as catalyst support. This is because the Lapindo mud has a high SiO2 content of 45.33 %. This research aims to produce a hydrocracking catalyst based on Lapindo mud through impregnation of Ni and Pt metals as well as grafting amine groups. Ni and Pt metals impregnation using wet impregnation method followed by amine group grafting. The best catalyst in this study was NiPt-NH2/LM which contained Ni and Pt metals, surface area, and pore diameters of 1.68 wt.% and 0.4 wt.%, 6.59 m2/g, 15.51 nm, respectively. The effectiveness of the catalyst was tested against temperature and catalyst: feed ratio. The catalyst with the best activity and selectivity was tested for reusability 3 times through hydrocracking process. The yield of liquid products obtained in the hydrocracking process of WPO using NiPt-NH2/LM catalyst with the optimum temperature and the weight ratio of catalyst:feed at 550 oC was 79.4 wt. % which consists of hydrocarbon compound of 55.9 wt.%. The yield of liquid products obtained in the hydrocracking WPO using the used NiPt-BH2/LM catalyst was 28.4 wt.% which consists of hydrocarbon compound of 23.6 wt.%. Copyright © 2022 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).https://journal.bcrec.id/index.php/bcrec/article/view/15472bimetallic ni-pthydrocrackingammonia-functionalized catalystmud catalystreusable catalyst |
spellingShingle | Wega Trisunaryanti Triyono Triyono Iip Izul Fallah Shafira Salsiah Gesha Desy Alisha Highly Selective Bio-hydrocarbon Production using Sidoarjo Mud Based-Catalysts in the Hydrocracking of Waste Palm Cooking Oil Bulletin of Chemical Reaction Engineering & Catalysis bimetallic ni-pt hydrocracking ammonia-functionalized catalyst mud catalyst reusable catalyst |
title | Highly Selective Bio-hydrocarbon Production using Sidoarjo Mud Based-Catalysts in the Hydrocracking of Waste Palm Cooking Oil |
title_full | Highly Selective Bio-hydrocarbon Production using Sidoarjo Mud Based-Catalysts in the Hydrocracking of Waste Palm Cooking Oil |
title_fullStr | Highly Selective Bio-hydrocarbon Production using Sidoarjo Mud Based-Catalysts in the Hydrocracking of Waste Palm Cooking Oil |
title_full_unstemmed | Highly Selective Bio-hydrocarbon Production using Sidoarjo Mud Based-Catalysts in the Hydrocracking of Waste Palm Cooking Oil |
title_short | Highly Selective Bio-hydrocarbon Production using Sidoarjo Mud Based-Catalysts in the Hydrocracking of Waste Palm Cooking Oil |
title_sort | highly selective bio hydrocarbon production using sidoarjo mud based catalysts in the hydrocracking of waste palm cooking oil |
topic | bimetallic ni-pt hydrocracking ammonia-functionalized catalyst mud catalyst reusable catalyst |
url | https://journal.bcrec.id/index.php/bcrec/article/view/15472 |
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