Bis(2-Cyclooctylidenehydrazene-1-carbothioamide)Zinc(II), a good single source precursor for ZnS nanoparticles – Synthesis and crystal structure
2-Cyclooctylidenehydrazene-1-carbothioamide and its Zinc complex Bis(2-Cyclooctylidenehydrazene-1-carbothioamide)Zinc(II), [(C9H16N3S)2Zn] that can be used as a single source precursor for ZnS, were synthesized and characterised by CHNS analysis, IR and SCXRD studies. The complex was found to belong...
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| Format: | Article |
| Language: | English |
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Elsevier
2022-01-01
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| Series: | Results in Chemistry |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2211715622003204 |
| _version_ | 1798006349627392000 |
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| author | Jisha George G. Rathika Nath K. Rajesh |
| author_facet | Jisha George G. Rathika Nath K. Rajesh |
| author_sort | Jisha George |
| collection | DOAJ |
| description | 2-Cyclooctylidenehydrazene-1-carbothioamide and its Zinc complex Bis(2-Cyclooctylidenehydrazene-1-carbothioamide)Zinc(II), [(C9H16N3S)2Zn] that can be used as a single source precursor for ZnS, were synthesized and characterised by CHNS analysis, IR and SCXRD studies. The complex was found to belong to Monoclinic crystal system with space group P21/n, where a = 15.9645(17) Å, b = 15.2974(12) Å, c = 19.185(2) Å, α = 90° β = 110.142(3)°, γ = 90°, V = 4398.6(7) Å3 and Z = 8 and also a number of short term interactions involving four inter molecular hydrogen bonds make possible a three dimensional lattice structure for this crystal. Thermal decomposition of this precursor complex by polyol method in a high boiling solvent Glycerol gave high quality mono-dispersed crystalline ZnS nanoparticles having size ranges between 4.51 and 8.76 nm with homogenous distribution. Further characterisation studies of these particles were done by SEM, EDX, TEM, PXRD, UV and PL. |
| first_indexed | 2024-04-11T12:53:21Z |
| format | Article |
| id | doaj.art-e7f69c8127be4d848724874f4fd66317 |
| institution | Directory Open Access Journal |
| issn | 2211-7156 |
| language | English |
| last_indexed | 2024-04-11T12:53:21Z |
| publishDate | 2022-01-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Results in Chemistry |
| spelling | doaj.art-e7f69c8127be4d848724874f4fd663172022-12-22T04:23:08ZengElsevierResults in Chemistry2211-71562022-01-014100601Bis(2-Cyclooctylidenehydrazene-1-carbothioamide)Zinc(II), a good single source precursor for ZnS nanoparticles – Synthesis and crystal structureJisha George0G. Rathika Nath1K. Rajesh2Department of Chemistry, University College, Trivandrum, India (Research Centre, University of Kerala)Department of Chemistry, KSM DB College, Sasthamcotta, Kerala, India (Research Centre, University of Kerala)Department of Chemistry, University College, Trivandrum, India (Research Centre, University of Kerala); Corresponding author.2-Cyclooctylidenehydrazene-1-carbothioamide and its Zinc complex Bis(2-Cyclooctylidenehydrazene-1-carbothioamide)Zinc(II), [(C9H16N3S)2Zn] that can be used as a single source precursor for ZnS, were synthesized and characterised by CHNS analysis, IR and SCXRD studies. The complex was found to belong to Monoclinic crystal system with space group P21/n, where a = 15.9645(17) Å, b = 15.2974(12) Å, c = 19.185(2) Å, α = 90° β = 110.142(3)°, γ = 90°, V = 4398.6(7) Å3 and Z = 8 and also a number of short term interactions involving four inter molecular hydrogen bonds make possible a three dimensional lattice structure for this crystal. Thermal decomposition of this precursor complex by polyol method in a high boiling solvent Glycerol gave high quality mono-dispersed crystalline ZnS nanoparticles having size ranges between 4.51 and 8.76 nm with homogenous distribution. Further characterisation studies of these particles were done by SEM, EDX, TEM, PXRD, UV and PL.http://www.sciencedirect.com/science/article/pii/S2211715622003204CarbothioamideSingle source precursorThermal decompositionPolyol methodNano particle |
| spellingShingle | Jisha George G. Rathika Nath K. Rajesh Bis(2-Cyclooctylidenehydrazene-1-carbothioamide)Zinc(II), a good single source precursor for ZnS nanoparticles – Synthesis and crystal structure Results in Chemistry Carbothioamide Single source precursor Thermal decomposition Polyol method Nano particle |
| title | Bis(2-Cyclooctylidenehydrazene-1-carbothioamide)Zinc(II), a good single source precursor for ZnS nanoparticles – Synthesis and crystal structure |
| title_full | Bis(2-Cyclooctylidenehydrazene-1-carbothioamide)Zinc(II), a good single source precursor for ZnS nanoparticles – Synthesis and crystal structure |
| title_fullStr | Bis(2-Cyclooctylidenehydrazene-1-carbothioamide)Zinc(II), a good single source precursor for ZnS nanoparticles – Synthesis and crystal structure |
| title_full_unstemmed | Bis(2-Cyclooctylidenehydrazene-1-carbothioamide)Zinc(II), a good single source precursor for ZnS nanoparticles – Synthesis and crystal structure |
| title_short | Bis(2-Cyclooctylidenehydrazene-1-carbothioamide)Zinc(II), a good single source precursor for ZnS nanoparticles – Synthesis and crystal structure |
| title_sort | bis 2 cyclooctylidenehydrazene 1 carbothioamide zinc ii a good single source precursor for zns nanoparticles synthesis and crystal structure |
| topic | Carbothioamide Single source precursor Thermal decomposition Polyol method Nano particle |
| url | http://www.sciencedirect.com/science/article/pii/S2211715622003204 |
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