Tris(2,2′-bipyridyl-κ2N,N′)copper(II) sulfate 7.5-hydrate
The title compound, [Cu(C10H8N2)3]SO4·7.5H2O, is a six-coordinate copper(II) complex with a slightly elongated octahedral coordination geometry. The pyridyl rings of the three bipyridyl ligands are not coplanar, making dihedral angels of 9.5 (5), 5.2 (4) and 5.8̳...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808043821 |
| _version_ | 1828137816674009088 |
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| author | Wei Huang Wei You Feng Xu |
| author_facet | Wei Huang Wei You Feng Xu |
| author_sort | Wei Huang |
| collection | DOAJ |
| description | The title compound, [Cu(C10H8N2)3]SO4·7.5H2O, is a six-coordinate copper(II) complex with a slightly elongated octahedral coordination geometry. The pyridyl rings of the three bipyridyl ligands are not coplanar, making dihedral angels of 9.5 (5), 5.2 (4) and 5.8 (5)°. In the crystal, several O—H...O and C—H...O hydrogen-bonding interactions are observed due to the existance of a large number of water molecules and the sulfate dianions. |
| first_indexed | 2024-04-11T18:24:40Z |
| format | Article |
| id | doaj.art-e7fbf69ab55541aaa1502a1fa9688f4f |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T18:24:40Z |
| publishDate | 2009-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-e7fbf69ab55541aaa1502a1fa9688f4f2022-12-22T04:09:39ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-02-01652m129m13010.1107/S1600536808043821Tris(2,2′-bipyridyl-κ2N,N′)copper(II) sulfate 7.5-hydrateWei HuangWei YouFeng XuThe title compound, [Cu(C10H8N2)3]SO4·7.5H2O, is a six-coordinate copper(II) complex with a slightly elongated octahedral coordination geometry. The pyridyl rings of the three bipyridyl ligands are not coplanar, making dihedral angels of 9.5 (5), 5.2 (4) and 5.8 (5)°. In the crystal, several O—H...O and C—H...O hydrogen-bonding interactions are observed due to the existance of a large number of water molecules and the sulfate dianions.http://scripts.iucr.org/cgi-bin/paper?S1600536808043821 |
| spellingShingle | Wei Huang Wei You Feng Xu Tris(2,2′-bipyridyl-κ2N,N′)copper(II) sulfate 7.5-hydrate Acta Crystallographica Section E |
| title | Tris(2,2′-bipyridyl-κ2N,N′)copper(II) sulfate 7.5-hydrate |
| title_full | Tris(2,2′-bipyridyl-κ2N,N′)copper(II) sulfate 7.5-hydrate |
| title_fullStr | Tris(2,2′-bipyridyl-κ2N,N′)copper(II) sulfate 7.5-hydrate |
| title_full_unstemmed | Tris(2,2′-bipyridyl-κ2N,N′)copper(II) sulfate 7.5-hydrate |
| title_short | Tris(2,2′-bipyridyl-κ2N,N′)copper(II) sulfate 7.5-hydrate |
| title_sort | tris 2 2 8242 bipyridyl 954 2n n 8242 copper ii sulfate 7 5 hydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808043821 |
| work_keys_str_mv | AT weihuang tris228242bipyridyl9542nn8242copperiisulfate75hydrate AT weiyou tris228242bipyridyl9542nn8242copperiisulfate75hydrate AT fengxu tris228242bipyridyl9542nn8242copperiisulfate75hydrate |