Synergistic Effects of La and Y on the Microstructure and Mechanical Properties of Cast Al-Si-Cu Alloys

The effects of La and Y on the microstructure and mechanical properties of cast Al-Si-Cu alloys were investigated by X-ray diffractometer (XRD), optical microscope (OM), and scanning electron microscope (SEM). The results indicated that the addition of La and Y had a great effect on the refinement o...

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Bibliographic Details
Main Authors: Luming Shuai, Xiuliang Zou, Yuqiang Rao, Xiaobin Lu, Hong Yan
Format: Article
Language:English
Published: MDPI AG 2022-10-01
Series:Materials
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Online Access:https://www.mdpi.com/1996-1944/15/20/7283
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Summary:The effects of La and Y on the microstructure and mechanical properties of cast Al-Si-Cu alloys were investigated by X-ray diffractometer (XRD), optical microscope (OM), and scanning electron microscope (SEM). The results indicated that the addition of La and Y had a great effect on the refinement of α-Al grains, the modification of eutectic Si phase, and the reduction of β-Al<sub>5</sub>FeSi length in Al-Si-Cu alloys. The A380 + 0.6 wt.% La/Y alloy exhibited the best microstructure and mechanical properties. The UTS and EI of the A380 + 0.6 wt.% La/Y alloy were 215.3 MPa and 5.1%, which were 22.9% and 37.8% higher than those of the matrix alloy, respectively. In addition, neither Al<sub>11</sub>La<sub>3</sub> nor Al<sub>3</sub>Y generated by the addition of La and Y could not serve as the nucleation core of α-Al grains, so the grain refinement of α-Al originated from the growth limitation and constitutional supercooling. Since La and Y promote twinning generation and constitutional supercooling, the eutectic Si phase also changed from stripe-like to short fibrous or even granular and was significantly refined. Furthermore, thermodynamic calculations indicated that the Al<sub>11</sub>La<sub>3</sub> phase was formed first and the Al<sub>3</sub>Y phase was generated on the Al<sub>11</sub>La<sub>3</sub> phase.
ISSN:1996-1944