Bis(2-aminopyridine-κN1)bis(benzoato-κO)cobalt(II)
In the title compound, [Co(C7H5O2)2(C5H6N2)2], the CoII atom is hexacoordinated by four O atoms from two benzoate anions, and two N atoms from two 2-aminopyridine molecules, resulting in a distorted octahedral geometry. Both benzoate anions act as bidentate ligands and both 2-aminopyridine molecules...
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-01-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536807063933 |
| _version_ | 1798018565105778688 |
|---|---|
| author | Di-Chang Zhong Gui-Quan Guo Xiao-Hua Zuo Ji-Hua Deng Lin Yuan Rong-Hua Zhu |
| author_facet | Di-Chang Zhong Gui-Quan Guo Xiao-Hua Zuo Ji-Hua Deng Lin Yuan Rong-Hua Zhu |
| author_sort | Di-Chang Zhong |
| collection | DOAJ |
| description | In the title compound, [Co(C7H5O2)2(C5H6N2)2], the CoII atom is hexacoordinated by four O atoms from two benzoate anions, and two N atoms from two 2-aminopyridine molecules, resulting in a distorted octahedral geometry. Both benzoate anions act as bidentate ligands and both 2-aminopyridine molecules are coordinated to the metal through their pyridyl N atoms. The crystal packing is stabilized by intermolecular N—H...O hydrogen bonds, C—H...π, and π–π stacking interactions involving benzoate anions and 2-aminopyridine molecules. |
| first_indexed | 2024-04-11T16:24:59Z |
| format | Article |
| id | doaj.art-e85a7b5400bd45beacbca7557ede8048 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:24:59Z |
| publishDate | 2008-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-e85a7b5400bd45beacbca7557ede80482022-12-22T04:14:12ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641m88m8910.1107/S1600536807063933Bis(2-aminopyridine-κN1)bis(benzoato-κO)cobalt(II)Di-Chang ZhongGui-Quan GuoXiao-Hua ZuoJi-Hua DengLin YuanRong-Hua ZhuIn the title compound, [Co(C7H5O2)2(C5H6N2)2], the CoII atom is hexacoordinated by four O atoms from two benzoate anions, and two N atoms from two 2-aminopyridine molecules, resulting in a distorted octahedral geometry. Both benzoate anions act as bidentate ligands and both 2-aminopyridine molecules are coordinated to the metal through their pyridyl N atoms. The crystal packing is stabilized by intermolecular N—H...O hydrogen bonds, C—H...π, and π–π stacking interactions involving benzoate anions and 2-aminopyridine molecules.http://scripts.iucr.org/cgi-bin/paper?S1600536807063933 |
| spellingShingle | Di-Chang Zhong Gui-Quan Guo Xiao-Hua Zuo Ji-Hua Deng Lin Yuan Rong-Hua Zhu Bis(2-aminopyridine-κN1)bis(benzoato-κO)cobalt(II) Acta Crystallographica Section E |
| title | Bis(2-aminopyridine-κN1)bis(benzoato-κO)cobalt(II) |
| title_full | Bis(2-aminopyridine-κN1)bis(benzoato-κO)cobalt(II) |
| title_fullStr | Bis(2-aminopyridine-κN1)bis(benzoato-κO)cobalt(II) |
| title_full_unstemmed | Bis(2-aminopyridine-κN1)bis(benzoato-κO)cobalt(II) |
| title_short | Bis(2-aminopyridine-κN1)bis(benzoato-κO)cobalt(II) |
| title_sort | bis 2 aminopyridine 954 n1 bis benzoato 954 o cobalt ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536807063933 |
| work_keys_str_mv | AT dichangzhong bis2aminopyridine954n1bisbenzoato954ocobaltii AT guiquanguo bis2aminopyridine954n1bisbenzoato954ocobaltii AT xiaohuazuo bis2aminopyridine954n1bisbenzoato954ocobaltii AT jihuadeng bis2aminopyridine954n1bisbenzoato954ocobaltii AT linyuan bis2aminopyridine954n1bisbenzoato954ocobaltii AT ronghuazhu bis2aminopyridine954n1bisbenzoato954ocobaltii |