Trace-element analysis of mineral grains in Ryugu rock fragment sections by synchrotron-based confocal X-ray fluorescence
Abstract A fundamental parameter-based quantification scheme for confocal XRF was applied to sub-micron synchrotron radiation X-ray fluorescence (SR-XRF) data obtained at the beamline P06 of the Deutsches Elektronen-Synchrotron (DESY, Hamburg, Germany) from two sections C0033-01 and C0033-04 that we...
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SpringerOpen
2022-11-01
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| Series: | Earth, Planets and Space |
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| Online Access: | https://doi.org/10.1186/s40623-022-01726-y |
| _version_ | 1798044335493611520 |
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| author | Benjamin Bazi Pieter Tack Miles Lindner Bart Vekemans Ella De Pauw Beverley Tkalcec Frank E. Brenker Jan Garrevoet Gerald Falkenberg Hikaru Yabuta Hisayoshi Yurimoto Tomoki Nakamura Kana Amano Megumi Matsumoto Yuri Fujioka Yuma Enokido Daisuke Nakashima Masayuki Uesugi Hiroshi Naraoka Takaaki Noguchi Ryuji Okazaki Kanako Sakamoto Toru Yada Masahiro Nishimura Aiko Nakato Akiko Miyazaki Kasumi Yogata Masanao Abe Tatsuaki Okada Tomohiro Usui Makoto Yoshikawa Takanao Saiki Satoshi Tanaka Fuyuto Terui Satoru Nakazawa Shogo Tachibana Sei-ichiro Watanabe Yuichi Tsuda Laszlo Vincze |
| author_facet | Benjamin Bazi Pieter Tack Miles Lindner Bart Vekemans Ella De Pauw Beverley Tkalcec Frank E. Brenker Jan Garrevoet Gerald Falkenberg Hikaru Yabuta Hisayoshi Yurimoto Tomoki Nakamura Kana Amano Megumi Matsumoto Yuri Fujioka Yuma Enokido Daisuke Nakashima Masayuki Uesugi Hiroshi Naraoka Takaaki Noguchi Ryuji Okazaki Kanako Sakamoto Toru Yada Masahiro Nishimura Aiko Nakato Akiko Miyazaki Kasumi Yogata Masanao Abe Tatsuaki Okada Tomohiro Usui Makoto Yoshikawa Takanao Saiki Satoshi Tanaka Fuyuto Terui Satoru Nakazawa Shogo Tachibana Sei-ichiro Watanabe Yuichi Tsuda Laszlo Vincze |
| author_sort | Benjamin Bazi |
| collection | DOAJ |
| description | Abstract A fundamental parameter-based quantification scheme for confocal XRF was applied to sub-micron synchrotron radiation X-ray fluorescence (SR-XRF) data obtained at the beamline P06 of the Deutsches Elektronen-Synchrotron (DESY, Hamburg, Germany) from two sections C0033-01 and C0033-04 that were wet cut from rock fragment C0033 collected from Cb-type asteroid (162173) Ryugu by JAXA’s Hayabusa2 mission. Trace-element quantifications show that C0033 bulk matrix is CI-like, whereas individual mineral grains (i.e., magnetite, pyrrhotite, dolomite, apatite and breunnerite) show, depending on the respective phase, minor to strong deviations. The non-destructive nature of SR-XRF coupled with a new PyMca (a Python toolkit for XRF data analysis)-based quantification approach, performed in parallel with the synchrotron experiments, proves to be an attractive tool for the initial analysis of samples from return missions, such as Hayabusa2 and OSIRIS-REx, the latter returning material from a B-type asteroid (101955) Bennu in 2023. Graphical Abstract |
| first_indexed | 2024-04-11T23:03:14Z |
| format | Article |
| id | doaj.art-e873f82415ac4a06b709057262b476ac |
| institution | Directory Open Access Journal |
| issn | 1880-5981 |
| language | English |
| last_indexed | 2024-04-11T23:03:14Z |
| publishDate | 2022-11-01 |
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| record_format | Article |
| series | Earth, Planets and Space |
| spelling | doaj.art-e873f82415ac4a06b709057262b476ac2022-12-22T03:58:06ZengSpringerOpenEarth, Planets and Space1880-59812022-11-0174111710.1186/s40623-022-01726-yTrace-element analysis of mineral grains in Ryugu rock fragment sections by synchrotron-based confocal X-ray fluorescenceBenjamin Bazi0Pieter Tack1Miles Lindner2Bart Vekemans3Ella De Pauw4Beverley Tkalcec5Frank E. Brenker6Jan Garrevoet7Gerald Falkenberg8Hikaru Yabuta9Hisayoshi Yurimoto10Tomoki Nakamura11Kana Amano12Megumi Matsumoto13Yuri Fujioka14Yuma Enokido15Daisuke Nakashima16Masayuki Uesugi17Hiroshi Naraoka18Takaaki Noguchi19Ryuji Okazaki20Kanako Sakamoto21Toru Yada22Masahiro Nishimura23Aiko Nakato24Akiko Miyazaki25Kasumi Yogata26Masanao Abe27Tatsuaki Okada28Tomohiro Usui29Makoto Yoshikawa30Takanao Saiki31Satoshi Tanaka32Fuyuto Terui33Satoru Nakazawa34Shogo Tachibana35Sei-ichiro Watanabe36Yuichi Tsuda37Laszlo Vincze38Department of Chemistry, Ghent UniversityDepartment of Chemistry, Ghent UniversityDepartment of Geosciences, Goethe University FrankfurtDepartment of Chemistry, Ghent UniversityDepartment of Chemistry, Ghent UniversityDepartment of Geosciences, Goethe University FrankfurtDepartment of Geosciences, Goethe University FrankfurtDeutsches Elektronen-Synchrotron, DESYDeutsches Elektronen-Synchrotron, DESYGraduate School of Advanced Science and Engineering, Hiroshima UniversityDepartment of Natural History Sciences, Hokkaido UniversityDepartment of Earth Science, Tohoku UniversityDepartment of Earth Science, Tohoku UniversityDepartment of Earth Science, Tohoku UniversityDepartment of Earth Science, Tohoku UniversityDepartment of Earth Science, Tohoku UniversityDepartment of Earth Science, Tohoku UniversityJASRI/SPring-8Department of Earth and Planetary Sciences, Kyushu UniversityLaboratory for Planetary Sciences, Kyoto UniversityDepartment of Earth and Planetary Sciences, Kyushu UniversityInstitute of Space and Astronautical Science (ISAS), Japan Aerospace Exploration Agency (JAXA)Institute of Space and Astronautical Science (ISAS), Japan Aerospace Exploration Agency (JAXA)Institute of Space and Astronautical Science (ISAS), Japan Aerospace Exploration Agency (JAXA)Institute of Space and Astronautical Science (ISAS), Japan Aerospace Exploration Agency (JAXA)Institute of Space and Astronautical Science (ISAS), Japan Aerospace Exploration Agency (JAXA)Institute of Space and Astronautical Science (ISAS), Japan Aerospace Exploration Agency (JAXA)Institute of Space and Astronautical Science (ISAS), Japan Aerospace Exploration Agency (JAXA)Institute of Space and Astronautical Science (ISAS), Japan Aerospace Exploration Agency (JAXA)Institute of Space and Astronautical Science (ISAS), Japan Aerospace Exploration Agency (JAXA)Institute of Space and Astronautical Science (ISAS), Japan Aerospace Exploration Agency (JAXA)Institute of Space and Astronautical Science (ISAS), Japan Aerospace Exploration Agency (JAXA)Institute of Space and Astronautical Science (ISAS), Japan Aerospace Exploration Agency (JAXA)Kanagawa Institute of TechnologyInstitute of Space and Astronautical Science (ISAS), Japan Aerospace Exploration Agency (JAXA)Department of Earth and Planetary Science, The University of TokyoDepartment of Earth and Planetary Sciences, Nagoya UniversityInstitute of Space and Astronautical Science (ISAS), Japan Aerospace Exploration Agency (JAXA)Department of Chemistry, Ghent UniversityAbstract A fundamental parameter-based quantification scheme for confocal XRF was applied to sub-micron synchrotron radiation X-ray fluorescence (SR-XRF) data obtained at the beamline P06 of the Deutsches Elektronen-Synchrotron (DESY, Hamburg, Germany) from two sections C0033-01 and C0033-04 that were wet cut from rock fragment C0033 collected from Cb-type asteroid (162173) Ryugu by JAXA’s Hayabusa2 mission. Trace-element quantifications show that C0033 bulk matrix is CI-like, whereas individual mineral grains (i.e., magnetite, pyrrhotite, dolomite, apatite and breunnerite) show, depending on the respective phase, minor to strong deviations. The non-destructive nature of SR-XRF coupled with a new PyMca (a Python toolkit for XRF data analysis)-based quantification approach, performed in parallel with the synchrotron experiments, proves to be an attractive tool for the initial analysis of samples from return missions, such as Hayabusa2 and OSIRIS-REx, the latter returning material from a B-type asteroid (101955) Bennu in 2023. Graphical Abstracthttps://doi.org/10.1186/s40623-022-01726-yX-ray fluorescenceConfocalQuantificationFundamental parameter methodRyuguHayabusa2 |
| spellingShingle | Benjamin Bazi Pieter Tack Miles Lindner Bart Vekemans Ella De Pauw Beverley Tkalcec Frank E. Brenker Jan Garrevoet Gerald Falkenberg Hikaru Yabuta Hisayoshi Yurimoto Tomoki Nakamura Kana Amano Megumi Matsumoto Yuri Fujioka Yuma Enokido Daisuke Nakashima Masayuki Uesugi Hiroshi Naraoka Takaaki Noguchi Ryuji Okazaki Kanako Sakamoto Toru Yada Masahiro Nishimura Aiko Nakato Akiko Miyazaki Kasumi Yogata Masanao Abe Tatsuaki Okada Tomohiro Usui Makoto Yoshikawa Takanao Saiki Satoshi Tanaka Fuyuto Terui Satoru Nakazawa Shogo Tachibana Sei-ichiro Watanabe Yuichi Tsuda Laszlo Vincze Trace-element analysis of mineral grains in Ryugu rock fragment sections by synchrotron-based confocal X-ray fluorescence Earth, Planets and Space X-ray fluorescence Confocal Quantification Fundamental parameter method Ryugu Hayabusa2 |
| title | Trace-element analysis of mineral grains in Ryugu rock fragment sections by synchrotron-based confocal X-ray fluorescence |
| title_full | Trace-element analysis of mineral grains in Ryugu rock fragment sections by synchrotron-based confocal X-ray fluorescence |
| title_fullStr | Trace-element analysis of mineral grains in Ryugu rock fragment sections by synchrotron-based confocal X-ray fluorescence |
| title_full_unstemmed | Trace-element analysis of mineral grains in Ryugu rock fragment sections by synchrotron-based confocal X-ray fluorescence |
| title_short | Trace-element analysis of mineral grains in Ryugu rock fragment sections by synchrotron-based confocal X-ray fluorescence |
| title_sort | trace element analysis of mineral grains in ryugu rock fragment sections by synchrotron based confocal x ray fluorescence |
| topic | X-ray fluorescence Confocal Quantification Fundamental parameter method Ryugu Hayabusa2 |
| url | https://doi.org/10.1186/s40623-022-01726-y |
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