catena-Poly[[[triaqua(nitrato-κ2O,O′)neodymium(III)]-bis(μ2-pyridinium-4-carboxylato-κ2O:O′)] bis(perchlorate) monohydrate]
In the title compound, {[Nd(NO3)(C6H5NO2)2(H2O)3](ClO4)2·H2O}n, the NdIII atom is nine-coordinated by four O atoms from four pyridinium-4-carboxylate ligands, two O atoms from a chelating nitrate anion and three water molecules in a distorted tricapped trigonal–prismatic coordinat...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808043997 |
| _version_ | 1818959672302895104 |
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| author | Jia-Zhi Pu |
| author_facet | Jia-Zhi Pu |
| author_sort | Jia-Zhi Pu |
| collection | DOAJ |
| description | In the title compound, {[Nd(NO3)(C6H5NO2)2(H2O)3](ClO4)2·H2O}n, the NdIII atom is nine-coordinated by four O atoms from four pyridinium-4-carboxylate ligands, two O atoms from a chelating nitrate anion and three water molecules in a distorted tricapped trigonal–prismatic coordination geometry. Adjacent Nd atoms are linked by the bidentate pyridinium-4-carboxylate ligands into a chain running along the b axis. The chains are further connected by O—H...O and N—H...O hydrogen bonds into a three-dimensional network. |
| first_indexed | 2024-12-20T11:45:22Z |
| format | Article |
| id | doaj.art-e89d2f8f05564b0ea8e1a6a66807f208 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:45:22Z |
| publishDate | 2009-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-e89d2f8f05564b0ea8e1a6a66807f2082022-12-21T19:41:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-02-01652m146m14710.1107/S1600536808043997catena-Poly[[[triaqua(nitrato-κ2O,O′)neodymium(III)]-bis(μ2-pyridinium-4-carboxylato-κ2O:O′)] bis(perchlorate) monohydrate]Jia-Zhi PuIn the title compound, {[Nd(NO3)(C6H5NO2)2(H2O)3](ClO4)2·H2O}n, the NdIII atom is nine-coordinated by four O atoms from four pyridinium-4-carboxylate ligands, two O atoms from a chelating nitrate anion and three water molecules in a distorted tricapped trigonal–prismatic coordination geometry. Adjacent Nd atoms are linked by the bidentate pyridinium-4-carboxylate ligands into a chain running along the b axis. The chains are further connected by O—H...O and N—H...O hydrogen bonds into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536808043997 |
| spellingShingle | Jia-Zhi Pu catena-Poly[[[triaqua(nitrato-κ2O,O′)neodymium(III)]-bis(μ2-pyridinium-4-carboxylato-κ2O:O′)] bis(perchlorate) monohydrate] Acta Crystallographica Section E |
| title | catena-Poly[[[triaqua(nitrato-κ2O,O′)neodymium(III)]-bis(μ2-pyridinium-4-carboxylato-κ2O:O′)] bis(perchlorate) monohydrate] |
| title_full | catena-Poly[[[triaqua(nitrato-κ2O,O′)neodymium(III)]-bis(μ2-pyridinium-4-carboxylato-κ2O:O′)] bis(perchlorate) monohydrate] |
| title_fullStr | catena-Poly[[[triaqua(nitrato-κ2O,O′)neodymium(III)]-bis(μ2-pyridinium-4-carboxylato-κ2O:O′)] bis(perchlorate) monohydrate] |
| title_full_unstemmed | catena-Poly[[[triaqua(nitrato-κ2O,O′)neodymium(III)]-bis(μ2-pyridinium-4-carboxylato-κ2O:O′)] bis(perchlorate) monohydrate] |
| title_short | catena-Poly[[[triaqua(nitrato-κ2O,O′)neodymium(III)]-bis(μ2-pyridinium-4-carboxylato-κ2O:O′)] bis(perchlorate) monohydrate] |
| title_sort | catena poly triaqua nitrato 954 2o o 8242 neodymium iii bis 956 2 pyridinium 4 carboxylato 954 2o o 8242 bis perchlorate monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808043997 |
| work_keys_str_mv | AT jiazhipu catenapolytriaquanitrato9542oo8242neodymiumiiibis9562pyridinium4carboxylato9542oo8242bisperchloratemonohydrate |