Structural role of Cu in the soil active glasses

Glasses from the SiO2-P2O5-K2O-CaO-MgO-CuO system acting as slow release fertilizers were synthesized by the melt-quenching technique. Influence of copper addition on structure of the glasses was evaluated by XRD, SEM, FT-IR and Raman spectroscopy. Chemical activity of the glasses in 2 wt.% citric a...

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Main Authors: Irena Wacławska, Justyna Sułowska
Format: Article
Language:English
Published: University of Novi Sad 2012-06-01
Series:Processing and Application of Ceramics
Subjects:
Online Access:http://www.tf.uns.ac.rs/publikacije/PAC/pdf/PAC%2016%2002.pdf
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author Irena Wacławska
Justyna Sułowska
author_facet Irena Wacławska
Justyna Sułowska
author_sort Irena Wacławska
collection DOAJ
description Glasses from the SiO2-P2O5-K2O-CaO-MgO-CuO system acting as slow release fertilizers were synthesized by the melt-quenching technique. Influence of copper addition on structure of the glasses was evaluated by XRD, SEM, FT-IR and Raman spectroscopy. Chemical activity of the glasses in 2 wt.% citric acid solutions was measured by ICP-AES method. It has been found that increasing content of phosphorous increased solubility of copper in the structure of the studied glasses which was the result of formation of P-O-Cu bonds.
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spelling doaj.art-e89d8117366b4045803e7edcdad0958b2022-12-21T17:58:00ZengUniversity of Novi SadProcessing and Application of Ceramics1820-61312012-06-01627782Structural role of Cu in the soil active glassesIrena WacławskaJustyna SułowskaGlasses from the SiO2-P2O5-K2O-CaO-MgO-CuO system acting as slow release fertilizers were synthesized by the melt-quenching technique. Influence of copper addition on structure of the glasses was evaluated by XRD, SEM, FT-IR and Raman spectroscopy. Chemical activity of the glasses in 2 wt.% citric acid solutions was measured by ICP-AES method. It has been found that increasing content of phosphorous increased solubility of copper in the structure of the studied glasses which was the result of formation of P-O-Cu bonds.http://www.tf.uns.ac.rs/publikacije/PAC/pdf/PAC%2016%2002.pdfGlassy fertilizersStructural characterizationFT-IRRaman spectroscopyXRD
spellingShingle Irena Wacławska
Justyna Sułowska
Structural role of Cu in the soil active glasses
Processing and Application of Ceramics
Glassy fertilizers
Structural characterization
FT-IR
Raman spectroscopy
XRD
title Structural role of Cu in the soil active glasses
title_full Structural role of Cu in the soil active glasses
title_fullStr Structural role of Cu in the soil active glasses
title_full_unstemmed Structural role of Cu in the soil active glasses
title_short Structural role of Cu in the soil active glasses
title_sort structural role of cu in the soil active glasses
topic Glassy fertilizers
Structural characterization
FT-IR
Raman spectroscopy
XRD
url http://www.tf.uns.ac.rs/publikacije/PAC/pdf/PAC%2016%2002.pdf
work_keys_str_mv AT irenawacławska structuralroleofcuinthesoilactiveglasses
AT justynasułowska structuralroleofcuinthesoilactiveglasses