Electrochemical Hydrogen Charging on Corrosion Behavior of Ti-6Al-4V Alloy in Artificial Seawater

Abstract This study employs advanced electrochemical and surface characterization techniques to investigate the impact of electrochemical hydrogen charging on the corrosion behavior and surface film of the Ti-6Al-4V alloy. The findings revealed the formation of γ-TiH and δ-TiH2 hydrides in the alloy...

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Main Authors: Yanxin Qiao, Yue Qin, Huiling Zhou, Lanlan Yang, Xiaojing Wang, Zhengbin Wang, Zhenguang Liu, Jiasheng Zou
Format: Article
Language:English
Published: SpringerOpen 2024-01-01
Series:Chinese Journal of Mechanical Engineering
Subjects:
Online Access:https://doi.org/10.1186/s10033-023-00983-6
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author Yanxin Qiao
Yue Qin
Huiling Zhou
Lanlan Yang
Xiaojing Wang
Zhengbin Wang
Zhenguang Liu
Jiasheng Zou
author_facet Yanxin Qiao
Yue Qin
Huiling Zhou
Lanlan Yang
Xiaojing Wang
Zhengbin Wang
Zhenguang Liu
Jiasheng Zou
author_sort Yanxin Qiao
collection DOAJ
description Abstract This study employs advanced electrochemical and surface characterization techniques to investigate the impact of electrochemical hydrogen charging on the corrosion behavior and surface film of the Ti-6Al-4V alloy. The findings revealed the formation of γ-TiH and δ-TiH2 hydrides in the alloy after hydrogen charging. Prolonging hydrogen charging resulted in more significant degradation of the alloy microstructure, leading to deteriorated protectiveness of the surface film. This trend was further confirmed by the electrochemical measurements, which showed that the corrosion resistance of the alloy progressively worsened as the hydrogen charging time was increased. Consequently, this work provides valuable insights into the mechanisms underlying the corrosion of Ti-6Al-4V alloy under hydrogen charging conditions.
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spelling doaj.art-e8ad91de462b4797821e96fbd69c27492024-01-07T12:14:38ZengSpringerOpenChinese Journal of Mechanical Engineering2192-82582024-01-0137111310.1186/s10033-023-00983-6Electrochemical Hydrogen Charging on Corrosion Behavior of Ti-6Al-4V Alloy in Artificial SeawaterYanxin Qiao0Yue Qin1Huiling Zhou2Lanlan Yang3Xiaojing Wang4Zhengbin Wang5Zhenguang Liu6Jiasheng Zou7School of Materials Science and Engineering, Jiangsu University of Science and TechnologySchool of Materials Science and Engineering, Jiangsu University of Science and TechnologySchool of Materials Science and Engineering, Jiangsu University of Science and TechnologySchool of Materials Science and Engineering, Jiangsu University of Science and TechnologySchool of Materials Science and Engineering, Jiangsu University of Science and TechnologyCAS Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research, Chinese Academy of SciencesSchool of Materials Science and Engineering, Jiangsu University of Science and TechnologySchool of Materials Science and Engineering, Jiangsu University of Science and TechnologyAbstract This study employs advanced electrochemical and surface characterization techniques to investigate the impact of electrochemical hydrogen charging on the corrosion behavior and surface film of the Ti-6Al-4V alloy. The findings revealed the formation of γ-TiH and δ-TiH2 hydrides in the alloy after hydrogen charging. Prolonging hydrogen charging resulted in more significant degradation of the alloy microstructure, leading to deteriorated protectiveness of the surface film. This trend was further confirmed by the electrochemical measurements, which showed that the corrosion resistance of the alloy progressively worsened as the hydrogen charging time was increased. Consequently, this work provides valuable insights into the mechanisms underlying the corrosion of Ti-6Al-4V alloy under hydrogen charging conditions.https://doi.org/10.1186/s10033-023-00983-6Ti-6Al-4V alloyHydrogen chargingElectrochemical corrosionPassive film
spellingShingle Yanxin Qiao
Yue Qin
Huiling Zhou
Lanlan Yang
Xiaojing Wang
Zhengbin Wang
Zhenguang Liu
Jiasheng Zou
Electrochemical Hydrogen Charging on Corrosion Behavior of Ti-6Al-4V Alloy in Artificial Seawater
Chinese Journal of Mechanical Engineering
Ti-6Al-4V alloy
Hydrogen charging
Electrochemical corrosion
Passive film
title Electrochemical Hydrogen Charging on Corrosion Behavior of Ti-6Al-4V Alloy in Artificial Seawater
title_full Electrochemical Hydrogen Charging on Corrosion Behavior of Ti-6Al-4V Alloy in Artificial Seawater
title_fullStr Electrochemical Hydrogen Charging on Corrosion Behavior of Ti-6Al-4V Alloy in Artificial Seawater
title_full_unstemmed Electrochemical Hydrogen Charging on Corrosion Behavior of Ti-6Al-4V Alloy in Artificial Seawater
title_short Electrochemical Hydrogen Charging on Corrosion Behavior of Ti-6Al-4V Alloy in Artificial Seawater
title_sort electrochemical hydrogen charging on corrosion behavior of ti 6al 4v alloy in artificial seawater
topic Ti-6Al-4V alloy
Hydrogen charging
Electrochemical corrosion
Passive film
url https://doi.org/10.1186/s10033-023-00983-6
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AT yueqin electrochemicalhydrogenchargingoncorrosionbehaviorofti6al4valloyinartificialseawater
AT huilingzhou electrochemicalhydrogenchargingoncorrosionbehaviorofti6al4valloyinartificialseawater
AT lanlanyang electrochemicalhydrogenchargingoncorrosionbehaviorofti6al4valloyinartificialseawater
AT xiaojingwang electrochemicalhydrogenchargingoncorrosionbehaviorofti6al4valloyinartificialseawater
AT zhengbinwang electrochemicalhydrogenchargingoncorrosionbehaviorofti6al4valloyinartificialseawater
AT zhenguangliu electrochemicalhydrogenchargingoncorrosionbehaviorofti6al4valloyinartificialseawater
AT jiashengzou electrochemicalhydrogenchargingoncorrosionbehaviorofti6al4valloyinartificialseawater