Valorization of Banana Peel Using Carbonization: Potential Use in the Sustainable Manufacturing of Flexible Supercapacitors

Sustainable and environmentally friendly activated carbon from biomass materials is proposed to produce supercapacitors from banana peels and has the potential to replace the non-sustainable and hazardous process from either graphite or/and fossil fuels. In order to determine the potential of using...

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Main Authors: Melkie Getnet Tadesse, Esubalew Kasaw, Jörn Felix Lübben
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Micromachines
Subjects:
Online Access:https://www.mdpi.com/2072-666X/14/2/330
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author Melkie Getnet Tadesse
Esubalew Kasaw
Jörn Felix Lübben
author_facet Melkie Getnet Tadesse
Esubalew Kasaw
Jörn Felix Lübben
author_sort Melkie Getnet Tadesse
collection DOAJ
description Sustainable and environmentally friendly activated carbon from biomass materials is proposed to produce supercapacitors from banana peels and has the potential to replace the non-sustainable and hazardous process from either graphite or/and fossil fuels. In order to determine the potential of using banana peel for supercapacitor application, raw banana peel, a bio-waste, was activated both mechanically and chemically to observe the real differences. The sample was activated at 700 °C and chemically activated using KOH. Characterization of activated banana peel was performed using FTIR, DLS, TGA and XRD analytical equipment. FTIR analysis revised the presence of hydroxyl, carbonyl and aromatic compounds on a banana peel cellulose-based carbon. The TGA results proved that 700 °C could be sufficient to totally carbonize banana peel. DLS clearly showed a strong difference between the carbonized and KOH-activated material in particle size distribution. Meanwhile, surface area analysis using BET displayed an increase from 553.862 m<sup>2</sup>/g to 565.024 m<sup>2</sup>/g BET in surface area (SBET) when carbon was activated using KOH with a nitrogen isotherm at 77.350 K. Specific capacitance was increased from 0.3997 Fg<sup>−1</sup> to 0.821 Fg<sup>−1</sup>, suggesting more than a 100% increase in the specific capacity due to KOH activation, as proved by the cyclic voltammetry (CV) curve. The X-ray diffraction results revealed the patterns of activated carbon. The findings demonstrated the feasibility of using banana peel waste as a low-cost and sustainable material for the preparation of flexible supercapacitor batteries.
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spelling doaj.art-e8bf207a345e4dfcb8acebe3e960d14f2023-11-16T22:10:44ZengMDPI AGMicromachines2072-666X2023-01-0114233010.3390/mi14020330Valorization of Banana Peel Using Carbonization: Potential Use in the Sustainable Manufacturing of Flexible SupercapacitorsMelkie Getnet Tadesse0Esubalew Kasaw1Jörn Felix Lübben2Sustainable Engineering (STE), Albstadt-Sigmaringen University, 72458 Albstadt, GermanyEthiopian Institute of Textile and Fashion Technology, Bahir Dar University, Bahir Dar 1037, EthiopiaSustainable Engineering (STE), Albstadt-Sigmaringen University, 72458 Albstadt, GermanySustainable and environmentally friendly activated carbon from biomass materials is proposed to produce supercapacitors from banana peels and has the potential to replace the non-sustainable and hazardous process from either graphite or/and fossil fuels. In order to determine the potential of using banana peel for supercapacitor application, raw banana peel, a bio-waste, was activated both mechanically and chemically to observe the real differences. The sample was activated at 700 °C and chemically activated using KOH. Characterization of activated banana peel was performed using FTIR, DLS, TGA and XRD analytical equipment. FTIR analysis revised the presence of hydroxyl, carbonyl and aromatic compounds on a banana peel cellulose-based carbon. The TGA results proved that 700 °C could be sufficient to totally carbonize banana peel. DLS clearly showed a strong difference between the carbonized and KOH-activated material in particle size distribution. Meanwhile, surface area analysis using BET displayed an increase from 553.862 m<sup>2</sup>/g to 565.024 m<sup>2</sup>/g BET in surface area (SBET) when carbon was activated using KOH with a nitrogen isotherm at 77.350 K. Specific capacitance was increased from 0.3997 Fg<sup>−1</sup> to 0.821 Fg<sup>−1</sup>, suggesting more than a 100% increase in the specific capacity due to KOH activation, as proved by the cyclic voltammetry (CV) curve. The X-ray diffraction results revealed the patterns of activated carbon. The findings demonstrated the feasibility of using banana peel waste as a low-cost and sustainable material for the preparation of flexible supercapacitor batteries.https://www.mdpi.com/2072-666X/14/2/330activated banana peelsupercapacitorbio-wasteBET-surfaceXRDCV
spellingShingle Melkie Getnet Tadesse
Esubalew Kasaw
Jörn Felix Lübben
Valorization of Banana Peel Using Carbonization: Potential Use in the Sustainable Manufacturing of Flexible Supercapacitors
Micromachines
activated banana peel
supercapacitor
bio-waste
BET-surface
XRD
CV
title Valorization of Banana Peel Using Carbonization: Potential Use in the Sustainable Manufacturing of Flexible Supercapacitors
title_full Valorization of Banana Peel Using Carbonization: Potential Use in the Sustainable Manufacturing of Flexible Supercapacitors
title_fullStr Valorization of Banana Peel Using Carbonization: Potential Use in the Sustainable Manufacturing of Flexible Supercapacitors
title_full_unstemmed Valorization of Banana Peel Using Carbonization: Potential Use in the Sustainable Manufacturing of Flexible Supercapacitors
title_short Valorization of Banana Peel Using Carbonization: Potential Use in the Sustainable Manufacturing of Flexible Supercapacitors
title_sort valorization of banana peel using carbonization potential use in the sustainable manufacturing of flexible supercapacitors
topic activated banana peel
supercapacitor
bio-waste
BET-surface
XRD
CV
url https://www.mdpi.com/2072-666X/14/2/330
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AT jornfelixlubben valorizationofbananapeelusingcarbonizationpotentialuseinthesustainablemanufacturingofflexiblesupercapacitors