Dihydroxyacetone valorization with high atom efficiency via controlling radical oxidation pathways over natural mineral-inspired catalyst
Radicals-mediated Fenton chemistry has the potential for biomass valorization. Here, inspired from the natural goethite mineral, the authors develop a MnO2/goethite catalyst showing excellent yields of glycolic acid and formic acid from dihydroxyacetone, an important biomass-based platform molecule.
| Main Authors: | , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2021-11-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-021-27240-5 |
| _version_ | 1818839904823541760 |
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| author | Jinling Wang Xingchao Dai Hualin Wang Honglai Liu Jabor Rabeah Angelika Brückner Feng Shi Ming Gong Xuejing Yang |
| author_facet | Jinling Wang Xingchao Dai Hualin Wang Honglai Liu Jabor Rabeah Angelika Brückner Feng Shi Ming Gong Xuejing Yang |
| author_sort | Jinling Wang |
| collection | DOAJ |
| description | Radicals-mediated Fenton chemistry has the potential for biomass valorization. Here, inspired from the natural goethite mineral, the authors develop a MnO2/goethite catalyst showing excellent yields of glycolic acid and formic acid from dihydroxyacetone, an important biomass-based platform molecule. |
| first_indexed | 2024-12-19T04:01:42Z |
| format | Article |
| id | doaj.art-e8d2684a54d64b22a4f32e63a70cacd8 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-19T04:01:42Z |
| publishDate | 2021-11-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-e8d2684a54d64b22a4f32e63a70cacd82022-12-21T20:36:40ZengNature PortfolioNature Communications2041-17232021-11-0112111110.1038/s41467-021-27240-5Dihydroxyacetone valorization with high atom efficiency via controlling radical oxidation pathways over natural mineral-inspired catalystJinling Wang0Xingchao Dai1Hualin Wang2Honglai Liu3Jabor Rabeah4Angelika Brückner5Feng Shi6Ming Gong7Xuejing Yang8National Engineering Laboratory for Industrial Wastewater Treatment, East China University of Science and Technology (ECUST)Leibniz-Institut für Katalyse e.V. an der Universität Rostock (LIKAT)National Engineering Laboratory for Industrial Wastewater Treatment, East China University of Science and Technology (ECUST)State Key Laboratory of Chemical Engineering, ECUSTLeibniz-Institut für Katalyse e.V. an der Universität Rostock (LIKAT)Leibniz-Institut für Katalyse e.V. an der Universität Rostock (LIKAT)State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of SciencesDepartment of Chemistry, Fudan UniversityNational Engineering Laboratory for Industrial Wastewater Treatment, East China University of Science and Technology (ECUST)Radicals-mediated Fenton chemistry has the potential for biomass valorization. Here, inspired from the natural goethite mineral, the authors develop a MnO2/goethite catalyst showing excellent yields of glycolic acid and formic acid from dihydroxyacetone, an important biomass-based platform molecule.https://doi.org/10.1038/s41467-021-27240-5 |
| spellingShingle | Jinling Wang Xingchao Dai Hualin Wang Honglai Liu Jabor Rabeah Angelika Brückner Feng Shi Ming Gong Xuejing Yang Dihydroxyacetone valorization with high atom efficiency via controlling radical oxidation pathways over natural mineral-inspired catalyst Nature Communications |
| title | Dihydroxyacetone valorization with high atom efficiency via controlling radical oxidation pathways over natural mineral-inspired catalyst |
| title_full | Dihydroxyacetone valorization with high atom efficiency via controlling radical oxidation pathways over natural mineral-inspired catalyst |
| title_fullStr | Dihydroxyacetone valorization with high atom efficiency via controlling radical oxidation pathways over natural mineral-inspired catalyst |
| title_full_unstemmed | Dihydroxyacetone valorization with high atom efficiency via controlling radical oxidation pathways over natural mineral-inspired catalyst |
| title_short | Dihydroxyacetone valorization with high atom efficiency via controlling radical oxidation pathways over natural mineral-inspired catalyst |
| title_sort | dihydroxyacetone valorization with high atom efficiency via controlling radical oxidation pathways over natural mineral inspired catalyst |
| url | https://doi.org/10.1038/s41467-021-27240-5 |
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