Probing the Electronic Structure of Dinuclear Carbon-Rich Complexes Containing an Octa-3,5-diene-1,7-diyndiyl Bridging Ligand

Probing the Electronic Structure of Dinuclear Carbon-Rich Complexes Containing an Octa-3,5-diene-1,7-diyndiyl Bridging Ligand

One electron oxidation of the monometallic alkenylacetylide complexes [Ru{C≡CC(R)=CH<sub>2</sub>}(dppe)Cp*] (<b>1</b>) and [Ru{C≡CC(R)=CH<sub>2</sub>}Cl(dppe)<sub>2</sub>] (<b>2</b>) (R = Ph (<b>a</b>); R = 4-MeS-C<sub>6&l...

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Bibliographic Details
Main Authors: Michael R. Hall, Stephen A. Moggach, Paul J. Low
Format: Article
Language:English
Published: MDPI AG 2024-01-01
Series:Inorganics
Subjects:
organometallic complexes
cumulene
oxidative coupling
carbon-rich ligand
mixed-valence
Robin–Day classification
Online Access:https://www.mdpi.com/2304-6740/12/1/20

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