Study on the Characteristics of Damaged Sandstone in the Longshan Grottoes Using Water Chemistry and Freeze–Thaw Cycling

Sandstone from the Longshan Grottoes in Taiyuan, China, was the research object of this paper. The sandstone samples were soaked in distilled water, Na<sub>2</sub>SO<sub>4</sub> solution, and NaCl solution and subjected to freeze–thaw testing. Sandstone specimens were treated...

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Main Authors: Bo Sun, Xingyue Li, Kai Cui, Ningbo Peng, Jie Hong, Rui Chen, Chen Jia
Format: Article
Language:English
Published: MDPI AG 2023-03-01
Series:Minerals
Subjects:
Online Access:https://www.mdpi.com/2075-163X/13/3/430
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author Bo Sun
Xingyue Li
Kai Cui
Ningbo Peng
Jie Hong
Rui Chen
Chen Jia
author_facet Bo Sun
Xingyue Li
Kai Cui
Ningbo Peng
Jie Hong
Rui Chen
Chen Jia
author_sort Bo Sun
collection DOAJ
description Sandstone from the Longshan Grottoes in Taiyuan, China, was the research object of this paper. The sandstone samples were soaked in distilled water, Na<sub>2</sub>SO<sub>4</sub> solution, and NaCl solution and subjected to freeze–thaw testing. Sandstone specimens were treated with 0, 5, 10, 15, 20, 25, and 30 freeze–thaw cycles. The mass ratio, P-wave velocity, surface hardness, uniaxial compressive strength, and other physical-mechanical features of rock samples were measured after different numbers of cycles. The results of mercury injection, scanning electron microscopy, and X-ray diffraction were combined to explore the damage mechanisms and characteristics of the rock samples under the combined action of chemicals and freeze–thaw cycles. It was found that the damage degree of sandstone increased logarithmically with the number of cycles, with Na<sub>2</sub>SO<sub>4</sub> solution causing the most damage. Damage variables D of the samples soaked in distilled water, Na<sub>2</sub>SO<sub>4</sub> solution, and NaCl solution after 30 freeze–thaw cycles were 3.89%, 6.51%, and 4.74%, respectively. The difference in damage between the solutions is caused by the combination of frost heave, dissolution, and salt crystallization, and the damage process generally occurs from the inside and the outside and is manifested as an increase in the number of macropores and the appearance of new pores. Freezing–thawing and salt action are important causes of the powdering and detachment of sandstone in the Longshan Grottoes.
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spelling doaj.art-e8e4a40ef4e04ecf8f2d10dddcfd14122023-11-17T12:48:29ZengMDPI AGMinerals2075-163X2023-03-0113343010.3390/min13030430Study on the Characteristics of Damaged Sandstone in the Longshan Grottoes Using Water Chemistry and Freeze–Thaw CyclingBo Sun0Xingyue Li1Kai Cui2Ningbo Peng3Jie Hong4Rui Chen5Chen Jia6Key Laboratory of Disaster Prevention and Mitigation, Department of Civil Engineering, Lanzhou University of Technology, Lanzhou 730050, ChinaKey Laboratory of Disaster Prevention and Mitigation, Department of Civil Engineering, Lanzhou University of Technology, Lanzhou 730050, ChinaKey Laboratory of Disaster Prevention and Mitigation, Department of Civil Engineering, Lanzhou University of Technology, Lanzhou 730050, ChinaFaculty of Architecture and Civil Engineering, Huaiyin Institute of Technology, Huaian 223001, ChinaNorthwest Research Institute Limited Company of China Railway Engineering Corporation, Lanzhou 730000, ChinaNorthwest Research Institute Limited Company of China Railway Engineering Corporation, Lanzhou 730000, ChinaTaiyuan Cultural Relics Protection and Research Institute, Taiyuan 030012, ChinaSandstone from the Longshan Grottoes in Taiyuan, China, was the research object of this paper. The sandstone samples were soaked in distilled water, Na<sub>2</sub>SO<sub>4</sub> solution, and NaCl solution and subjected to freeze–thaw testing. Sandstone specimens were treated with 0, 5, 10, 15, 20, 25, and 30 freeze–thaw cycles. The mass ratio, P-wave velocity, surface hardness, uniaxial compressive strength, and other physical-mechanical features of rock samples were measured after different numbers of cycles. The results of mercury injection, scanning electron microscopy, and X-ray diffraction were combined to explore the damage mechanisms and characteristics of the rock samples under the combined action of chemicals and freeze–thaw cycles. It was found that the damage degree of sandstone increased logarithmically with the number of cycles, with Na<sub>2</sub>SO<sub>4</sub> solution causing the most damage. Damage variables D of the samples soaked in distilled water, Na<sub>2</sub>SO<sub>4</sub> solution, and NaCl solution after 30 freeze–thaw cycles were 3.89%, 6.51%, and 4.74%, respectively. The difference in damage between the solutions is caused by the combination of frost heave, dissolution, and salt crystallization, and the damage process generally occurs from the inside and the outside and is manifested as an increase in the number of macropores and the appearance of new pores. Freezing–thawing and salt action are important causes of the powdering and detachment of sandstone in the Longshan Grottoes.https://www.mdpi.com/2075-163X/13/3/430Longshan Grottoessandstonefreeze–thaw cyclechemical solutiondamage characteristics
spellingShingle Bo Sun
Xingyue Li
Kai Cui
Ningbo Peng
Jie Hong
Rui Chen
Chen Jia
Study on the Characteristics of Damaged Sandstone in the Longshan Grottoes Using Water Chemistry and Freeze–Thaw Cycling
Minerals
Longshan Grottoes
sandstone
freeze–thaw cycle
chemical solution
damage characteristics
title Study on the Characteristics of Damaged Sandstone in the Longshan Grottoes Using Water Chemistry and Freeze–Thaw Cycling
title_full Study on the Characteristics of Damaged Sandstone in the Longshan Grottoes Using Water Chemistry and Freeze–Thaw Cycling
title_fullStr Study on the Characteristics of Damaged Sandstone in the Longshan Grottoes Using Water Chemistry and Freeze–Thaw Cycling
title_full_unstemmed Study on the Characteristics of Damaged Sandstone in the Longshan Grottoes Using Water Chemistry and Freeze–Thaw Cycling
title_short Study on the Characteristics of Damaged Sandstone in the Longshan Grottoes Using Water Chemistry and Freeze–Thaw Cycling
title_sort study on the characteristics of damaged sandstone in the longshan grottoes using water chemistry and freeze thaw cycling
topic Longshan Grottoes
sandstone
freeze–thaw cycle
chemical solution
damage characteristics
url https://www.mdpi.com/2075-163X/13/3/430
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