Diamagnetic cobalt(III)tris(o-ethylxanthate) and nickel(II)bis(o-ethylxanthate)

Diamagnetic [Co(xanth)3] and [Ni(xanth)2] complexes have been prepared by reaction of Co(II) and Ni(II) salts with potassium O-ethyl xanthate (Kxanth). The isolated Co(III) and Ni(II) complexes have been characterized by single-crystal X-ray crystallography, UV-VIS and IR spectroscopy, computational...

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Main Authors: Varga Filip, Titiš Ján, Rajnák Cyril, Moncoľ Ján, Boča Roman
Format: Article
Language:English
Published: SciCell s.r.o. 2017-12-01
Series:Nova Biotechnologica et Chimica
Subjects:
Online Access:http://www.degruyter.com/view/j/nbec.2017.16.issue-2/nbec-2017-0019/nbec-2017-0019.xml?format=INT
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author Varga Filip
Titiš Ján
Rajnák Cyril
Moncoľ Ján
Boča Roman
author_facet Varga Filip
Titiš Ján
Rajnák Cyril
Moncoľ Ján
Boča Roman
author_sort Varga Filip
collection DOAJ
description Diamagnetic [Co(xanth)3] and [Ni(xanth)2] complexes have been prepared by reaction of Co(II) and Ni(II) salts with potassium O-ethyl xanthate (Kxanth). The isolated Co(III) and Ni(II) complexes have been characterized by single-crystal X-ray crystallography, UV-VIS and IR spectroscopy, computational methods, and magnetic measurements.
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spelling doaj.art-e8e60373dc24450d9e97a5e06d6377fa2022-12-22T00:34:03ZengSciCell s.r.o.Nova Biotechnologica et Chimica1338-69052017-12-0116213814610.1515/nbec-2017-0019nbec-2017-0019Diamagnetic cobalt(III)tris(o-ethylxanthate) and nickel(II)bis(o-ethylxanthate)Varga Filip0Titiš Ján1Rajnák Cyril2Moncoľ Ján3Boča Roman4Department of Chemistry, Faculty of Natural Sciences, University of SS. Cyril and Methodius in Trnva, Nám. J. Herdu 2, Trnava, SK-917 01, Slovak RepublicDepartment of Chemistry, Faculty of Natural Sciences, University of SS. Cyril and Methodius in Trnva, Nám. J. Herdu 2, Trnava, SK-917 01, Slovak RepublicDepartment of Chemistry, Faculty of Natural Sciences, University of SS. Cyril and Methodius in Trnva, Nám. J. Herdu 2, Trnava, SK-917 01, Slovak RepublicInstitute of Inorganic Chemistry, FCHPT, Slovak University of Technology, Bratislava, SK-812 37, Slovak RepublicDepartment of Chemistry, Faculty of Natural Sciences, University of SS. Cyril and Methodius in Trnva, Nám. J. Herdu 2, Trnava, SK-917 01, Slovak RepublicDiamagnetic [Co(xanth)3] and [Ni(xanth)2] complexes have been prepared by reaction of Co(II) and Ni(II) salts with potassium O-ethyl xanthate (Kxanth). The isolated Co(III) and Ni(II) complexes have been characterized by single-crystal X-ray crystallography, UV-VIS and IR spectroscopy, computational methods, and magnetic measurements.http://www.degruyter.com/view/j/nbec.2017.16.issue-2/nbec-2017-0019/nbec-2017-0019.xml?format=INTAb initio calculationsCo(III) complexMagnetismNi(II) complexO-ethyl xanthateUV-VIS spectra
spellingShingle Varga Filip
Titiš Ján
Rajnák Cyril
Moncoľ Ján
Boča Roman
Diamagnetic cobalt(III)tris(o-ethylxanthate) and nickel(II)bis(o-ethylxanthate)
Nova Biotechnologica et Chimica
Ab initio calculations
Co(III) complex
Magnetism
Ni(II) complex
O-ethyl xanthate
UV-VIS spectra
title Diamagnetic cobalt(III)tris(o-ethylxanthate) and nickel(II)bis(o-ethylxanthate)
title_full Diamagnetic cobalt(III)tris(o-ethylxanthate) and nickel(II)bis(o-ethylxanthate)
title_fullStr Diamagnetic cobalt(III)tris(o-ethylxanthate) and nickel(II)bis(o-ethylxanthate)
title_full_unstemmed Diamagnetic cobalt(III)tris(o-ethylxanthate) and nickel(II)bis(o-ethylxanthate)
title_short Diamagnetic cobalt(III)tris(o-ethylxanthate) and nickel(II)bis(o-ethylxanthate)
title_sort diamagnetic cobalt iii tris o ethylxanthate and nickel ii bis o ethylxanthate
topic Ab initio calculations
Co(III) complex
Magnetism
Ni(II) complex
O-ethyl xanthate
UV-VIS spectra
url http://www.degruyter.com/view/j/nbec.2017.16.issue-2/nbec-2017-0019/nbec-2017-0019.xml?format=INT
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AT titisjan diamagneticcobaltiiitrisoethylxanthateandnickeliibisoethylxanthate
AT rajnakcyril diamagneticcobaltiiitrisoethylxanthateandnickeliibisoethylxanthate
AT moncoljan diamagneticcobaltiiitrisoethylxanthateandnickeliibisoethylxanthate
AT bocaroman diamagneticcobaltiiitrisoethylxanthateandnickeliibisoethylxanthate