Nickel ferrite/TiO2 Nanofibrous Composite: Enhanced Photocatalytic Dye Degradation Under Visible Light

A highly efficient NiFe2O4/TiO2 nanofibrous photocatalyst was prepared by a simultaneous solution blow spinning method. The hybrid fibers were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Raman spectroscopy, and magnetometry. The photocatalytic properties were evalua...

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Main Authors: Hellen C. T. Firmino, Emanuel P. Nascimento, Rondinele N. Araujo, Francisco J.A. Loureiro, Gelmires A. Neves, Marco A. Morales, Romualdo R. Menezes
Format: Article
Language:English
Published: Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol) 2024-02-01
Series:Materials Research
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392024000100209&tlng=en
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author Hellen C. T. Firmino
Emanuel P. Nascimento
Rondinele N. Araujo
Francisco J.A. Loureiro
Gelmires A. Neves
Marco A. Morales
Romualdo R. Menezes
author_facet Hellen C. T. Firmino
Emanuel P. Nascimento
Rondinele N. Araujo
Francisco J.A. Loureiro
Gelmires A. Neves
Marco A. Morales
Romualdo R. Menezes
author_sort Hellen C. T. Firmino
collection DOAJ
description A highly efficient NiFe2O4/TiO2 nanofibrous photocatalyst was prepared by a simultaneous solution blow spinning method. The hybrid fibers were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Raman spectroscopy, and magnetometry. The photocatalytic properties were evaluated using Crystal violet (CV) and Congo red (CR) dyes under visible light irradiation. Fibers calcined at 600 ºC and 700 ºC showed the highest CV decolorization (77%). On the other hand, for CR, the best performance was encountered with the photocatalysts heat-treated at 500 ºC, which exhibited photocatalytic degradation of 87% after only 30 min of visible light irradiation. The high reaction rates (0.018 to 0.067 min-1) explain the fast decolorization yielded by the combined effect of adsorption and photocatalytic processes. Moreover, recyclability assays showed stable CR dye efficiency after five recycling cycles. Therefore, the NiFe2O4/TiO2 nanofibers present a high potential for application in the decolorization treatment of wastewater from the textile industry.
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publishDate 2024-02-01
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spelling doaj.art-e8e6ad82991b40b08e44b9b95ecc481b2024-02-20T07:35:05ZengAssociação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)Materials Research1516-14392024-02-012710.1590/1980-5373-mr-2023-0391Nickel ferrite/TiO2 Nanofibrous Composite: Enhanced Photocatalytic Dye Degradation Under Visible LightHellen C. T. Firminohttps://orcid.org/0000-0003-0627-2587Emanuel P. NascimentoRondinele N. AraujoFrancisco J.A. LoureiroGelmires A. NevesMarco A. MoralesRomualdo R. MenezesA highly efficient NiFe2O4/TiO2 nanofibrous photocatalyst was prepared by a simultaneous solution blow spinning method. The hybrid fibers were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Raman spectroscopy, and magnetometry. The photocatalytic properties were evaluated using Crystal violet (CV) and Congo red (CR) dyes under visible light irradiation. Fibers calcined at 600 ºC and 700 ºC showed the highest CV decolorization (77%). On the other hand, for CR, the best performance was encountered with the photocatalysts heat-treated at 500 ºC, which exhibited photocatalytic degradation of 87% after only 30 min of visible light irradiation. The high reaction rates (0.018 to 0.067 min-1) explain the fast decolorization yielded by the combined effect of adsorption and photocatalytic processes. Moreover, recyclability assays showed stable CR dye efficiency after five recycling cycles. Therefore, the NiFe2O4/TiO2 nanofibers present a high potential for application in the decolorization treatment of wastewater from the textile industry.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392024000100209&tlng=enNickel ferrite/titania nanofibersCongo redCrystal violetPhotocatalysis
spellingShingle Hellen C. T. Firmino
Emanuel P. Nascimento
Rondinele N. Araujo
Francisco J.A. Loureiro
Gelmires A. Neves
Marco A. Morales
Romualdo R. Menezes
Nickel ferrite/TiO2 Nanofibrous Composite: Enhanced Photocatalytic Dye Degradation Under Visible Light
Materials Research
Nickel ferrite/titania nanofibers
Congo red
Crystal violet
Photocatalysis
title Nickel ferrite/TiO2 Nanofibrous Composite: Enhanced Photocatalytic Dye Degradation Under Visible Light
title_full Nickel ferrite/TiO2 Nanofibrous Composite: Enhanced Photocatalytic Dye Degradation Under Visible Light
title_fullStr Nickel ferrite/TiO2 Nanofibrous Composite: Enhanced Photocatalytic Dye Degradation Under Visible Light
title_full_unstemmed Nickel ferrite/TiO2 Nanofibrous Composite: Enhanced Photocatalytic Dye Degradation Under Visible Light
title_short Nickel ferrite/TiO2 Nanofibrous Composite: Enhanced Photocatalytic Dye Degradation Under Visible Light
title_sort nickel ferrite tio2 nanofibrous composite enhanced photocatalytic dye degradation under visible light
topic Nickel ferrite/titania nanofibers
Congo red
Crystal violet
Photocatalysis
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392024000100209&tlng=en
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