Recent advances of single-atom alloy catalyst: Properties, synthetic methods and electrocatalytic applications

Developing high-performance and cost-effective electrocatalysts for clean and renewable energy conversion process has been proved a promising approach to deal with the global energy and environment issues. Single-atom alloy (SAA) catalyst, with foreign metal atoms atomically dispersed in the surface...

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Main Authors: Jiahao Zhuang, Dingsheng Wang
Format: Article
Language:English
Published: Elsevier 2023-09-01
Series:Materials Today Catalysis
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2949754X23000091
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author Jiahao Zhuang
Dingsheng Wang
author_facet Jiahao Zhuang
Dingsheng Wang
author_sort Jiahao Zhuang
collection DOAJ
description Developing high-performance and cost-effective electrocatalysts for clean and renewable energy conversion process has been proved a promising approach to deal with the global energy and environment issues. Single-atom alloy (SAA) catalyst, with foreign metal atoms atomically dispersed in the surface of a host metal, combines the merits of conventional metal alloys and single-atom catalysts. The maximum atomic utilization of active metal and unique structural and electrical properties of SAA offer great potential in boosting electrocatalytic activity and reducing the cost of manufacture. Meanwhile, the well-defined active sites raise an opportunity to shed the light on structure-activity relationship and further direct the synthesis of high-efficiency electrocatalysts. Herein, we focus on the recent developments of advanced SAA catalysts and discussed the general properties of SAAs. Then the design principle and synthetic methods were summarized. Next, we highlighted the practical applications of SAAs in electrocatalytic energy conversion and chemicals production, including hydrogen evolution reaction, oxygen evolution reaction, CO2 reduction reaction, N2 reduction reaction and other representative reactions. Finally, the challenges and future directions of SAAs are presented.
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spelling doaj.art-e8e6fbbc4b9d4987aa1998b6a6f1c0532024-03-28T06:40:32ZengElsevierMaterials Today Catalysis2949-754X2023-09-012100009Recent advances of single-atom alloy catalyst: Properties, synthetic methods and electrocatalytic applicationsJiahao Zhuang0Dingsheng Wang1Department of Chemistry, Tsinghua University, Beijing 100084, ChinaCorresponding author.; Department of Chemistry, Tsinghua University, Beijing 100084, ChinaDeveloping high-performance and cost-effective electrocatalysts for clean and renewable energy conversion process has been proved a promising approach to deal with the global energy and environment issues. Single-atom alloy (SAA) catalyst, with foreign metal atoms atomically dispersed in the surface of a host metal, combines the merits of conventional metal alloys and single-atom catalysts. The maximum atomic utilization of active metal and unique structural and electrical properties of SAA offer great potential in boosting electrocatalytic activity and reducing the cost of manufacture. Meanwhile, the well-defined active sites raise an opportunity to shed the light on structure-activity relationship and further direct the synthesis of high-efficiency electrocatalysts. Herein, we focus on the recent developments of advanced SAA catalysts and discussed the general properties of SAAs. Then the design principle and synthetic methods were summarized. Next, we highlighted the practical applications of SAAs in electrocatalytic energy conversion and chemicals production, including hydrogen evolution reaction, oxygen evolution reaction, CO2 reduction reaction, N2 reduction reaction and other representative reactions. Finally, the challenges and future directions of SAAs are presented.http://www.sciencedirect.com/science/article/pii/S2949754X23000091ElectrocatalysisSingle-atom alloy catalystsSynthetic methodsStructure-activity relationship
spellingShingle Jiahao Zhuang
Dingsheng Wang
Recent advances of single-atom alloy catalyst: Properties, synthetic methods and electrocatalytic applications
Materials Today Catalysis
Electrocatalysis
Single-atom alloy catalysts
Synthetic methods
Structure-activity relationship
title Recent advances of single-atom alloy catalyst: Properties, synthetic methods and electrocatalytic applications
title_full Recent advances of single-atom alloy catalyst: Properties, synthetic methods and electrocatalytic applications
title_fullStr Recent advances of single-atom alloy catalyst: Properties, synthetic methods and electrocatalytic applications
title_full_unstemmed Recent advances of single-atom alloy catalyst: Properties, synthetic methods and electrocatalytic applications
title_short Recent advances of single-atom alloy catalyst: Properties, synthetic methods and electrocatalytic applications
title_sort recent advances of single atom alloy catalyst properties synthetic methods and electrocatalytic applications
topic Electrocatalysis
Single-atom alloy catalysts
Synthetic methods
Structure-activity relationship
url http://www.sciencedirect.com/science/article/pii/S2949754X23000091
work_keys_str_mv AT jiahaozhuang recentadvancesofsingleatomalloycatalystpropertiessyntheticmethodsandelectrocatalyticapplications
AT dingshengwang recentadvancesofsingleatomalloycatalystpropertiessyntheticmethodsandelectrocatalyticapplications