Effect of Graphene Oxide Modified with Organic Amine on the Aging Resistance, Rolling Loss and Wet-Skid Resistance of Solution Polymerized Styrene-Butadiene Rubber
Graphene oxide (GO) was modified by p-phenylenediamine (PPD), aiming at improving the wet-skid resistance and reduce the rolling loss of solution polymerized styrene-butadiene rubber (SSBR). PPD with amino groups enabled GO to obtain anti-aging function. The structure of modified GO (PPD-GO) was cha...
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MDPI AG
2020-02-01
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| Series: | Materials |
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| Online Access: | https://www.mdpi.com/1996-1944/13/5/1025 |
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| author | Songhan Wan Xiaobin Lu Hongguo Zhao Songbo Chen Shuwei Cai Xianru He Rui Zhang |
| author_facet | Songhan Wan Xiaobin Lu Hongguo Zhao Songbo Chen Shuwei Cai Xianru He Rui Zhang |
| author_sort | Songhan Wan |
| collection | DOAJ |
| description | Graphene oxide (GO) was modified by p-phenylenediamine (PPD), aiming at improving the wet-skid resistance and reduce the rolling loss of solution polymerized styrene-butadiene rubber (SSBR). PPD with amino groups enabled GO to obtain anti-aging function. The structure of modified GO (PPD-GO) was characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and Raman spectroscopy. Mechanical tests showed that the mechanical properties of SSBR before and after aging were improved by adding PPD-GO. The results of thermogravimetric-differential scanning calorimeter synchronization analysis (TGA-DSC) indicated that SSBR/PPD-GO obtained good thermo-oxidative stability. The dynamic mechanical analysis (DMA) of SSBR composites showed that the mechanical loss factor (tanδ) peak moved to high temperature with the content of PPD-GO. The tanδ values of SSBR composites showed that it had a good effect on improving the wet-skid resistance and reducing the rolling loss of SSBR by adjusting the content of PPD-GO. In particular, with the addition of 4 phr GO, SSBR was effectively improved in mechanical properties, aging resistance, wet-skid resistance and low rolling loss. |
| first_indexed | 2024-04-12T05:29:37Z |
| format | Article |
| id | doaj.art-e8f4cf1116514e2283a7acb96f93d698 |
| institution | Directory Open Access Journal |
| issn | 1996-1944 |
| language | English |
| last_indexed | 2024-04-12T05:29:37Z |
| publishDate | 2020-02-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Materials |
| spelling | doaj.art-e8f4cf1116514e2283a7acb96f93d6982022-12-22T03:46:08ZengMDPI AGMaterials1996-19442020-02-01135102510.3390/ma13051025ma13051025Effect of Graphene Oxide Modified with Organic Amine on the Aging Resistance, Rolling Loss and Wet-Skid Resistance of Solution Polymerized Styrene-Butadiene RubberSonghan Wan0Xiaobin Lu1Hongguo Zhao2Songbo Chen3Shuwei Cai4Xianru He5Rui Zhang6School of Materials Science and Engineering, Southwest Petroleum University, Chengdu 610500, ChinaSchool of Materials Science and Engineering, Southwest Petroleum University, Chengdu 610500, ChinaPetrochemical Research Institute, PetroChina, Lanzhou 730060, ChinaSchool of Materials Science and Engineering, Southwest Petroleum University, Chengdu 610500, ChinaSchool of Materials Science and Engineering, Southwest Petroleum University, Chengdu 610500, ChinaSchool of Materials Science and Engineering, Southwest Petroleum University, Chengdu 610500, ChinaInstitute für Physik, Universität Rostock, 18051 Rostock, GermanyGraphene oxide (GO) was modified by p-phenylenediamine (PPD), aiming at improving the wet-skid resistance and reduce the rolling loss of solution polymerized styrene-butadiene rubber (SSBR). PPD with amino groups enabled GO to obtain anti-aging function. The structure of modified GO (PPD-GO) was characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and Raman spectroscopy. Mechanical tests showed that the mechanical properties of SSBR before and after aging were improved by adding PPD-GO. The results of thermogravimetric-differential scanning calorimeter synchronization analysis (TGA-DSC) indicated that SSBR/PPD-GO obtained good thermo-oxidative stability. The dynamic mechanical analysis (DMA) of SSBR composites showed that the mechanical loss factor (tanδ) peak moved to high temperature with the content of PPD-GO. The tanδ values of SSBR composites showed that it had a good effect on improving the wet-skid resistance and reducing the rolling loss of SSBR by adjusting the content of PPD-GO. In particular, with the addition of 4 phr GO, SSBR was effectively improved in mechanical properties, aging resistance, wet-skid resistance and low rolling loss.https://www.mdpi.com/1996-1944/13/5/1025p-phenylenediamine (ppd)graphene oxide (go)solution polymerized styrene-butadiene rubber (ssbr)aging resistancerolling losswet-skid resistance |
| spellingShingle | Songhan Wan Xiaobin Lu Hongguo Zhao Songbo Chen Shuwei Cai Xianru He Rui Zhang Effect of Graphene Oxide Modified with Organic Amine on the Aging Resistance, Rolling Loss and Wet-Skid Resistance of Solution Polymerized Styrene-Butadiene Rubber Materials p-phenylenediamine (ppd) graphene oxide (go) solution polymerized styrene-butadiene rubber (ssbr) aging resistance rolling loss wet-skid resistance |
| title | Effect of Graphene Oxide Modified with Organic Amine on the Aging Resistance, Rolling Loss and Wet-Skid Resistance of Solution Polymerized Styrene-Butadiene Rubber |
| title_full | Effect of Graphene Oxide Modified with Organic Amine on the Aging Resistance, Rolling Loss and Wet-Skid Resistance of Solution Polymerized Styrene-Butadiene Rubber |
| title_fullStr | Effect of Graphene Oxide Modified with Organic Amine on the Aging Resistance, Rolling Loss and Wet-Skid Resistance of Solution Polymerized Styrene-Butadiene Rubber |
| title_full_unstemmed | Effect of Graphene Oxide Modified with Organic Amine on the Aging Resistance, Rolling Loss and Wet-Skid Resistance of Solution Polymerized Styrene-Butadiene Rubber |
| title_short | Effect of Graphene Oxide Modified with Organic Amine on the Aging Resistance, Rolling Loss and Wet-Skid Resistance of Solution Polymerized Styrene-Butadiene Rubber |
| title_sort | effect of graphene oxide modified with organic amine on the aging resistance rolling loss and wet skid resistance of solution polymerized styrene butadiene rubber |
| topic | p-phenylenediamine (ppd) graphene oxide (go) solution polymerized styrene-butadiene rubber (ssbr) aging resistance rolling loss wet-skid resistance |
| url | https://www.mdpi.com/1996-1944/13/5/1025 |
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