Chlorido[2,2′-(oxydimethylene)dipyridine]copper(II) perchlorate–aquachlorido[2,2′-(oxydimethylene)dipyridine]copper(II) perchlorate (1/1)
The asymmetric unit of the title compound, [CuCl(C12H12N2O)][CuCl(C12H12N2O)(H2O)](ClO4)2, contains two different discrete cations. In one cation, the CuII ion is coordinated in a slightly distorted square-planar geometry, while in the other the CuII ion is in a slightly distorted square-pyramidal e...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809027123 |
| Summary: | The asymmetric unit of the title compound, [CuCl(C12H12N2O)][CuCl(C12H12N2O)(H2O)](ClO4)2, contains two different discrete cations. In one cation, the CuII ion is coordinated in a slightly distorted square-planar geometry, while in the other the CuII ion is in a slightly distorted square-pyramidal environment. In the crystal structure, there are O—H...O hydrogen bonds between coordinated water molecules and perchlorate anions. Both types of cations are linked into one-dimensional chains along the b axis by weak electrostatic Cu...Cl interactions, with Cu...Cl distances of 2.8088 (16) and 3.2074 (17) Å. |
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| ISSN: | 1600-5368 |